Zooming on light packaging waste differences by scanning electron microscopy

Environmental Science and Pollution Research - In the present paper, different types of pure and commercial plastic waste from different EU countries (UK, France, Italy, and Romania) were...     

Management of waste electrical and electronic equipment in two EU countries: A comparison

The paper presents some data regarding waste electrical and electronic (WEEE) management in one of the founding countries of the EU, Italy, and in a recent entry into the EU, Romania. The aim of this research was to analyze some problems that countries entering the EU will have to solve with respect to WEEE management. The experiences of Italy and Romania could provide an interesting reference point. The strengths and weaknesses that the two EU countries have encountered can be used in order to give a more rational plan for other countries. In Italy the increase of WEEE collection was achieved in parallel with the increase of the efficiency of selective Municipal Solid Waste collection. In Romania, pilot experiences were useful to increase the awareness of the population. The different interests of the two populations towards recyclable waste led to a different scenario: in Romania all types of WEEE have been collected since its entrance into the EU; in Italy the “interest” in recycling is typically related to large household appliances, with a secondary role of lighting equipment.     

Vehicle-Induced Lead and Cadmium Contamination of Roadside Soil and Plants in Italy

Lead and cadmium concentrations in spontaneous vegetation and in soil sampled at various distances (0–208 m) from several motorways throughout Italy were measured. Lead and cadmium concentrations appear to be correlated to distance from the motorway and to traffic levels. A comparison with data from a remote and unpolluted site shows that foliar lead concentrations can be up to 40 times higher, and foliar cadmium concentrations up to 3 times higher. Plants behave differently in their accumulation of lead and cadmium; conifers present the highest levels. Also the various receptors and compartments of the roadside ecosystem differ in their accumulation of lead and cadmium; soil and bark have consistently higher concentrations, while the leaves and twigs of trees have consistently lower levels. the data recorded by ad hoc introduced bio-accumulating plants (Lolium multiflorum L.) are consistent with those of the spontaneous vegetation. the concentrations of both lead and cadmium in Lolium vary from June to November, following in part the fluctuation in traffic density.     

Some characteristics of a plume from a point source based on analytical solution of the two-dimensional advection–diffusion equation

The moments of the concentration distribution obtained using a recent analytical solution of the steady-state two-dimensional advection–diffusion equation are presented. The solving methodology is the Generalized Integral Laplace Transform Technique, which allows obtaining a reliable solution of the advection–diffusion equation without any restrictive assumption about the eddy diffusivity coefficients and wind speed profiles. The first four moments and value and position of maximum ground level concentration are calculated. The concentration standard deviation is compared against the semi-empirical ones used in operative Gaussian models.     

Soil humic acids may favour the persistence of hexavalent chromium in soil

The interaction between hexavalent chromium Cr(VI), as K₂CrO₄, and standard humic acids (HAs) in bulk solution was studied using three complementary analytical methods: UV-Visible spectroscopy, X-ray absorption spectroscopy and differential pulse stripping voltammetry. The observed UV-Vis and X-ray absorption spectra showed that, under our experimental conditions, HAs did not induce reduction of Cr(VI) to its trivalent chemical form. The interaction between Cr(VI) and HAs has rather led to the formation of Cr(VI)-HAs micelles via supramolecular chemical processes. The reported results could contribute towards explaining the relative persistence of ecotoxic hexavalent chromium in soils.     

Microbial oxygen uptake in sludge as influenced by compost physical parameters

The wide range of optimal values reported for the physical parameters of compost mixtures suggest that their interactive relationships should be investigated. The objective of this study was to examine the microbial O₂ uptake rate (OUR) in 16 sludge waste recipes, offering a range of moisture content (MC), waste/bulking agent (W/BA) ratio and BA particle size levels determined using a central composite experimental design. The 3 kg samples were maintained at a constant temperature and aeration rate for 28 days, during which a respirometer recorded O₂ uptake to provide a measure of microbial activity and biodegradability. The cumulative O₂ consumption after 14 and 28 days was found to be significantly influenced by MC, W/BA ratio, BA particle size and the interaction between MC and W/BA ratio (p < 0.05). Using multivariate regression analysis, the experimental data was used to generate a model with good predictive ability for cumulative O₂ consumption after 28 days as a function of the significant physical variables (R² = 0.84). The prediction of O₂ uptake by the model depended highly on the interaction between MC and W/BA ratio. A MC outside of the traditional 50–60% (wet basis) range still resulted in a high level of microbial O₂ uptake as long as the W/BA ratio was adjusted to maintain a suitable O₂ exchange in the sample. The evolution of OUR in the samples was also investigated, uncovering strong associations between short and long-term respirometric indices, such as peak OUR and cumulative O₂ consumption (p < 0.005). Combining peak OUR data with cumulative O₂ consumption after 14 days allowed for accurate predictions of cumulative O₂ after 28 days of aeration (R² = 0.96), implying that future studies need only run trials up to 14 days to evaluate the overall O₂ consumption or biodegradability of similar sludge mixtures.     

Outcome of fetal echogenic bowel: A systematic review and meta-analysis

The main aim of this systematic review was to explore the outcome of fetuses with isolated echogenic bowel (EB) on antenatal ultrasound. Inclusion criteria were singleton pregnancies with isolated EB no associated major structural anomalies at the time of diagnosis. The outcomes observed were: chromosomal anomalies, cystic fibrosis (CF), associated structural anomalies detected only at follow-up scans and at birth, regression during pregnancy, congenital infections, intra-uterine (IUD), neonatal (NND) and perinatal (PND) death. Twenty-five studies (12 971 fetuses) were included. Chromosomal anomalies occurred in 3.3% of the fetuses, mainly Trisomy 21 and aneuploidies involving the sex chromosomes. Cystic fibrosis occurred in 2.2%. Congenital infections affected 2.2%, mainly congenital Cytomegalovirus (CMV) infection. The majority of fetuses with EB experienced regression or disappearance of the EB at follow-up scans. Associated anomalies were detected at a follow-up scan in 1.8%. Associated anomalies were detected at birth and missed at ultrasound in 2.1% of cases. IUD occurred in 3.2% of cases while the corresponding figures for NND and PND were 0.4% and 3.1%. Fetuses with EB are at increased risk of adverse perinatal outcome, highlighting the need for a thorough antenatal management and postnatal follow-up. Assessment during pregnancy and after birth should be performed in order to look for signs of fetal aneuploidy, congenital infections and associated structural anomalies.     

Population structure of Brachidontes pharaonis (P. Fisher, 1870) (Bivalvia, Mytilidae) in the Mediterranean Sea, and evolution of a novel mtDNA polymorphism

Brachidontes pharaonis (Fisher P, 1870) is an Indo-Pacific mussel that has colonized the Mediterranean Sea via the Suez Canal. Mussels may have migrated by natural dispersal of pelagic larvae, or they may have been transported on the hulls of ships, or in ballast water, or by some combination of these. Mitochondrial COI sequences (618 bp) from 101 mussels from six localities in the central and eastern Mediterranean Sea and from one site in the Red Sea were used to describe population structure. Analysis of molecular variance indicated that frequencies differed among populations, and that 92% of the variation resided within populations. The majority of haplotypes were private alleles. No simple pattern of longitudinal variation was detected for haplotype frequencies, haplotype diversity, or nucleotide diversity. A variety of tree-building algorithms (NJ, MP, ME) gave consistent results, showing two sister groups. One clade had a leucine (L-form) and the other one a methionine (M-form) at the 30th amino acid. These sympatric forms were detected within all localities and they had similar frequencies in males and females. The M- and L-form were separated by a 7.3% sequence divergence, indicating that this is an ancient polymorphism. Closely related species of mussels had exclusively the L-form, so we infer that the M-form evolved from the L-form lineage of B. pharaonis, probably in the northern portion of the Red Sea. Neutrality tests detected an excess of rare mutations, a pattern of variation expected in expanding populations. Patterns of variation detected by Tajima’s D suggest that some form of balancing selection has maintained this polymorphism.     

Correlates of copulatory success in a fallow deer lek

Summary We studied the behavior and copulatory success of fallow deer (Cervus dama) males at a lek. We recorded 471 copulations in 3 years. Most males did not copulate. The top three males accounted for between 60 and 90% of copulations each year. Lek attendance time was the major determinant of male copulatory success, but territory location also affected the number of copulations achieved. Copulatory success was correlated with the number of females in a male's territory and possibly with dominance status, but not with fighting success or fighting rate. All males that defended lek territories were 5 years of age or older. Copulatory success may improve with age. Body condition appears to be an important determinant of male copulatory success, because only males in superior condition could defend a lek territory for up to 2 weeks. Males do not feed while defending lek territories. Foraging ability during the year probably determines condition at the onset of the rut. Females appear to choose mates at least partially on the basis of location, preferring males located near traditional routes. Females may ultimately select mates in the best body condition.