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91.
92.
Serum concentrations of perfluorooctanesulfonate and other fluorochemicals in an elderly population from Seattle, Washington 总被引:14,自引:0,他引:14
Olsen GW Church TR Larson EB van Belle G Lundberg JK Hansen KJ Burris JM Mandel JH Zobel LR 《Chemosphere》2004,54(11):1599-1611
Perfluorooctanesulfonyl fluoride (POSF, C8F17SO2F) related-materials have been used as surfactants, paper and packaging treatments, and surface (e.g., carpet, textile, upholstery) protectants. A metabolite, perfluorooctanesulfonate (PFOS, C8F17SO3−), has been identified in the serum and liver of non-occupationally exposed humans and wildlife. Because of its persistence, an important question was whether elderly humans might have higher PFOS concentrations. From a prospective study designed to examine cognitive function in the Seattle (WA) metropolitan area, blood samples were collected from 238 dementia-free subjects (ages 65–96). High-pressure liquid chromatography-electrospray tandem mass spectrometry determined seven fluorochemicals: PFOS; N-ethyl perfluorooctanesulfonamidoacetate; N-methyl perfluorooctanesulfonamidoacetate; perfluorooctanesulfonamidoacetate; perfluorooctanesulfonamide; perfluorooctanoate; and perfluorohexanesulfonate. Serum PFOS concentrations ranged from less than the lower limit of quantitation (3.4 ppb) to 175.0 ppb (geometric mean 31.0 ppb; 95% CI 28.8–33.4). An estimate of the 95% tolerance limit was 84.1 ppb (upper 95% confidence limit 104.0 ppb). Serum PFOS concentrations were slightly lower among the most elderly. There were no significant differences by sex or years residence in Seattle. The distributions of the other fluorochemicals were approximately an order of magnitude lower. Similar to other reported findings of younger adults, the geometric mean serum PFOS concentration in non-occupational adult populations likely approximates 30–40 ppb with 95% of the population’s serum PFOS concentrations below 100 ppb. 相似文献
93.
S. Isari S. Psarra P. Pitta P. Mara M. O. Tomprou A. Ramfos S. Somarakis A. Tselepides C. Koutsikopoulos N. Fragopoulu 《Marine Biology》2007,151(3):1035-1050
Mesozooplankton group composition was examined in the Northeastern Aegean Sea (NEA) over a grid of 30 stations sampled during
July 2004. The surface water layer influenced by the low salinity Black Sea waters (BSW) is considered in this paper. We attempted
to study horizontal distribution patterns of major mesozooplankters within a more comprehensive framework, taking into account
not only hydrology but also available, concurrently collected data on lower trophic levels (autotrophic and microbial heterotrophic
communities). BSW was mainly restricted in the eastern part of the surveyed area where it was entrapped in a ca. 50-km wide
anticyclone (the “Samothraki” gyre). High Chlα concentrations, autotrophic biomass as well as abundance and biomass of mesozooplankton were associated with the BSW, with
the highest values recorded inside the gyre as well as at its coastal northern periphery and the lowest values towards the
western and offshore part of the surveyed area characterized by high salinity waters of Levantine origin. Among mesozooplankters,
cladocerans (mainly Penilia avirostris) showed a high abundance within the gyre in contrast to the very low abundance of copepods and appendicularians. Low salinity-high
temperature gyre waters were characterized by the dominance of cyanobacteria of the genus Synechococcus in autotrophic biomass and the significant contribution of heterotrophic nanoflagellates in microbial heterotrophic biomass.
Based on existing knowledge on ecophysiological traits and prey size-spectra selectivity, we discuss the observed distribution
patterns of major mesozooplankton groups in terms of ambient abiotic parameters and the possible biological interactions among
these groups as well as with lower or upper trophic levels. 相似文献
94.
Ruiz-Pérez M Almeida M Dewi S Costa EM Pantoja MC Puntodewo A de Postigo AA de Andrade AG 《Ambio》2005,34(3):218-223
Extractive reserves constitute an innovative approach to match conservation and development objectives, which were originally envisaged as part of a land struggle by forest dwellers in Brazil. In spite of the idea's popularity and the attempts to apply the concept to different tropical regions, there has been little analysis of the combined conservation and development performance of extractive reserve programs. We present a detailed analysis of deforestation and demographic and socioeconomic changes in Alto Juruá, the first extractive reserve created in Brazil in 1990. Forest cover has remained fairly stable. Population has declined slightly, with some internal displacements. The cash economy base has shifted from the original rubber production to a diversified portfolio of agriculture and livestock, and there has been a dramatic rise in nonagrarian income. We conclude that the Reserve represents a very dynamic setting with positive conservation and development outcomes during its first decade. 相似文献
95.
Watershed-Based Survey Designs 总被引:2,自引:0,他引:2
Detenbeck NE Cincotta D Denver JM Greenlee SK Olsen AR Pitchford AM 《Environmental monitoring and assessment》2005,103(1-3):59-81
Watershed-based sampling design and assessment tools help serve the multiple goals for water quality monitoring required under
the Clean Water Act, including assessment of regional conditions to meet Section 305(b), identification of impaired water
bodies or watersheds to meet Section 303(d), and development of empirical relationships between causes or sources of impairment
and biological responses. Creation of GIS databases for hydrography, hydrologically corrected digital elevation models, and
hydrologic derivatives such as watershed boundaries and upstream–downstream topology of subcatchments would provide a consistent
seamless nationwide framework for these designs. The elements of a watershed-based sample framework can be represented either
as a continuous infinite set defined by points along a linear stream network, or as a discrete set of watershed polygons.
Watershed-based designs can be developed with existing probabilistic survey methods, including the use of unequal probability
weighting, stratification, and two-stage frames for sampling. Case studies for monitoring of Atlantic Coastal Plain streams,
West Virginia wadeable streams, and coastal Oregon streams illustrate three different approaches for selecting sites for watershed-based
survey designs. 相似文献
96.
The primary objective of this study was to evaluate temporal changes in heavy metal content of lower Columbia River sediment
following terminated or reduced soluble heavy metal loading from the world's largest lead-zinc refinery and mining districts
in the USA and Canada. Sediment cores were collected from two fine sediment depositional sites (∼600 km downstream) in August
1999 and were analyzed for total metal content, texture, and age/dating parameters. Zinc, cadmium and lead contents in 1999
declined by only a factor of two over their depth profile maxima (dated as between 1970 and 1980). In sharp contrast, more
than a 10-fold decrease in dissolved metal loading occurred during this same period. Zinc in filtered Columbia River water
at downstream locations also declined by > 10-fold, consistent with the reduced upper river solute-metal loading. Once soluble
metal releases are reduced or terminated, the solute half-time in Columbia River water is months versus ∼20 yr for adsorbed
metals on surficial (or resuspended) bed sediments. The much slower rate of decline for sediment, as compared to the solute
phase, is attributed to resuspension, transport and redeposition of irreversibly bound metals from upstream sedimentary deposits.
This implies downstream exposure of benthic or particle-ingesting biota can continue for years following source remediation
and/or termination of soluble metal releases. Accordingly, contaminant contents of both particulate and solute phases of river
water, as well as sediment core sections, are suggested for assessing long-term biotic exposure/response to mitigation activities
in the Columbia River and similar fluvial ecosystems. 相似文献
97.
98.
Elina Leonova Karlis Shvirksts Mara Grube Lubov Ignatovich Calvin Yu-Chian Chen Tatjana Sjakste 《毒物与环境化学》2017,99(4):601-612
Ftorafur is an antimetabolite antitumour drug successfully used for treatment of various tumours. It is generally accepted that ftorafur is converted to 5-fluoruracil. However, some data indicate direct interactions of the compound with DNA. To test this hypothesis we have performed spectrophotometric study of DNA interactions of ftorafur and some of its elementoorganic derivatives with DNA. UV-VIS spectra of the tested compounds were recorded in absence and presence of increasing amounts of DNA. DNA caused a hypochromic effect in spectra of ftorafur, similar, but weaker effect was observed in 5-fluoruracil spectra. Trimethylgermyl derivative of ftorafur manifested a higher DNA-binding capacity compared to ftorafur. To reveal possible mechanism of interaction between the tested nucleosides and DNA ethidium bromide extrusion experiments were performed. It was shown that the compounds did not compete with EBr for intercalation. Fourier transformation infrared spectroscopy analyses revealed decrease in intensity of several bands in spectra of ftorafur, its trimethylgermyl derivative and fluorouracil in presence of DNA indicating again interactions between the compounds and DNA. Docking experiments reveal interactions of the tested nucleosides with the DNA minor groove. Thus ftorafur is capable to interact directly with DNA; further modifications of the molecule enhance this capacity. 相似文献
99.
100.