全文获取类型
收费全文 | 143篇 |
免费 | 2篇 |
国内免费 | 2篇 |
专业分类
安全科学 | 3篇 |
废物处理 | 14篇 |
环保管理 | 11篇 |
综合类 | 32篇 |
基础理论 | 12篇 |
污染及防治 | 52篇 |
评价与监测 | 17篇 |
社会与环境 | 6篇 |
出版年
2023年 | 1篇 |
2022年 | 9篇 |
2021年 | 8篇 |
2020年 | 3篇 |
2019年 | 5篇 |
2018年 | 11篇 |
2017年 | 7篇 |
2016年 | 10篇 |
2015年 | 5篇 |
2014年 | 13篇 |
2013年 | 11篇 |
2012年 | 6篇 |
2011年 | 14篇 |
2010年 | 7篇 |
2009年 | 3篇 |
2008年 | 4篇 |
2007年 | 7篇 |
2006年 | 3篇 |
2005年 | 3篇 |
2004年 | 2篇 |
2003年 | 3篇 |
2002年 | 7篇 |
2001年 | 1篇 |
2000年 | 1篇 |
1999年 | 2篇 |
1994年 | 1篇 |
排序方式: 共有147条查询结果,搜索用时 765 毫秒
31.
Solomon D Lehmann J de Zarruk KK Dathe J Kinyangi J Liang B Machado S 《Journal of environmental quality》2011,40(3):704-718
We investigated speciation, oxidative state changes, and long- and short-term molecular-level dynamics of organic S after 365 d of aerobic incubation with and without the addition of sugarcane residue using XANES spectroscopy. Soil samples were collected from the upper 15 cm of undisturbed grasslands since 1880, from undisturbed grasslands since 1931, and from cultivated fields since 1880 in the western United States. We found three distinct groups of organosulfur compounds in these grassland-derived soils: (i) strongly reduced (S to S) organic S that encompasses thiols, monosulfides, disulfides, polysulfides, and thiophenes; (ii) organic S in intermediate oxidation (S to S) states, which include sulfoxides and sulfonates; and (iii) strongly oxidized (S) organic S, which comprises ester-SO-S. The first two groups represent S directly linked to C and accounted for 80% of the total organic S detected by XANES from the undisturbed soils. Aerobic incubation without the addition of sugarcane residue led to a 21% decline in organanosulfur compounds directly linked to C and to up to an 82% increase inorganic S directly bonded to O. Among the C-bonded S compounds, low-valence thiols, sulfides, thiophenic S, and intermediate-valence sulfoxide S seem to be highly susceptible to microbial attack and may represent the most reactive components of organic S pool in these grassland soils. Sulfonate S exhibited a much lower short-term reactivity. The incorporation of sugarcane residue resulted in an increase in organosulfur compounds directly bonded to C at the early stage of incubation. However, similar to soils incubated without residue addition, the proportion of organic S directly linked to C continued to decline with increasing duration of aerobic incubation, whereas the proportion of organic S directly bonded to O showed a steady rise. 相似文献
32.
Rita JC Gama-Rodrigues EF Gama-Rodrigues AC Polidoro JC Machado RC Baligar VC 《Environmental management》2011,48(1):134-141
Agroforestry systems (AFSs) have an important role in capturing above and below ground soil carbon and play a dominant role
in mitigation of atmospheric CO2. Attempts has been made here to identify soil organic matter fractions in the cacao-AFSs that have different susceptibility
to microbial decomposition and further represent the basis of understanding soil C dynamics. The objective of this study was
to characterize the organic matter density fractions and soil size fractions in soils of two types of cacao agroforestry systems
and to compare with an adjacent natural forest in Bahia, Brazil. The land-use systems studied were: (1) a 30-year-old stand
of natural forest with cacao (cacao cabruca), (2) a 30-year-old stand of cacao with Erythrina glauca as shade trees (cacao + erythrina), and (3) an adjacent natural forest without cacao. Soil samples were collected from 0-10 cm
depth layer in reddish-yellow Oxisols. Soil samples was separated by wet sieving into five fraction-size classes (>2000 μm,
1000–2000 μm, 250–1000 μm, 53–250 μm, and <53 μm). C and N accumulated in to the light (free- and intra-aggregate density
fractions) and heavy fractions of whole soil and soil size fraction were determined. Soil size fraction obtained in cacao
AFS soils consisted mainly (65 %) of mega-aggregates (>2000 μm) mixed with macroaggregates (32–34%), and microaggregates (1–1.3%).
Soil organic carbon (SOC) and total N content increased with increasing soil size fraction in all land-use systems. Organic
C-to-total N ratio was higher in the macroaggregate than in the microaggregate. In general, in natural forest and cacao cabruca
the contribution of C and N in the light and heavy fractions was similar. However, in cacao + erythrina the heavy fraction
was the most common and contributed 67% of C and 63% of N. Finding of this study shows that the majority of C and N in all
three systems studied are found in macroaggregates, particularly in the 250–1000 μm size aggregate class. The heavy fraction
was the most common organic matter fraction in these soils. Thus, in mature cacao AFS on highly weathered soils the main mechanisms
of C stabilization could be the physical protection within macroaggregate structures thereby minimizing the impact of conversion
of forest to cacao AFS. 相似文献
33.
Fumian Tulio Machado Ferreira Fernando César de Andrade Juliana da Silva Ribeiro Canal Natália Silva Gomes Gabriela Teixeira Lilian Borges Miagostovich Marize Pereira 《Food and environmental virology》2021,13(4):553-559
Food and Environmental Virology - Norovirus is a major cause of foodborne-associated acute gastroenteritis (AGE) outbreaks worldwide. Usually, food products are contaminated either during... 相似文献
34.
John E.L. Maddock Maria B.P. Dos Santos Sonia R.N. Alves de Sá Pedro L.O. de A. Machado 《Environment, Development and Sustainability》2004,6(1-2):175-182
Soil respiration rates of a clay-loam textured Acrisol under different uses (Atlantic forest, manioc, horticulture and pasture) from Rio de Janeiro State were measured. The relationship between carbon dioxide (CO2) emissions and soil physico-chemical properties were investigated. Rates of CO2 emission of two sites (Atlantic forest and horticulture) were also evaluated in different seasons in 1997 and 1998. In the forest site, monthly means of measured respiration rates showed good correlation with soil temperature in the range 19.6–24.1°C (r2 = 0.89). In the horticulture site, no change was observed with soil moisture alone, in the range 3.0–13.2 wt%. In the horticulture soil, even when the surface soil was very dry, respiration rates increased in the hot, wetter summer but remained higher than the mean flux from forest soil. The CO2 emission flux of the Acrisol under different use showed good correlation with soil temperature (r2 = 0.72) and moisture (r2 = 0.61). 相似文献
35.
Manuel Benítez 《Ambio-人类环境杂志》2002,31(4):285-294
本文概述了引起萨尔瓦多红树林退化的各种因素,并分析了拟议中的红树林产权变化对贫困的海岸带社区红树林的意义.目前萨尔瓦多红树林生态系统的采伐和转化模式可通过补贴权利的透镜来观察,这种补助就是为特定用途向一些参与者授予财产权(而不授权给别人).遗憾的是,对红树林资源的使用进行管理的现有法律法规体系是相互矛盾和含混不清的.一些现行的法律对生态系统的使用和转变问题做出了完全相反的规定.如果不对各项补贴权利重新定义,就不能确保对红树林进行合理、持续的管理.但这种权利的重新定义应考虑其生活与生态系统的健康状况密切相关的那些群体的需要. 相似文献
36.
Sediments as monitors of heavy metal contamination in the Ave river basin (Portugal): multivariate analysis of data 总被引:13,自引:0,他引:13
Soares HM Boaventura RA Machado AA Esteves da Silva JC 《Environmental pollution (Barking, Essex : 1987)》1999,105(3):311-323
The concentrations of heavy metals (Cd, Cr, Cu, Ni, Pb, Zn) were determined in river sediments collected at the Ave river basin (Portugal) to obtain a general classification scenery of the pollution in this highly polluted region. Multivariate data analysis techniques of clustering, principal components and eigenvector projections were used in this classification. Five general areas with different polluting characteristics were detected and several individual heavy metal concentration abnormalities were detected in restricted areas. A good correlation between the overall metal contamination determined by multivariate analysis and metal pollution indexes for all sampling stations was obtained. Some preliminary experiments showed that the metal concentrations normalised to the volatile matter content in the sediment fraction with grain size <63 microm seems to be an adequate method for assessing metal pollution. 相似文献
37.
Antonio G. Checa Concepción Jiménez-López Alejandro Rodríguez-Navarro Jorge P. Machado 《Marine Biology》2007,150(5):819-827
To understand the relative importance of biological versus physicochemical control over biomineralization, we have tested
if the chemical composition of the medium (i.e., the Mg/Ca ratio) can change the mineralogy of mollusk shells. The shells
of mollusks are made of calcite and/or aragonite, which are by far the most common CaCO3 polymorphs. Several species of bivalves with predominantly calcitic shells have been cultivated in artificial seawater with
a Mg/Ca molar ratio within the range of 8.3–9.2, well above the present value for seawater (5.2). Four out of six species
used (the scallop Chlamys varia, the oyster Ostrea edulis, the saddle oyster Anomia ephippium and the mussel Mytilus edulis) survived long enough to secrete significant amounts of calcium carbonate. The deposits (sometimes extensive) formed on the
interior shell surfaces were predominantly aragonitic. Three individuals of C. varia also increased their length by adding new shell at the margin. Contrary to the internal shell deposits, these margins were
high-Mg calcite. This implies that the marginal mantle is able to exert a more strict control on the secreted mineral phase
than the mantle facing the internal shell surface. This is the first report on an in vivo experimentally forced switch in
bivalve shell mineralogy, from calcite to aragonite due to a change in water chemistry. 相似文献
38.
Miagostovich Marize Pereira Rocha Mônica Simões dos Reis Fabiane Bertoni Sampaio Marcelo Santos de Saldanha da Gama Gracie Carrijo Renata Malta Fabio Correia Rodrigues Janaína Genuino Amanda Ribeiro da Silva Assis Matheus Fumian Tulio Machado Barrocas Paulo Rubens Guimarães 《Food and environmental virology》2020,12(2):130-136
Food and Environmental Virology - The availability of drinking water is one of the main determinants of quality of life, disease prevention and the promotion of health. Viruses are important agents... 相似文献
39.
40.
Lourdes Teresinha Kist Said El Moutaqi Ênio Leandro Machado 《Journal of Cleaner Production》2009,17(13):1200-1205
This study included the layout characterization for the production process of a poultry slaughterhouse using qualitative and quantitative flow charts for water management; analysis of general parameters for pollution load in the wastewater produced in critical stages of the production process and assessment of environmental impact indicators. Prognoses for cleaner production based on water management were established. The diagnostic stage revealed that the scalding, pre-chilling, separated points of wastewater disposal for the wastewater treatment plant and disposal of treated and non-reused wastewater were critical for water management. Dissolved oxygen depletion and eutrophication account for the major environmental impacts of these wastewaters, resulting in an environmental pressure index of 32.1. The opportunities for cleaner production implementation resulting from this study include the reuse of wastewaters from pre-chilling and chilling for pre-washing of carcasses, since average temperatures of these wastewaters range between 4 and 16 °C. This will contribute to lowering the oil and grease pollution load. Another strategy concerns the standardization of cleaning procedures with rational water use in all work shifts and implementation of water meters on a sector-by-sector basis. In the latter case, which has already been implemented, water consumption was reduced by 13%. 相似文献