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31.
Environmental Persistence of Chemicals 总被引:1,自引:0,他引:1
- DOI: http://dx.doi.org/10.1065/espr2006.01.008
Background The hazard criterion of persistence as it applies to chemicals in the environment is reviewed and discussed. This quantity
can not be measured directly in the environment, thus it must be estimated using models that synthesise information on chemical
half-lives and partitioning properties, the nature of the environment and how the chemical is released into the environment.
Main Features It is suggested that the preferred criterion is the average residence time of the chemical in the environment, i.e. conceptually
the sum of the life-times of all molecules (attributable only to losses by degrading reactions) divided by the number of molecules.
If all chemical fate processes are first order, this persistence is independent of the quantity of chemical introduced and
whether introduction is steady- or unsteady-state in nature. It is shown that in a multimedia environment persistence is affected
not only by degradation kinetics, but also by mode-of-entry and partitioning. For screening level purposes a Level II equilibrium
model may be adequate but a Level III model is generally preferable for estimating the average persistence. If a distribution
of persistences is required a dynamic Level IV model must be used.
Discussion The implications for regulating chemicals on the basis of persistence are discussed.
Conclusion It is concluded that the preferred strategy is to use Level II, III, and IV models and that the use of only degradation kinetics
or media-specific half-lives can be misleading and uneconomical. 相似文献
32.
Neethu Kariyil Veettil Nandan Sivasankaran Bijoy Xavier Nelkunnassery Dominic Don Jayachandran Paravanparambil Rajakumar Anu Pashnath Raghu Midhun Alungal Manikandan Mohan Dhandapani Marigoudar Shambanagouda R. 《Environmental science and pollution research international》2021,28(2):1775-1788
Environmental Science and Pollution Research - The southwest coast of India along the Cochin region is seriously affected by metal contamination from increasing industrial activities. This... 相似文献
33.
After a 40-year absence caused by pollution and eutrophication, burrowing mayflies (Hexagenia spp.) recolonized western Lake Erie in the mid 1990s as water quality improved. Mayflies are an important food resource for the economically valuable yellow perch fishery and are considered to be major indicator species of the ecological condition of the lake. Since their reappearance, however, mayfly populations have suffered occasional unexplained recruitment failures. In 2002, a failure of fall recruitment followed an unusually warm summer in which western Lake Erie became temporarily stratified, resulting in low dissolved oxygen levels near the lake floor. In the present study, we examined a possible link between Hexagenia recruitment and periods of intermittent stratification for the years 1997 2002. A simple model was developed using surface temperature, wind speed, and water column data from 2003 to predict stratification. The model was then used to detect episodes of stratification in past years for which water column data are unavailable. Low or undetectable mayfly recruitment occurred in 1997 and 2002, years in which there was frequent or extended stratification between June and September. Highest mayfly reproduction in 2000 corresponded to the fewest stratified periods. These results suggest that even relatively brief periods of stratification can result in loss of larval mayfly recruitment, probably through the effects of hypoxia. A trend toward increasing frequency of hot summers in the Great Lakes region could result in recurrent loss of mayfly larvae in western Lake Erie and other shallow areas in the Great Lakes. 相似文献
34.
BETR-World: a geographically explicit model of chemical fate: application to transport of alpha-HCH to the Arctic 总被引:1,自引:0,他引:1
Toose L Woodfine DG MacLeod M Mackay D Gouin J 《Environmental pollution (Barking, Essex : 1987)》2004,128(1-2):223-240
The Berkeley-Trent (BETR)-World model, a 25 compartment, geographically explicit fugacity-based model is described and applied to evaluate the transport of chemicals from temperate source regions to receptor regions (such as the Arctic). The model was parameterized using GIS and an array of digital data on weather, oceans, freshwater, vegetation and geo-political boundaries. This version of the BETR model framework includes modification of atmospheric degradation rates by seasonally variable hydroxyl radical concentrations and temperature. Degradation rates in all other compartments vary with seasonally changing temperature. Deposition to the deep ocean has been included as a loss mechanism. A case study was undertaken for alpha-HCH. Dynamic emission scenarios were estimated for each of the 25 regions. Predicted environmental concentrations showed good agreement with measured values for the northern regions in air, and fresh and oceanic water and with the results from a previous model of global chemical fate. Potential for long-range transport and deposition to the Arctic region was assessed using a Transfer Efficiency combined with estimated emissions. European regions and the Orient including China have a high potential to contribute alpha-HCH contamination in the Arctic due to high rates of emission in these regions despite low Transfer Efficiencies. Sensitivity analyses reveal that the performance and reliability of the model is strongly influenced by parameters controlling degradation rates. 相似文献
35.
Levels of polychlorinated biphenyls and organochlorine pesticides in serum samples of Egyptian Vulture (Neophron percnopterus) from Spain 总被引:1,自引:0,他引:1
Concentrations of 23 polychlorinated biphenyls (PCBs), p,p'-DDT and two of its metabolites, p,p'-DDE and p,p'-TDE have been measured in serum samples of up to 1 ml of Egyptian Vulture (Neophron percnopterus) gathered from five populations in Spain. SigmaPCB concentrations were found to be in the range 3.2-97 ng/ml, while those of SigmaDDTs ranged from 0.93 to 38 ng/ml. p,p'-DDT/p,p'-DDE ratios higher than one were only found in the Segovia population, which could be an indication of recent use of p,p'-DDT in the area. In all cases, PCB profiles were dominated by congeners 52, 132 + 105, 138, 153 and 180. However, some differences among the five populations studied became evident when their profiles were compared with those of technical PCB mixtures by principal components analysis. The DDT and PCB levels detected in the serums analysed were lower than those previously reported for similar avian species and those reported to have deleterious effects on survival or reproduction of birds. 相似文献
36.
The toxicity of seawater dispersions of a chemical dispersant to two marine crustaceans was investigated in the presence and absence of various quantities of a non-toxic mineral oil. From the results and a physical-chemical partitioning analysis, a limiting value of the oil-water partition coefficient of the toxic compounds is deduced suggesting that essentially all of the toxic compounds in the dispersant will partition into solution in water following dispersant application to an oil spill. This conclusion simplifies interpretation and prediction of the toxic effects of a dispersed oil spill.The combined bioassay-partitioning procedure may have applications to the study of the toxicity of other complex mixtures such as industrial effluents. 相似文献
37.
Evidence for the "grasshopper" effect and fractionation during long-range atmospheric transport of organic contaminants 总被引:11,自引:0,他引:11
Gouin T Mackay D Jones KC Harner T Meijer SN 《Environmental pollution (Barking, Essex : 1987)》2004,128(1-2):139-148
Although there is indisputable evidence that long-range atmospheric transport (LRAT) of organic contaminants occurs on a global scale, uncertainties remain about the detailed mechanism and extent of this phenomenon as well as the physical-chemical properties which facilitate LRAT. In this study, we discuss how mass balance models and monitoring data can contribute to a fuller understanding of the mechanism and extent of LRAT. Specifically we address the issues of "grasshopping" or "hopping" (the extent to which molecules are subject to multiple hops as distinct from a single emission-deposition event) and "global fractionation" (the differing behavior of chemicals as they are transported). It is shown that simple mass balance models can be used to assist the interpretation of monitoring data while also providing an instrument that can be used to assess the LRAT potential and the extent of hopping that organic substances may experience. The available evidence supports the notion that many persistent organic pollutants experience varying degrees of "hopping" during their environmental journey and as a consequence become fractionated with distance from source. 相似文献
38.
MacLeod M Woodfine DG Mackay D McKone T Bennett D Maddalena R 《Environmental science and pollution research international》2001,8(3):156-163
We present the Berkeley-Trent North American contaminant fate model (BETR North America), a regionally segmented multimedia contaminant fate model based on the fugacity concept. The model is built on a framework that links contaminant fate models of individual regions, and is generally applicable to large, spatially heterogeneous areas. The North American environment is modeled as 24 ecological regions, within each region contaminant fate is described using a 7 compartment multimedia fugacity model including a vertically segmented atmosphere, freshwater, freshwater sediment, soil, coastal water and vegetation compartments. Inter-regional transport of contaminants in the atmosphere, freshwater and coastal water is described using a database of hydrological and meteorological data compiled with Geographical Information Systems (GIS) techniques. Steady-state and dynamic solutions to the 168 mass balance equations that make up the linked model for North America are discussed, and an illustrative case study of toxaphene transport from the southern United States to the Great Lakes Basin is presented. Regionally segmented models such as BETR North America can provide a critical link between evaluative models of long-range transport potential and contaminant concentrations observed in remote regions. The continent-scale mass balance calculated by the model provides a sound basis for evaluating long-range transport potential of organic pollutants, and formulation of continent-scale management and regulatory strategies for chemicals. 相似文献
39.
Don C. MacIver 《Environmental monitoring and assessment》1998,49(2-3):177-189
Strategies to conserve biodiversity need to include the monitoring, modelling, adaptation and regulation of the composition of the atmosphere. Atmospheric issues include climate variability and extremes; climate change; stratospheric ozone depletion; acid deposition; photochemical pollution; suspended particulate matter; and hazardous air pollutants. Coarse filter and fine filter approaches have been used to understand the complexity of the interactions between the atmosphere and biodiversity. In the first approach, climate-based models, using GIS technology, helped create future biodiversity scenarios under a 2 × CO2 atmosphere. In the second approach, the SI/MAB forest biodiversity monitoring protocols helped calibrate the climate-forest biodiversity baseline and, as global diagnostics, helped identify where the biodiversity was in equilibrium with the present climate. Forest climate monitoring, an enhancing protocol, was used in a co-location approach to define the thermal buffering capacity of forest ecosystems and their ability to reduce and ameliorate global climate variability, extremes and change. 相似文献
40.
José A. Donázar Alejandro Travaini Olga Ceballos Alejandro Rodríguez Miguel Delibes Fernando Hiraldo 《Behavioral ecology and sociobiology》1999,45(1):55-65
Phenotype-limited interference models assume competitive asymmetries among conspecifics and unequal sharing of resources.
Their main prediction is a correlation between dominance status and patch quality: dominant individuals should preferentially
exploit better-quality habitats. We tested assumptions and predictions of the phenotype-limited interference model in Andean
condors (Vultur gryphus), a New World vulture with strong sexual size dimorphism (males are 30–40% heavier than females). We recorded searching birds
in habitats differing in quality: mountains and plains. We also observed scavenging behaviour at 20 sheep carcasses, and videotaped
5 of them. Intraspecific hierarchy at carcasses was based on size: males dominated females and, within each sex, older birds
dominated younger ones. Adult males and juvenile females occupied extreme positions in the feeding hierarchy. Aggression was
directed at those individuals belonging to lower hierarchical levels. In high-quality areas (mountains), more condors arrived
at carcasses. Juvenile females were more often observed searching in low-quality areas (plains), far from breeding areas and
main roost sites. GLM analyses of individual behaviour showed that the hierarchy did not influence time of arrival, but low-ranking
individuals spent more time at carcasses, especially if the number of condors at arrival was high. Additionally, low-ranking
condors spent less time feeding at carcasses when individuals of higher hierarchical levels were present. On the other hand,
the number of condors present had a positive effect on feeding rates of dominant individuals, probably because of a reduction
in individual vigilance. These results support most of the assumptions and predictions of the phenotype-limited distribution
model, although a spatial truncated distribution between phenotypes was not observed. Asymmetric feeding pay-off, unequal
parental roles and sexual selection constraints could favour sexual divergence in body size in Andean condors.
Received: 6 April 1998 / Accepted after revision: 11 July 1998 相似文献