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71.
Ana P. L. Batista Hudson Wallace Pereira Carvalho Gustavo H. P. Luz Paulo F. Q. Martins Maraísa Gonçalves Luiz C. A. Oliveira 《Environmental Chemistry Letters》2010,8(1):63-67
A photocatalyst based on CuO/SiO2 was prepared, and evaluated for the degradation of methylene blue in aqueous medium. The photocatalyst was obtained by calcination
method of copper salt, in the presence of silica. The characterization by XRD, FTIR, and TPR techniques confirmed the formation
of CuO as active phase. SEM studies showed CuO deposited on the surface of SiO2. By ESI-MS, it was demonstrated that the degradation of methylene blue occurs through successive hydroxylations. Photodegradation
assays showed that CuO/SiO2 was efficient for degradation, and that the material worked better in the presence of UV light. 相似文献
72.
Monica Porto Rubem La Laina Porto Luiz Gabriel T. Azevedo 《Journal of the American Water Resources Association》1999,35(3):675-683
ABSTRACT: Brazil is currently facing the challenge of implementing a new water resources management system to promote the rational and sustainable use of the country's waters. This system is based on the following principles of water management: (2) stakeholders' participation; (2) the watershed as the planning and management unit; and (3) the economic value of water. Stakeholders' participation and the involvement of civil society in the decision making process is guaranteed by permanent seats in the watersheds' management committees. These committees are the highest decision level for the establishment of water policy and for planning its use. The executive branch of the committees is the watershed agency or the water agency. This paper presents the recently approved Brazilian water resources management system and discusses the participatory approach followed to validate and to ensure prompt response to decisions regarding water use by all stakeholders. The formulation of the National Water Law (January/1998) was also supported by extensive consultation with civil society, professional associations, state and municipal governments as well as with federal governmental agencies and private sector organizations. It also presents an overview of the formulation of the National Water Law. Finally, as watershed committees have been created and are already operating in a limited number of watersheds, some of the major obstacles to the success of the new system are discussed along with alternatives for overcoming such obstacles. 相似文献
73.
Carlos André Vaz Junior José Luiz de Medeiros Ofélia de Queiroz Fernandes Araújo 《Journal of Loss Prevention in the Process Industries》2010,23(3):462-475
This work presents a time series strategy for detection, location and quantification of leaks in large pipeline systems. The technology has two active components, which operate sequentially: the Detector and the Localizer. The Detector continuously screens real-time data, searching for any anomalies such as leaks, which are detected (or not) depending on their size and position. The Detector is based on auto-regressive multi-input/multi-output (MIMO) ARX predictors with one input filter. Subsequent to successful leak detection, the Localizer is launched to diagnose the leak via estimation of its parameters – diameter and location – using recorded data on a Search Time Window that includes information in the neighborhood of the instant of detection. The Localizer is also an ARX predictor, but with two input processors, the first is a filter for dynamic plant inputs and the second filter processes “parameter signals” of active leaks. The Localizer is developed beforehand via model identification with plant data under the action of known, artificially simulated, leaks. It is, therefore, able to recognize an active pattern of leak parameters, by maximizing the adherence of its predictions to data in the Search Time Window. The proposed detection and location methods were successfully tested in simulated leak scenarios for an industrial naphtha pipeline. 相似文献
74.
Baumgartner Matheus T. Piana Pitgoras A. Baumgartner Gilmar Gomes Luiz C. 《Environmental management》2020,65(2):220-231
Environmental Management - Water level variation has an important role in the biology of fish species, driving behavior, feeding, and reproduction both in natural and modified environments. In... 相似文献
75.
This article presents an analysis of the application of a cleaner production program within a Brazilian printing company and describes its specific characteristics to propose a benchmark for similar efforts at other companies. As a result, a very number of improvement opportunities (136) were identified, indicating that the printing industry needs to make reasonable, collective efforts to ensure that companies' environmental systems reach international marks. 相似文献
76.
Estrogens are a class of micro-pollutants found in water at low concentrations (in the ng L−1 range), but often sufficient to exert estrogenic effects due to their high estrogenic potency. Disinfection of waters containing estrogens through oxidative processes has been shown to lead to the formation of disinfection byproducts, which may also be estrogenic. The present work investigates the formation of disinfection byproducts of 17β-estradiol (E2) and estrone (E1) in the treatment of water with ozone. Experiments have been carried out at two different concentrations of the estrogens in ground water (100 ng L−1 and 100 μg L−1) and at varying ozone dosages (0-30 mg L−1). Detection of the estrogens and their disinfection byproducts in the water samples has been performed by means of ultra performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS) with a triple quadrupole (QqQ) and a quadrupole-time of flight (QqTOF) instrument. Both E2 and E1 have been found to form two main byproducts, with molecular mass (MM) 288 and 278 in the case of E2, and 286 and 276 in the case of E1, following presumably the same reaction pathways. The E2 byproduct with MM 288 has been identified as 10epsilon-17beta-dihydroxy-1,4-estradieno-3-one (DEO), in agreement with previously published results. The molecular structures and the formation pathways of the other three newly identified byproducts have been suggested. These byproducts have been found to be formed at both high and low concentrations of the estrogens and to be persistent even after application of high ozone dosages. 相似文献
77.
Luiz Eduardo Nochi Castro João Victor Furlan Santos Kátia Cristina Fagnani Helton José Alves Leda Maria Saragiotto Colpini 《Journal of environmental science and health. Part. B》2013,48(9):791-800
AbstractSugarcane vinasse is a by-product obtained during ethanol production in sugar-ethanol plants. For each 1?L of ethanol produced approximately 11?L of vinasse are generated. As this residue is obtained in high amounts, it is used as fertilizer in sugarcane crops. However, despite being rich in nutrients, sugarcane vinasse is approximately one hundred times more polluting than domestic sewage, making it an environmental problem. Thus, the aim of the present study was to propose a treatment sequence for sugarcane vinasse and evaluate the possibility of energetic use of the generated sludge in the coagulation/flocculation stage. pH, conductivity, turbidity and decreases in UV/Vis absorption spectra were determined for each treatment step. In addition, the upper calorific value of the generated sludge was also determined, while ash (adsorption treatment) and catalyst (heterogeneous photocatalysis) characterizations were also carried out. At the end of the treatment, initial vinasse turbidity was reduced by 100% and pH and conductivity values were stabilized. The sludge presented a higher calorific value of approximately 3,000?kcal kg?1 and the ash and catalyst displayed favorable characteristics to be applied to the sugarcane vinasse treatment stages. 相似文献
78.
Respiration induced by substrate and bacteria diversity after application of diuron,hexazinone, and sulfometuron-methyl alone and in mixture 总被引:1,自引:0,他引:1
Fabrícia Cristina Dos Reis Valdemar Luiz Tornisielo Bianca A. B. Martins Adijailton José de Souza Pedro Avelino Maia De Andrade Fernando Dini Andreote 《Journal of environmental science and health. Part. B》2013,48(7):560-568
AbstractAfter application, herbicides often reach the soil and affect non-target soil microorganisms, decreasing their population, diversity or affecting metabolic activity. Therefore, laboratory studies were performed to evaluate the effects of diuron, hexazinone and sulfometuron-methyl alone and mixed upon carbon transformation by soil microorganisms in clayey and sandy soils and the effect on bacterial diversity and structure. Control treatment without herbicide application was also performed. Sub-samples from the control and herbicide treatments (10?g – in triplicate) were collected before herbicide application and 7, 14, 28 and 42?days after treatment (DAT), then 1?mL of 14C-glucose solution was applied. The released 14CO2 was trapped in 2?M NaOH solution and the radioactivity was analyzed by liquid scintillation counting (LSC), 12?h after glucose application. The effect of herbicides on bacterial diversity was evaluated by T-RFLP. The experiment was conducted in a complete randomized design. Hexazinone did not affect 14CO2 evolution. Diuron showed a greater 14CO2 evolution in sandy and clayey soil, while sulfometuron-methyl led to an increase in sandy soil, at 42 DAT. A greater evolution of carbon was observed in the treatment with herbicide mixture in sandy soil, compared with the same treatment in clayey soil or control. However, the herbicide mixture application did not affect the soil biological activity measured by the respiration rate induced by substrate. On the other hand, the herbicide mixtures affected the bacterial diversity in both soils, being the strongest effect to diuron and sulfometuron-methyl in clayey soil and hexazinone in sandy soil. 相似文献
79.
Three-dimensional data interpolation for environmental purpose: lead in contaminated soils in southern Brazil 总被引:1,自引:0,他引:1
Tales Campos Piedade Vander Freitas Melo Luiz Cláudio Paula Souza Jeferson Dieckow 《Environmental monitoring and assessment》2014,186(9):5625-5638
Monitoring of heavy metal contamination plume in soils can be helpful in establishing strategies to minimize its hazardous impacts to the environment. The objective of this study was to apply a new approach of visualization, based on tridimensional (3D) images, of pseudo-total (extracted with concentrated acids) and exchangeable (extracted with 0.5 mol L?1 Ca(NO3)2) lead (Pb) concentrations in soils of a mining and metallurgy area to determine the spatial distribution of this pollutant and to estimate the most contaminated soil volumes. Tridimensional images were obtained after interpolation of Pb concentrations of 171 soil samples (57 points × 3 depths) with regularized spline with tension in a 3D function version. The tridimensional visualization showed great potential of use in environmental studies and allowed to determine the spatial 3D distribution of Pb contamination plume in the area and to establish relationships with soil characteristics, landscape, and pollution sources. The most contaminated soil volumes (10,001 to 52,000 mg Pb kg?1) occurred near the metallurgy factory. The main contamination sources were attributed to atmospheric emissions of particulate Pb through chimneys. The large soil volume estimated to be removed to industrial landfills or co-processing evidenced the difficulties related to this practice as a remediation strategy. 相似文献