经济增长和环境规制对雾霾的区际影响差异

为探究不同省级区域雾霾、经济增长和环境规制之间的空间关联效应,本文提出针对雾霾的引力模型空间权重矩阵,并利用该矩阵建立了空间杜宾模型,分别对全国、西部、中部和东部省区的面板数据进行了空间计量检验。实证结果显示:全国雾霾的莫兰指数值显著,且取值介于0.367—0.460之间;雾霾"重心"呈现先向东南再向西北移动的趋势,移动距离为76 557 m;雾霾的莫兰指数值为东部省区最大,西部省区最小,中部省区介于二者之间。全国的雾霾与经济增长之间呈显著的"U"型曲线,而西部、中部和东部省区则呈倒"U"型曲线,其中中部省区的曲线最为陡峭,西部省区次之,东部省区最为平缓。环境规制每增加1%,只有西部和东部的雾霾相应减少,且各自相应下降0.009和0.010个百分点。西部和东部经济增长的溢出效应均显著,而环境规制的溢出效应不显著。研究结果表明:(1)雾霾在空间上表现出集聚的特点,全国和三个区域的雾霾都存在显著的正向空间溢出效应,这种空间依赖性在时间维度上大致呈加强的趋势;雾霾的空间相关性表现为东部省区最强,西部省区紧随其后,中部省区最低。(2)西部和东部省区部分省市还未过拐点,全国意义上的环境库茨涅兹假说是不存在的,或者是至少还未出现。(3)西部和东部环境规制效果较为理想,而中部省区的环境规制效果不佳;从全国总体来看,当前的环境规制整体上对雾霾并未起到有效的抑制作用。(4)东西部省区和中部省区经济增长对雾霾溢出效应分别表现为正向和反向;环境规制对雾霾的溢出效应并不显著。建议加强对雾霾的区域协同治理,重点推进西部和东部省区经济结构的转型升级,调整和完善西部、中部和东部省区的环境规制政策。     

海上溢油应急处置技术探讨

海上溢油事故不仅给企业造成巨大经济损失,如果处置不当还将引发严重的环境污染事故。文章基于对大连"7.16"及BP"4.20"溢油污染事故处理方法分析,探讨了国内外海上溢油应急技术的发展概况,并结合中国石油企业海上溢油应急建设实际情况,探究了中国石油企业海上溢油应急处置的关键技术问题。为中国石油企业海上溢油应急管理建设和应急技术发展提供参考。     

Major Energy Plants and Their Potential for Bioenergy Development in China

China is rich in energy plant resources. In this article, 64 plant species are identified as potential energy plants in China. The energy plant species include 38 oilseed crops, 5 starch-producing crops, 3 sugar-producing crops and 18 species for lignocellulosic biomass. The species were evaluated on the basis of their production capacity and their resistance to salt, drought, and/or low temperature stress. Ten plant species have high production and/or stress resistance and can be potentially developed as the candidate energy plants. Of these, four species could be the primary energy plants in China: Barbados nut (Jatropha curcas L.), Jerusalem artichoke (Helianthus tuberosus L.), sweet sorghum (Sorghum bicolor L.) and Chinese silvergrass (Miscanthus sinensis Anderss.). We discuss the use of biotechnological techniques such as genome sequencing, molecular markers, and genetic transformation to improve energy plants. These techniques are being used to develop new cultivars and to analyze and manipulate genetic variation to improve attributes of energy plants in China.     

Comparison on gestation and lactation exposure of perfluorinated compounds for newborns

Perfluorinated compounds (PFCs) are worldwide present in the environment and the general population. Animal studies have shown developmental toxicity of these compounds. To investigate the PFCs exposure of neonates from mother during gestation and lactation, we analyzed twelve PFCs in matched maternal serum, cord serum and breast milk samples collected from 50 pairs of women and their newborns between June and July 2009 in Jinhu, China. Eight PFCs were detected in serum samples, and five of them were also detectable in breast milk. A significant intercorrelation between PFCs concentrations in matched maternal serum, cord serum and breast milk was observed (p<0.01, r=0.435-0.911). The median partition ratio was from 0.39:1 (PFDA) to 1.74:1 (PFTrDA) for seven PFCs through the placenta, and was from 0.02:1 (PFOS) to 0.09:1 (PFOA) for five PFCs through the lactation. A high transport efficiency of PFOA both through placental barrier and lactation was observed. The postnatal exposure of PFCs through lactation was higher compared to prenatal exposure, especially for PFOA.     

典型固体可燃物燃烧沉积物微观形貌特征的研究

利用火灾现场中燃烧物沉积物所特有的火灾原始信息,可以帮助火灾调查人员准确辨识与鉴别起火部位或起火点附近可燃物分部情况,辅助判断初始起火材料和起火部位的特点,通过燃烧模拟试验,开展了木材、化纤织物、棉织物、PVC制品、聚氨酯泡沫等常见固体可燃物燃烧沉积物微观形貌特征研究。首先,利用SEM 分析了不同材料沉积物中粒子分布、微观形貌等结构性差异。接着,进行了颗粒物的形貌学测量和组成成分测定。最终,得到了样本的量化差异特征。研究结果表明:5种固体可燃材料燃烧沉积物存在结构性差异,但并不显著;对组成粒子进行的形貌学测量和成分测定,可以量化区分材料属性。该方法可以为建立火灾现场起火部位可燃材料的燃烧时序性提供技术支持。     

天然矿物固硫剂及其对煤粉燃烧的影响

选取CaCO₃、Ca(OH)₂质量配比＝3∶2作为主固硫剂,用钙基固硫剂质量的2％的Na₂CO₃对其改性,利用蛭石作为固硫添加剂。在Ca/S＝2.25的情况下,通过固硫实验考察了主固硫剂以及添加剂的加入对固硫率的影响。实验结果表明,煤粉掺入该固硫剂在950℃下燃烧0.5 h,固硫率可以达到85％。还对添加不同固硫剂的煤粉进行热重实验,分析其对煤粉燃烧特性及动力学参数的影响。结果表明,固硫添加剂的加入不但能提高固硫率,还有利于煤的燃烧,减少灰渣的处理量。     

环境工艺方法论研究——移植嫁接法

移植嫁接法是环境工艺创新中的一种重要方法。本文从环境工艺的角度阐述了移植嫁接法的定义,从学科方法和自然过程移植两方面枚举了该法在环境工艺中的应用成果,在此基础上探讨了移植嫁接法中丰富的哲学内涵。     

The PCDD/F and PBDD/F pollution in the ambient atmosphere of Shanghai, China

Rapid economic growth in the last two decades in Shanghai has had a great adverse influence on its air quality. Therefore, the atmospheric pollutants of Shanghai have received much concern. In this study, concentrations of 2,3,7,8-substituted PCDD/Fs and PBDD/Fs congeners were measured in the ambient air of four districts in Shanghai. The mean atmospheric concentrations (TEQs) of total 2,3,7,8-PCDD/Fs and 2,3,7,8-PBDD/Fs were 8031 fg m(-3) (497.1 fg I-TEQ m(-3)) and 1358 fg m(-3) (304.1 fg I-TEQ m(-3)) for Jiading District, 5308 fg m(-3) (289.0 fg I-TEQ m(-3)) and 709 fg m(-3) (146.9 fg I-TEQ m(-3)) for Zhabei District, 4014 fg m(-3) (144.4 fg I-TEQ m(-3)) and 1239 fg m(-3) (256.9 fg I-TEQ m(-3)) for Pudong District, 3348 fg m(-3) (143.2 fg I-TEQ m(-3)) and 699 fg m(-3) (148.4 fg I-TEQ m(-3)) for Huangpu District, respectively. Our results showed that almost all the PCDD/Fs and PBDD/Fs congeners were partitioned into the particulate phase except the lower chlorinated or brominated ones. The logarithm of the gas/particle partitioning coefficient K(p) has good linear correlation with that of the sub-cooled vapor pressure p(L). Concentrations of PCDD/Fs and PBDD/Fs were both positively correlated to elemental carbon in all districts except Pudong District, suggesting elemental carbon could be a good indicator for dioxins' air pollution. It is intensively suggested that more detailed and deeper studies about PBDD/Fs should be carried out due to their relatively high atmospheric concentrations in Shanghai.     

The accumulation of nonylphenol in a wastewater recycling process

A mathematical model was developed in this paper to describe the nonylphenol (NP) accumulation in the effluent of a wastewater recycling system. The model quantitatively presented the relationships among the NP concentrations in the raw wastewater and the system effluent, the number of wastewater recycling cycles, the water recycling ratio, the system NP removal efficiency, and the NP accumulation factor. The mathematical model was then verified through experimental modeling of a wastewater recycling process, and it was indicated that the Pearson correlation coefficient between mathematical simulation and experimental modeling results was 0.652. The study results indicated that the NP accumulation factor of a wastewater recycling system would approach a constant for large number of wastewater recycling cycles given the wastewater recycling ratio and system NP removal efficiency. The results also revealed that the NP concentration in the effluent increased with the wastewater recycling ratio given the system NP removal efficiency, and the increase of NP removal efficiency would decrease the NP accumulation in the system effluent under a given wastewater recycling ratio condition. The model was then applied to compute the maximum wastewater recycling ratio, predict reclaimed water quality and direct the design and management of sewage recycling systems in China.