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321.
  总被引:1,自引:0,他引:1  
A measure of soil P status in agricultural soils is generally required for assisting with prediction of potential P loss from agricultural catchments and assessing risk for water quality. The objectives of this paper are twofold: (i) investigating the soil P status, distribution, and variability, both spatially and with soil depth, of two different first-order catchments; and (ii) determining variation in soil P concentration in relation to catchment topography (quantified as the \"topographic index\") and critical source areas (CSAs). The soil P measurements showed large spatial variability, not only between fields and land uses, but also within individual fields and in part was thought to be strongly influenced by areas where cattle tended to congregate and areas where manure was most commonly spread. Topographic index alone was not related to the distribution of soil P, and does not seem to provide an adequate indicator for CSAs in the study catchments. However, CSAs may be used in conjunction with soil P data for help in determining a more \"effective\" catchment soil P status. The difficulties in defining CSAs a priori, particularly for modeling and prediction purposes, however, suggest that other more \"integrated\" measures of catchment soil P status, such as baseflow P concentrations or streambed sediment P concentrations, might be more useful. Since observed soil P distribution is variable and is also difficult to relate to nationally available soil P data, any assessment of soil P status for determining risk of P loss is uncertain and problematic, given other catchment physicochemical characteristics and the sampling strategy employed.  相似文献   
322.
A surface drinking water monitoring program for four corn (Zea mays L.) herbicides was conducted during 1995-2001. Stratified random sampling was used to select 175 community water systems (CWSs) within a 12-state area, with an emphasis on the most vulnerable sites, based on corn intensity and watershed size. Finished drinking water was monitored at all sites, and raw water was monitored at many sites using activated carbon, which was shown capable of removing herbicides and their degradates from drinking water. Samples were collected biweekly from mid-March through the end of August, and twice during the off-season. The analytical method had a detection limit of 0.05 microg L(-1) for alachlor [2-chloro-N-(2,6-diethylphenyl)-N-(methoxymethyl)-acetamide] and 0.03 microg L(-1) for acetochlor [2-chloro-N-(ethoxymethyl)-N-(2-ethyl-6-methylphenyl)-acetamide], atrazine [6-chloro-N-ethyl-N'-(1-methylethyl)-1,3,5-triazine-2,4-diamine], and metolachlor [2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl)-acetamide]. Of the 16528 drinking water samples analyzed, acetochlor, alachlor, atrazine, and metolachlor were detected in 19, 7, 87, and 53% of the samples, respectively. During 1999-2001, samples were also analyzed for the presence of six major degradates of the chloroacetanilide herbicides, which were detected more frequently than their parent compounds, despite having higher detection limits of 0.1 to 0.2 microg L(-1). Overall detection frequencies were correlated with product use and environmental fate characteristics. Reservoirs were particularly vulnerable to atrazine, which exceeded its 3 microg L(-1) maximum contaminant level at 25 such sites during 1995-1999. Acetochlor annualized mean concentrations (AMCs) did not exceed its mitigation trigger (2 microg L(-1)) at any site, and comparisons of observed levels with standard measures of human and ecological hazards indicate that it poses no significant risk to human health or the environment.  相似文献   
323.
Collaboration has taken root in national forest planning, providing expanded opportunities for stakeholder participation in decision-making, but are these processes considered meaningful by key stakeholders? Do the processes result in increased participation by key stakeholders? We present results of a study of stakeholder perspectives of a collaborative planning process on the Grand Mesa, Uncompahgre, and Gunnison National Forests in Western Colorado, U.S.A. The stakeholders were stratified by participation levels in order to explore a possible relationship between participation and perceptions of the collaborative process. We used a Q-methodology approach to compare and contrast perspectives across participant levels in the North Fork Valley Landscape Working Group process. The results demonstrate four distinct perspectives on the collaborative process: 1) The collaborative process is valued by the Forest Service and will directly influence planning decisions; 2) The Forest Service, the collaborative process, and other stakeholders are not to be trusted; 3) The collaborative process is most effective when emphasizing place-specific dialogue that primarily involves stakeholders educating the Forest Service about issues; and 4) Forest planning involves issues requiring the application of scientific knowledge and expertise rather than collaboration. These perspectives were not strongly associated with participation levels, with time constraint being the primary mediating factor affecting participation. There are several possible actions policymakers and planners can take to enhance participation and overcome high rates of nonparticipation.  相似文献   
324.
This work builds on a previous study of long-term tillage trials that found use of no-tillage (NT) practices increased soil organic carbon (SOC) sequestration at Monmouth, IL (silt loam soil) by increasing the soil's protective capacity, but did not alter SOC storage in DeKalb, IL (silty clay loam), where higher clay contents provided a protective capacity not affected by tillage. The least limiting water range (LLWR), a multi-factor index of structural quality, predicted observed soil CO2 efflux patterns. Here we consider whether LLWR can predict sequestration trends at a third site, Perry, IL (silt loam soil) where SOC content is lower and bulk density is higher than in previously considered sites, and determine whether pore size characteristics can help explain the influence use of NT practices has had on SOC sequestration at all three locations. At Perry, LLWR was again related with differences in specific soil organic carbon mineralization rates (RESPsp) (2000-2001). Reduced RESPsp rates explain increases in SOC storage under NT management observed only after 17 yr. Trends in RESPsp suggest use of NT practices only enhance physical protection of SOC where soil bulk density is relatively high (approximately 1.4 g cm(-3)). In those soils (Monmouth and Perry), use of NT management reduced the volume of small macropores (15-150 microm) thought to be important for microbial activity. Physical properties appear to determine whether or not use of NT practices will enhance C storage by increasing physical protection of SOC. By refining the functions used to compute the LLWR and our understanding of the interactions between management, pore structure, and SOC mineralization, we should be able to predict the influence of tillage practices on SOC sequestration.  相似文献   
325.
Sand-sized particles (>63 microm) in whole storm water samples collected from urban runoff have the potential to produce data with substantial bias and/or poor precision both during sample splitting and laboratory analysis. New techniques were evaluated in an effort to overcome some of the limitations associated with sample splitting and analyzing whole storm water samples containing sand-sized particles. Wet-sieving separates sand-sized particles from a whole storm water sample. Once separated, both the sieved solids and the remaining aqueous (water suspension of particles less than 63 microm) samples were analyzed for total recoverable metals using a modification of USEPA Method 200.7. The modified version digests the entire sample, rather than an aliquot, of the sample. Using a total recoverable acid digestion on the entire contents of the sieved solid and aqueous samples improved the accuracy of the derived sediment-associated constituent concentrations. Concentration values of sieved solid and aqueous samples can later be summed to determine an event mean concentration.  相似文献   
326.
In this study, the Tsunami-caused deterioration of soil and groundwater quality in the agricultural fields of coastal Nagapattinam district of Tamilnadu state in India is presented by analyzing their salinity and sodicity parameters. To accomplish this, three sets of soil samples up to a depth of 30cm from the land surface were collected for the first six months of the year 2005 from 28 locations and the ground water samples were monitored from seven existing dug wells and hand pumps covering the study region at intervals of 3 months. The EC and pH values of both the soil and ground water samples were estimated and the spatial and temporal variability mappings of these parameters were performed using the geostatistical analysis module of ArcGIS((R)). It was observed that the spherical semivariogram fitted well with the data set of both EC and pH and the generated kriged maps explained the spatial and temporal variability under different ranges of EC and pH values. Further, the recorded EC and pH data of soil and ground water during pre-Tsunami periods were compared with the collected data and generated variability soil maps of EC and pH of the post-Tsunami period. It was revealed from this analysis that the soil quality six months after the Tsunami was nearing the pre-Tsunami scenario (EC< 1.5dSm(-1); pH<8), whereas the quality of ground water remained highly saline and unfit for irrigation and drinking. These observations were compared with the ground scenarios of the study region and possible causes for such changes and the remedial measures for taking up regular agricultural practices are also discussed.  相似文献   
327.
328.
The ecosystem services (ES) concept is being increasingly incorporated into environmental policy formulation and management approaches. The Corporate Ecosystem Services Review (ESR) is a framework used to assess the dependence and impact that a business has on ES. The success of the corporate experience of ES assessment provides an opportunity for adaption for local authority decision making. In this paper, the ESR tool was adapted to the South African setting at a local government level, and tested at two sites in the Msunduzi Municipality, KwaZulu-Natal. In testing the tool and gathering feedback from key stakeholders, it was found that there are both opportunities and challenges to this approach. Overall, however, it provides an opportunity for the systematic inclusion of ES assessment into existing regulatory frameworks for land-use planning and Integrated Environmental Management, whether in a strategic application, at a broader spatial (municipal) scale or in a specific locale within the municipality.  相似文献   
329.
330.
ABSTRACT: The applicability of the U.S Environmental Protection Agency's (USEPA) water temperature criteria in evaluating the impact of a thermal discharge from the P. H. Glatfelter Paper Company, Spring Grove, Pennsylvania, is analyzed. A review of the literature relative to 11 temperature Criteria was conducted for six fish species designated by the USEPA as “representative important species” (RIS) of the West Branch Codorus Creek, Susquehanna River drainage. The species were: Notemigonus crysolcucas (golden shiner), Notropis analostanus (satinfin shiner), Rhinichthys atratulus (blacknose dace), Catostomus comme-soni (white sucker), Lepomis gibbosus (pumpkinseed). and Micropterous salmoides (largemouth bass). It was found that by applying only USEPA suggested criteria that a complete evaluation was not satisfactory. Temperature behavior data, specifically preference and avoidance information, coupled with field sampliug was needed to properly assess the effects of the thermal effluent. The final analysis indicated that the thermal discharge of the paper company should have minimal effect on the fish community of Codorus Creek.  相似文献   
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