A Spatially Explicit Model for Estimating Annual Average Loads of Nonpoint Source Nutrient at the Watershed Scale

The overloaded nonpoint source (NPS) nutrients in upper streams always result in the nutrient enrichment at lakes and estuaries downstream. As NPS pollution has become a serious environmental concern in watershed management, the information about nutrient output distribution across a watershed has been critical in the designing of regional development policies. But existing watershed evaluation models often encounter difficulties in application because of their complicated structures and strict requirements for the input data. In this paper, a spatially explicit and process-based model, Integrated Grid’s Exporting and Delivery model, was introduced to estimate annual in-stream nutrient levels. Each grid cell in this model was regarded as having potentials of both exporting new nutrients and trapping nutrients passing by. The combined nutrient dynamics of a grid is mainly determined by the grid’s features in land use/land cover, soil drainage, and geomorphology. This simple-concept model was tested at some basins in north Georgia in the USA. Stations in one basin were used to calibrate the model. Then an external validation was employed by applying the calibrated model to stations in the other neighbor basins. Model evaluation statistics implied the model’s validity and good performance in estimating the annual NPS nutrients’ fluxes at the watershed scale. This study also provides a promising prospect that in-stream annual nutrient loads can be accurately estimated from a few public available datasets.     

Development of Dissolved Oxygen Model for a Highly Variable Flow River: A Case Study of Ravi River in Pakistan

A framework for dissolved oxygen (DO) modeling of the Ravi River has been developed based on a combination of laboratory measurements and field and monitoring data. Both the classical Streeter-Phelps (CSP) and the modified Streeter-Phelps (MSP) models are used for DO simulations. The MSP model considers the carbonaceous biochemical oxygen demand (CBOD) and nitrogenous biochemical oxygen demand (NBOD) separately, whereas the CSP model is evaluated considering only the CBOD and NBOD is incorporated in the overall BOD utilization rate. CBOD, NBOD and BOD rates have been determined through long-term BOD analysis of five main wastewater outfalls and two surface drains discharging into the Ravi River over a 98 km stretch. Analysis by Thomas Method manifests strong coefficient of determination “R²” between 0.72 and 0.98 for all the three types of BOD rates. Sensitivity analyses have also been carried out to find out a suitable reaeration rate formula for highly variable flows in the Ravi River. The CSP model results based on classical approach of considering only CBOD show significant difference between the model predictions and field measurements suggesting that NBOD needs to be incorporated for the model development. The dissolved oxygen values calculated using the MSP model and the CSP model based on overall BOD rate are in close agreement with field measurements and are thus suitable to model DO levels in the Ravi River.     

Mitigation Costs in a Globalized World: Climate Policy Analysis with REMIND-R

Within this paper, we present the novel hybrid model REMIND-R and its application in a climate policy context based on the EU target to avoid a warming of the Earth’s atmosphere by more than 2°C compared to the pre-industrial level. This paper aims to identify necessary long-term changes in the energy system and the magnitude of costs to attain such a climate protection target under different designs of the post-2012 climate policy regime. The regional specification of mitigation costs is analyzed in the context of globalization where regions are linked by global markets for emission permits, goods, and several resources. From simulation experiments with REMIND-R, it turns out that quite different strategies of restructuring the energy system are pursued by the regions. Furthermore, it is demonstrated that the variance of mitigation costs is higher across regions than across policy regimes. First-order impacts, in particular, reduced rents from trade in fossil resources, prevail regardless of the design of the policy regime.     

Comparison of some quality properties of soils around land-mined areas and adjacent agricultural fields

When agricultural lands are no longer used for agriculture and allowed to recover its natural vegetation, soil organic carbon can accumulate in the soil. Measurements of soil organic carbon and aggregate stability changes under various forms of land use are needed for the development of sustainable systems. Therefore, comparison of soil samples taken from both agricultural and nearby area close to land-mined fields where no agricultural practices have been done since 1956 can be a good approach to evaluate the effects of tillage and agriculture on soil quality. The objective of this study was to compare tillage, cropping and no tillage effects on some soil-quality parameters. Four different locations along the Turkey–Syria border were selected to determine effects of tillage and cropping on soil quality. Each location was evaluated separately because of different soil type and treatments. Comparisons were made between non-tilled and non-cropped fallow since 1956 and adjacent restricted lands that were tilled about every 2 years but not planted (T) or adjacent lands tilled and planted with wheat and lentil (P). Three samples were taken from the depths of 0–20 and 20–40 cm each site. Soil organic carbon (SOC), pH ,electrical conductivity, water soluble Ca⁺⁺, Mg⁺⁺, CO₃^-2{\rm CO}_{3}^{-2} and HCO₃^-{\rm HCO}_{3}^{-}, extractable potassium (K⁺) and sodium (Na⁺), soil texture, ammonium (NH₄⁺{\rm NH}_{4}^{+}–N) and nitrate (NO₃–N), extractable phosphorous and soil aggregate stability were determined. While the SOC contents of continuous tillage without cropping and continuous tillage and cropping were 2.2 and 11.6 g kg⁻¹, respectively, it was 30 g kg⁻¹ in non-tilled and non-planted site. Tillage of soil without the input of any plant material resulted in loss of carbon from the soil in all sites. Soil extractable NO₃−N contents of non-tilled and non-cropped sites were greatest among all treatments. Agricultural practices increased phosphorus and potassium contents in the soil profile. P₂O₅ contents of planted soils were approximately 20 to 39 times greater than those of non-tilled and non-cropped soils at different sites. FTIR spectra showed that never tilled sites had greater phenol, carboxylic acid, amide, aromatic compounds, polysaccharide and carbohydrates than other treatments.     

The effects of socioeconomic parameters on household solid-waste generation and composition in developing countries (a case study: Ahvaz,Iran)

Environment problems associated with the generation of waste are part of societal changes where households play an important role. These societal changes influence the size, structure and characteristic of given households. For the effective planning of solid-waste handling infrastructure, it is essential to know the quantity of waste generation and its composition. This paper presents the findings of a study carried out in an urban municipal area in Iran to determine the household solid-waste generation rate and waste composition based on field surveys and to determine the related socioeconomic parameters. The dependent variables were waste generation and composition, and independent variables were family size, family employment, age, number of room and education. Over 400 sample households were selected for the study using a stratified random sampling methodology and from five different socioeconomic groups. Waste collected from all groups of households were segregated and weighted. Waste generation rate was 5.4 kg/household/day. Household solid waste comprised of ten categories of wastes and with the largest component (76.9%). The generation and composition of household solid waste were correlated with family size, education level and households income. This paper adequately suggests new insights concerning the role of socioeconomic parameters in affecting the generation of household waste.     

Speciation of heavy metals in biosolids of wastewater treatment plants at Mysore,Karnataka, India

Urban wastewater treatment leads to the generation of large quantities of biosolids. Accumulation of biosolids is a problem of environmental relevance due to the existence of heavy metals in the biosolids. Determination of total metal in biosolid provides information relating pollution levels. Determination of their mobilization capacity and behaviour in the environment is an important task. An experimental approach commonly used for studying the mobility, transport and bioavailability of metal in biosolids is the use of selective sequential extraction procedure. In the present study an attempt has been made to study the heavy metal properties in biosolid samples collected from urban wastewater treatment plants located at Mysore, Karnataka. Few heavy metals selected for the present study are cadmium, chromium, copper, iron, nickel and zinc. The concentration of these metals in biosolids and their partition in different fractions are studied. The speciation of metals based on the sequential extraction scheme was carried out. The concentration of heavy metals is lower than that established by European legislation. The residual fraction has the maximum percentage of heavy metals whereas, only a small fraction of heavy metals (Fe, Zn and Cd) are extracted in the most soluble fractions, exchangeable and carbonate fractions.     

Heavy metal contamination in the Delhi segment of Yamuna basin

Concentration of heavy metals (Cd, Ni, Zn, Fe, Cu, Mn, Pb, Cr, Hg and As) in the waters of River Yamuna and in the soil of agricultural fields along its course in Delhi are reported from 13 sites, spread through the Delhi stretch of Yamuna, starting from the Wazirabad barrage till the Okhla barrage. Varying concentration of heavy metals was found. Peaks were observed in samples collected downstream of Wazirabad and Okhla barrage, indicating the anthropogenic nature of the contamination. The Wazirabad section of the river receives wastewater from Najafgarh and its supplementary drains, whereas the Shahdara drain releases its pollution load upstream of the Okhla barrage. Average heavy metal concentration at different locations in the river water varied in the order of Fe>Cr>Mn>Zn>Pb>Cu>Ni>Hg>As>Cd. The river basin soil shows higher level of contamination with lesser variation than the water samples among sampling locations, thereby suggesting deposition over long periods of time through the processes of adsorption and absorption. The average heavy metal concentration at different locations in soil varied in the order of Fe>Mn>Zn>Cr>Pb>Ni>Hg>Cu>As>Cd.     

Assessing reliable indicators to sewage pollution in coastal soft-bottom communities

Physicochemical characteristics of sediment and benthic communities were studied in the proximity of seven sewage outfalls with differences in flow and wastewater treatment in the Western Mediterranean Sea. Redox potential was the only abiotic parameter which showed a pattern related with distance to outfalls, whereas granulometry, percentage of organic matter, metal concentrations or pH did not show changes related with outfall presence. Benthic community analysis proved to be the most suitable monitoring tool. The results showed that the highest impacted stations corresponded with those closest to outfall with the highest flow and only pre-treatment, whilst a decrease of this tendency was detected in the locations where secondary treatment takes place. Meta-analysis showed a decrease of amphipods and tanaids abundance as well as redox potential, as the indicators with the clearest response to sewage presence.     

Evaluating the difference between the normalized difference vegetation index and net primary productivity as the indicators of vegetation vigor assessment at landscape scale

Both the net primary productivity (NPP) and the normalized difference vegetation index (NDVI) are commonly used as indicators to characterize vegetation vigor, and NDVI has been used as a surrogate estimator of NPP in some cases. To evaluate the reliability of such surrogation, here we examined the quantitative difference between NPP and NDVI in their outcomes of vegetation vigor assessment at a landscape scale. Using Landsat ETM+ data and a process model, the Boreal Ecosystem Productivity Simulator, NPP distribution was mapped at a resolution of 90 m, and total NDVI during the growing season was calculated in Heihe River Basin, Northwest China in 2002. The results from a comparison between the NPP and NDVI classification maps show that there existed a substantial difference in terms of both area and spatial distribution between the assessment outcomes of these two indicators, despite that they are strongly correlated. The degree of difference can be influenced by assessment schemes, as well as the type of vegetation and ecozone. Overall, NDVI is not a good surrogate of NPP as the indicators of vegetation vigor assessment in the study area. Nonetheless, NDVI could serve as a fairish surrogate indicator under the condition that the target region has low vegetation cover and the assessment has relatively coarse classification schemes (i.e., the class number is small). It is suggested that the use of NPP and NDVI should be carefully selected in landscape assessment. Their differences need to be further evaluated across geographic areas and biomes.     

Water quality evaluation of two interconnected dam lakes with field-captured and laboratory-acclimated fish, <Emphasis Type="BoldItalic">Cyprinus carpio</Emphasis>

Karakaya and Sultansuyu Dam Lakes, located in the eastern part of Turkey, are important water sources, both for irrigation and fishery. The main goal of the study was to investigate water qualities of dam lakes using a set of biomarkers in the fish Cyprinus carpio. For this aim, field sample and laboratory-acclimated fish were compared to identify changes in selected biomarkers. The activities of ethoxyresorufin-O-deethylase, glutathione S-transferase, glutathione reductase, and carboxylesterase were determined in liver samples. Also, plasma and liver lactate dehydrogenase, aspartate aminotransferase, and alanine aminotransferase activities were assayed. Brain acetylcholinesterase and carboxylesterase activities were also determined. The hepatosomatic index and condition factors were calculated. Plasma vitellogenin assays were evaluated for the presence of xenoestrogen. Physicochemical values of water samples showed the existence of eutrophication risk, and also, some chemicals in both lakes were determined to be over tolerable limits. The comparisons of samples from both dam lake and laboratory-acclimated fish showed that the lakes may be at risk of pollution by some xenobiotics, namely xenoestrogens and acetylcholinesterase-inhibiting agents.