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41.
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43.
Andreas Züttel 《Mitigation and Adaptation Strategies for Global Change》2007,12(3):343-365
Hydrogen storage and transportation or distribution is closely linked together. Hydrogen can be distributed continuously in
pipelines or batch wise by ships, trucks, railway or airplanes. All batch transportation requires a storage system but also
pipelines can be used as pressure storage system. Hydrogen exhibits the highest heating value per weight of all chemical fuels.
Furthermore, hydrogen is regenerative and environment friendly. There are two reasons why hydrogen is not the major fuel of
toady’s energy consumption: First of all, hydrogen is just an energy carrier. And, although it is the most abundant element
in the universe, it has to be produced, since on earth it only occurs in the form of water. This implies that we have to pay
for this energy, which results in a difficult economic task, because since the industrialization we are used to consuming
energy for free. The second difficulty with hydrogen as an energy carrier is the low critical temperature of 33 K, i.e. hydrogen
is a gas at room temperature. For mobile and in many cases also for stationary applications the volumetric and gravimetric
density of hydrogen in a storage system is crucial. Hydrogen can be stored by six different methods and phenomena: high pressure
gas cylinders (up to 800 bar), liquid hydrogen in cryogenic tanks (at 21 K), adsorbed hydrogen on materials with a large specific
surface area (at T < 100 K), absorbed on interstitial sites in a host metal (at ambient pressure and temperature), chemically bond in covalent
and ionic compounds (at ambient pressure), oxidation of reactive metals e.g. Li, Na, Mg, Al, Zn with water. These metals easily
react with water to the corresponding hydroxide and liberate the hydrogen from the water. Finally, the metal hydroxides can
be thermally reduced to the metals in a solar furnace. 相似文献
44.
An Application of a Modified Ecological Footprint Method and Structural Path Analysis in a Comparative Institutional Study 总被引:1,自引:0,他引:1
This paper presents an application of a modified ecological footprint method, using a regional, disturbance-based approach. In contrast to conventional institutional ecological footprint calculations, energy and land use resulting from all upstream production processes are explored by employing an input-output framework. Ecological footprints are calculated for two research institutions: the School of Physics (SoP) at the University of Sydney, and the Sustainable Ecosystems (CSE) Department of the Commonwealth Scientific and Industrial Research Organisation. These are broken down further in terms of land disturbance and greenhouse gas emissions, and as a function of production layer. To enable the use of the results in policy formulation, the ecological footprints are decomposed into detailed contributing paths, which are ranked according to their importance, using structural path analysis. The paper demonstrates that a considerable proportion of impacts occur upstream in industrial production. Thus a significant result of the study is the weight of obscure paths in the total footprints and, therefore, the importance of conducting an holistic assessment in order to ensure all upstream contributions are captured in the final impact of the institution. 相似文献
45.
FUENSANTA CARAVACA DINO FIGUEROA ANTONIO ROLDÁn CONCEPCIÓN AZCÓN-AGUILAR 《Environmental management》2003,31(3):0412-0420
The reestablisment of autochthonous plant species is an essential strategy for recovering degraded areas under semiarid conditions.
A field experiment was carried out to assess the short-term effect of two reafforestation methods involving mycorrhizal inoculation
and compost addition on soil quality parameters and Rhamnus lycioides seedling growth. The nutrient content (NPK) and enzymatic activities (dehydrogenase, urease, protease-BAA, acid phosphatase
and β-glucosidase) increased and bulk density decreased in the rhizosphere soil with the organic amendment. Biomass C of rhizosphere
soil increased by at least 240% with respect to the control soil after mycorrhizal inoculation and the combination of compost
addition + mycorrhizal inoculation. Both mycorrhizal inoculation and composted organic residue addition increased R. lycioides seedling growth in the same proportion. In the short term, we conclude that the application of both reafforestation methods
not only enhances the establishment of R. lycioides seedlings, but also improves soil quality. 相似文献
46.
Götz R Bauer OH Friesel P Herrmann T Jantzen E Kutzke M Lauer R Paepke O Roch K Rohweder U Schwartz R Sievers S Stachel B 《Chemosphere》2007,67(3):592-603
Concentrations of polychlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs) and other organic micropollutants were determined in dated sediment/soil cores collected from the flood-plain of the river Elbe near Pevestorf (PT), approximately 125 km upstream of Hamburg, and Heuckenlock (HL) in southeast of Hamburg. Concentrations of PCDD/Fs peaked sharply at PT in the 1950s and at HL at the end of the 1940s. Cluster analyses provide evidence that the region of Bitterfeld-Wolfen (about 350-400 km upstream of Hamburg) could be the source of the PCDD/F contamination existing in the cores PT and HL since the 1940s. Obviously it is caused by sediments of the river Elbe of a similar composition. Whereas the PCDD/Fs, HCHs (hexacyclohexane isomers), DDX (DDT, DDD, DDE), and tetrachlorinated ethers in PT and HL presumably originated predominantly from the Bitterfeld-Wolfen region, organotin compounds in HL and dichlorinated haloethers in HL during the 1940s and 1950s can probably largely be attributed to emissions from the Hamburg region. Although they are separated by a large distance, in both sediment cores PT and HL concentrations and composition patterns of most organic micropollutants analyzed widely match. Inductively it can be concluded that similar contaminations will be found in many of the river bank soils between the Bitterfeld-Wolfen region and Hamburg. Excavation of top soils may uncover highly contaminated materials. Since the dated sediment cores show the variation in contaminants in the Elbe sediments over a defined time period, it is possible to make an approximate assessment of the actual degree of contamination to be expected in areas where in previous decades contaminated dredged sediments from the Elbe and from the Port of Hamburg have been deposited on land and used for building plots or for agricultural purposes. 相似文献
47.
Variations between rice cultivars in root secretion of organic acids and the relationship with plant cadmium uptake 总被引:13,自引:0,他引:13
To attempt to understand certain mechanisms causing the variations between rice cultivars with regard to Cd uptake and accumulation,
pot soil experiments were conducted with two rice cultivars at different levels of Cd, i.e., 0 (the control), 10, 50 mg Cd
kg−1 soil. The two rice cultivars differ significantly with regard to Cd uptake and accumulation. Root secretions of low-molecular-weight
organic acids (LMWOA) for each treatment were measured with ion chromatography. The results showed that LMWOA concentrations
in the soil planted with Shan you 63 (a high soil Cd accumulator) were all higher than those in the soil planted with Wu yun jing 7 (low soil Cd accumulator) at different soil Cd levels, although the magnitudes of the differences varied for individual LMWOA
and depend on soil Cd concentrations. For all six LMWOA, there were significant differences at P < 0.05 or < 0.01 levels for soils treated with 10 and 50 mg kg−1 Cd. The magnitude of the differences was greater under soil Cd treatments, especially at relatively low levels (for example,
10 mg Cd kg−1 soil), than in the control. Acetic acid and formic acid constituted more than 96% of the total concentration of the six LMWOA,
while citric acid constituted only about 0.1%. The rice cultivar with higher concentrations of LMWOA in soil accumulated more
Cd in the plants. The results indicate that LMWOA secretion by rice root, especially in Cd-contaminated soils, is likely to
be one of the mechanisms determining the plant Cd uptake properties of rice cultivars. 相似文献
48.
A review of the distribution of particulate trace elements in urban terrestrial environments and its application to considerations of risk 总被引:6,自引:0,他引:6
We review the evolution, state of the art and future lines of research on the sources, transport pathways, and sinks of particulate
trace elements in urban terrestrial environments to include the atmosphere, soils, and street and indoor dusts. Such studies
reveal reductions in the emissions of some elements of historical concern such as Pb, with interest consequently focusing
on other toxic trace elements such as As, Cd, Hg, Zn, and Cu. While establishment of levels of these elements is important
in assessing the potential impacts of human society on the urban environment, it is also necessary to apply this knowledge
in conjunction with information on the toxicity of those trace elements and the degree of exposure of human receptors to an
assessment of whether such contamination represents a real risk to the city’s inhabitants and therefore how this risk can
be addressed. 相似文献
49.
We present a new system for microscopic multicolour variable chlorophyll fluorescence imaging of aquatic phototrophs. The
system is compact and portable and enables microscopic imaging of photosynthetic performance of individual cells and chloroplasts
using different combinations of blue, green, red or white light. Automated sequential exposure of microscopic samples to the
three excitation colours enables subsequent deconvolution of the resulting fluorescence signals and colour marking of cells
with different photopigmentation, i.e., cyanobacteria, green algae, red algae and diatoms. The photosynthetic activity in
complex mixtures of phototrophs and natural samples can thus be assigned to different types of phototrophs, which can be quantified
simultaneously. Here, we describe the composition and performance of the new imaging system and present applications with
both natural phytoplankton and microalgal culture samples. 相似文献
50.
Photo-polymerization of triclosan in aqueous solution induced by ultraviolet radiation 总被引:1,自引:0,他引:1
The formation of 2,8-dichlorodibenzo-p-dioxin and other harmful degradation products in the photo-degradation process of triclosan is of increasing concern. Here we worked on the identification of polymerized products at high triclosan concentration and on the mechanism of photoreaction. Five dimmers and two trimers of triclosan were detected by liquid chromatography-mass spectrum analysis. 2,8-dichlorodibenzo-p-dioxin was also identified by comparing with an authentic standard. Relatively low pH and high concentration favored the polymerization of triclosan. Three main routes of photoreaction were postulated, namely dechlorination, ring closure and polymerization. 相似文献