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191.
Linqiang Mao Hao Cui Chenchen Miao Hao An Jianping Zhai Qin Li 《Journal of Material Cycles and Waste Management》2016,18(3):573-581
This paper presents a study regarding the preparation of MgCr2O4 from waste tannery solution, and chromium leaching behavior is also investigated with varying amounts of sulfate, chloride and calcium. The phase transformation, crystallinity index and crystallite diameter were characterized using XRD, FT-IR and thermal analysis. A well-crystallized MgCr2O4 was successfully prepared at 1400 °C. The sintering temperature had a major impact on the formation of MgCr2O4 compared with sintering time. The MgCr2O4 phase was observed initially at 400 °C and its crystallite diameter increased with increasing temperature. The concentration of total chromium leached and Cr(VI) decreased gradually with increasing temperature. The considerable amount of Cr(VI) was found in the leachate at 300–500 °C caused by Cr(VI) intermediary products. Sulfate and chlorine could impact the transformation efficiency of chromium adversely, and chlorine has a more significant effect than sulfate. The presence of calcium disturbed the formation of MgCr2O4 and new chromium species (CaCrO4) appeared, which resulted in a sharp increase in the concentration of leached Cr(VI). Incorporating Cr(III) into the MgCr2O4 spinel for reusable products reduced its mobility significantly. This was demonstrated to be a promising strategy for the disposal of chromium containing waste resource. 相似文献
192.
Jingqiu Mao Xinrong Ren Shuang Chen William H. Brune Zhong Chen Monica Martinez Hartwig Harder Barry Lefer Bernhard Rappenglück James Flynn Michael Leuchner 《Atmospheric environment (Oxford, England : 1994)》2010,44(33):4107-4115
Both similarities and differences in summertime atmospheric photochemical oxidation appear in the comparison of four field studies: TEXAQS2000 (Houston, 2000), NYC2001 (New York City, 2001), MCMA2003 (Mexico City, 2003), and TRAMP2006 (Houston, 2006). The compared photochemical indicators are OH and HO2 abundances, OH reactivity (the inverse of the OH lifetime), HOx budget, OH chain length (ratio of OH cycling to OH loss), calculated ozone production, and ozone sensitivity. In terms of photochemical activity, Houston is much more like Mexico City than New York City. These relationships result from the ratio of volatile organic compounds (VOCs) to nitrogen oxides (NOx), which are comparable in Houston and Mexico City, but much lower in New York City. Compared to New York City, Houston and Mexico City also have higher levels of OH and HO2, longer OH chain lengths, a smaller contribution of reactions with NOx to the OH reactivity, and NOx-sensitivity for ozone production during the day. In all four studies, the photolysis of nitrous acid (HONO) and formaldehyde (HCHO) are significant, if not dominant, HOx sources. A problematic result in all four studies is the greater OH production than OH loss during morning rush hour, even though OH production and loss are expected to always be in balance because of the short OH lifetime. The cause of this discrepancy is not understood, but may be related to the under-predicted HO2 in high NOx conditions, which could have implications for ozone production. Three photochemical indicators show particularly high photochemical activity in Houston during the TRAMP2006 study: the long portion of the day for which ozone production was NOx-sensitive, the calculated ozone production rate that was second only to Mexico City's, and the OH chain length that was twice that of any other location. These results on photochemical activity provide additional support for regulatory actions to reduce reactive VOCs in Houston in order to reduce ozone and other pollutants. 相似文献
193.
In this research, which takes the ‘12.23’ Kaixian blowout accident in Chongqing as an example, firstly the basic information of the accident, including the affected area, the accident process and the accident consequences, was described. Secondly, the development of the accident and other correlative things were researched in detail, especially the monitoring result of concentrations of toxic gases at different times. Thirdly, the blowout accident was categorized into three stages, and the causes of each stage were analyzed in depth together with the events and causal factors charting. Lastly, the profound problems exposed in the disaster were thoroughly discussed. The analysis on ‘12.23’ Kaixian blowout accident indicates that deficiencies in the proper understanding of the hazards by the crew/management as well as inadequacies in risk assessment, management, and the absence of effective countermeasures resulted in the loss of lives. 相似文献
194.
2004年,国家安全监管局印发了《关于开展安全质量标准化活动的指导意见》,煤矿、非煤矿山、危险化学品、烟花爆竹、冶金、机械等行业均 相似文献
195.
Mao Xinyou Wang Lan Gu Shiqing Duan Yanyan Zhu Yunqing Wang Chuanyi Lichtfouse Eric 《Environmental Chemistry Letters》2018,16(2):653-658
Environmental Chemistry Letters - Water pollution caused by heavy metals has dramatically impacted ecosystems in recent years. For instance, 45.4% of lakes in China are in the category of moderate... 相似文献
196.
为研究套箍法加固RC偏压柱的承载力实用计算方法,利用29根加固柱的试验资料,对《混凝土结构加固设计规范》GB 50367—2013和GB 50367—2006的承载力计算方法进行了研究,将试件承载力计算值与实测值进行对比发现,两部规范的承载力计算结果比较接近,计算结果的整体准确性都不够好、偏于不安全,尤其对大偏压柱的承载力计算较为不安全。根据加固柱的受力破坏特性,定义了3种破坏极限状态,基于3种极限状态下的截面应变分布分析,建立了加固柱的承载力计算公式,验证表明,该公式的计算结果与试验结果吻合较好,且偏于安全。 相似文献
197.
We investigated the efficiency and kinetics of the degradation of soluble dyes over the p H range 5.0–9.0 using a method employing microwave radiation in combination with nanoscale zero-valent iron(MW–n ZVI). The n ZVI particles(40–70 nm in diameter) were prepared by a liquid-phase chemical reduction method employing starch as a dispersant.Compared to the removal of Solvent Blue 36 and Reactive Yellow K-RN using only n ZVI,more rapid and efficient dye removal and total organic carbon removal were achieved using MW–n ZVI. The dye removal efficiency increased significantly with decreasing p H, but was negligibly affected by variation in the microwave power. The kinetics of dye removal by MW–n ZVI followed both an empirical equation and the pseudo first-order model, while the kinetics of dye removal using n ZVI could only be described by an empirical equation. It was also concluded that microwave heating of the dye solutions as well as acceleration of corrosion of n ZVI and consumption of Fe(II) were possible reasons behind the enhanced dye degradation. 相似文献
198.
Photodegradation(PD) of methylmercury(MMHg) is a key process of mercury(Hg) cycling i water systems, maintaining MMHg at a low level in water systems. However, we posses little knowledge of this important process in the Jialing River of Chongqing, China. In sit incubation experiments were thus performed to measure temporal patterns and influencin factors of MMHg PD in this river. The results showed that MMHg underwent a ne demethylation process under solar radiation in the water column, which predominantl occurred in surface waters. For surface water, the highest PD rate constants were observed i spring(12 × 10-3± 1.5 × 10~(-3)m~2/E), followed by summer(9.0 × 10~(-3)± 1.2 × 10~(-3)m~2/E), autum(1.4 × 10~(-3)± 0.12 × 10~(-3)m~2/E), and winter(0.78 × 10~(-3)± 0.11 × 10~(-3)m~2/E). UV-A radiatio(320–400 nm), UV-B radiation(280–320 nm), and photosynthetically active radiation(PAR400–700 nm) accounted for 43%–64%, 14%–31%, and 16%–45% of MMHg PD, respectively. PD rat constants varied substantially with the treatments that filtered the river water and amended with chemicals(i.e., Cl-, NO_3~-, dissolved organic matter(DOM), Fe(III)), which reveals tha suspended particulate matter and water components are important factors in affecting the PD process. For the entire water column, the PD rate constant determined for each wavelengt range decreased rapidly with water depth. UV-A, UV-B, and PAR contributed 27%–46%, 6.2%12%, and 42%–65% to the PD process, respectively. PD flux was estimated to be 4.7 μg/(m~2·yea in the study site. Our results are very important to understand the cycling characteristics o MMHg in the Jialing River of Chongqing, China. 相似文献
199.
在依据出口能力不同对中国工业行业进行分类的基础上,利用灰色关联分析,定量比较了出口能力不同工业行业对环境污染的影响差异;通过构造环境影响系数,分析了依出口能力差异划分的工业结构变动对环境污染的影响趋势。研究表明,中国出口能力强的工业行业对环境污染影响较大,目前的工业行业出口能力结构变动趋势对环境污染有减轻迹象,适度降低工业行业结构中出口能力强行业的比重,有助于减轻中国环境污染压力。 相似文献
200.
To evaluate decolorization and detoxification of Azure B dye by a newly isolated Bacillus sp. MZS10 strain, the cultivation medium and decolorization mechanism of the isolate were investigated. The decolorization was discovered to be dependent on cell density of the isolate and reached 93.55%(0.04 g/L) after 14 hr of cultivation in a 5 L stirred-tank fermenter at 2.0 g/L yeast extract and 6.0 g/L soluble starch and a small amount of mineral salts. The decolorization metabolites were identified with ultra performance liquid chromatography-tandem mass spectroscopy(UPLC-MS). A mechanism for decolorization of Azure B was proposed as follows: the C=N in Azure B was initially reduced to –NH by nicotinamide adenine dinucleotide phosphate(NADPH)-dependent quinone dehydrogenase, and then the –NH further combined with –OH derived from glucose to form a stable and colorless compound through a dehydration reaction. The phytotoxicity was evaluated for both Azure B and its related derivatives produced by Bacillus sp. MZS10 decolorization, indicating that the decolorization metabolites were less toxic than original dye. The decolorization efficiency and mechanism shown by Bacillus sp. MZS10 provided insight on its potential application for the bioremediation of the dye Azure B. 相似文献