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161.
Sónia?Roxo José?António?de?AlmeidaEmail author Filipa?Vieira?Matias Herlander?Mata-Lima Sofia?Barbosa 《Environmental monitoring and assessment》2016,188(3):129
This paper proposes a multistep approach for creating a 3D stochastic model of total petroleum hydrocarbon (TPH) grade in potentially polluted soils of a deactivated oil storage site by using chemical analysis results as primary or hard data and classes of sensory perception variables as secondary or soft data. First, the statistical relationship between the sensory perception variables (e.g. colour, odour and oil–water reaction) and TPH grade is analysed, after which the sensory perception variable exhibiting the highest correlation is selected (oil–water reaction in this case study). The probabilities of cells belonging to classes of oil–water reaction are then estimated for the entire soil volume using indicator kriging. Next, local histograms of TPH grade for each grid cell are computed, combining the probabilities of belonging to a specific sensory perception indicator class and conditional to the simulated values of TPH grade. Finally, simulated images of TPH grade are generated by using the P-field simulation algorithm, utilising the local histograms of TPH grade for each grid cell. The set of simulated TPH values allows several calculations to be performed, such as average values, local uncertainties and the probability of the TPH grade of the soil exceeding a specific threshold value. 相似文献
162.
163.
Stefania Squadrone Livio Favaro Maria Cesarina Abete Barbara Vivaldi Marino Prearo 《Environmental monitoring and assessment》2014,186(4):2313-2320
Polycyclic aromatic hydrocarbons (PAHs) are a major concern in environmental studies as many of them have been labeled as probable carcinogens by the International Agency for Research on Cancer (IARC 1983). Due to their lipophilic properties and resistance to degradation, PAHs can accumulate in organic tissue. As a consequence, alarming concentrations of these compounds have been found in many aquatic species. The European catfish (Silurus glanis) is a top food chain predator that is considered to be a reliable bio-indicator of environmental pollution. From 2009 to 2011, 54 specimens of S. glanis were captured from four different sites covering the area of the Po River basin (Northern Italy). Fish muscles were analyzed in the laboratory to determine the levels of nine PAHs, namely naphthalene, acenaphthene, fluorene, phenanthrene, anthracene, pyrene, benz[a]anthracene, chrysene, and benz[a]pyrene (BaP), which were detected by high-performance liquid chromatography (HPLC). The total average concentration of PAHs was 26.90?±?49.50 ng g?1 (min 0.60, max 275.75 ng g?1). Analysis showed that 9.20 % of the fish muscles exceeded the maximum levels of 2 ng g?1 set for BaP by European regulations (Commission Regulation (EC), 2006). Values measured for benz[a]pyrene ranged from 0.05 to 8.20 ng g?1 (mean 1.07?±?1.58 ng g?1). Chrysene and benz[a]anthracene, both considered potential human carcinogens (PAH2), were found at levels of 4.40 and 0.05 ng g?1 (mean values), respectively. The highest mean concentration was recorded for anthracene (12.92 ng g?1), which has been recently included in the list of substances of very high concern (SVHC) as reported by the European Chemicals Agency (ECHA 1–9, 2009). 相似文献
164.
Manuela Carneiro Bruno Colaço Ricardo Brandão Carla Ferreira Nuno Santos Vanessa Soeiro Aura Colaço Maria João Pires Paula A. Oliveira Santiago Lavín 《Environmental monitoring and assessment》2014,186(11):7011-7021
The accumulation of heavy metals in the environment may have a wide range of health effects on animals and humans. Thus, in this study, the concentrations of arsenic (As), cadmium (Cd), lead (Pb), and mercury (Hg) in the blood and tissues (liver and kidney) of Portuguese common buzzards (Buteo buteo) were determined by inductively coupled plasma-mass spectrometer (ICP-MS) in order to monitor environmental pollution to these elements. In general, Hg and As were the elements which appeared in the highest and lowest concentrations, respectively. A highest percentage of non-detected concentration was found for blood Cd (94.6 %) but, in turn, it was the only metal that was detected in all kidney samples. The kidney was the analyzed sample which showed the highest concentrations of each element evaluated. Statistically, significant differences among blood, liver, and kidney samples were observed for As and Cd (P?0.05). Cd concentrations in kidney and liver varied significantly with age: Adults showed higher hepatic and renal Cd concentrations than juveniles. Blood Pb concentration seems to show an association with the hunting season. Although raptors are at the top of the food chain and are thus potentially exposed to any biomagnification processes that may occur in a food web, the individuals evaluated in this study generally had low levels of heavy metals in blood and tissues. However, chronic exposure to these metals was verified. The results presented here lend weight to arguments in favor of continuous biomonitoring of metals and metalloids, since heavy metals may accumulate to levels that will pose a risk to both human health and the environment. 相似文献
165.
The concentrations of seven metals (Cd, Cr, Cu, Fe, Mn, Ni and Zn) were determined in coastal seawaters and soft and hard tissues of the barnacle Chthamalus montagui from the northwest coast of Portugal to assess the potential use of C. montagui as biomonitor of metal contamination. The results of this study showed that C. montagui soft tissues can be used for monitoring metal bioavailabilities in these coastal seawaters: (1) there were significant correlations (p?0.05) between the metal concentrations in soft tissues and their concentrations in seawaters and (2) barnacle soft tissues were sensitive to spatial variation of metal bioavailabilities, accumulating different amounts of metals in different locations. The range of concentrations in tissues were: 0.59-1.7 mg Cd kg(-1), 0.5-3.2 mg Cr kg(-1), 0.72-3.0 mg Ni kg(-1), 1.2-6.7 mg Cu kg(-1), 9-26 mg Mn kg(-1), 214-785 mg Fe kg(-1) and 178-956 mg Zn kg(-1); (3) mean logarithmic bioaccumulation factors (log BAF) of Fe, Cr and Cd were higher, 5.49, 4.93 and 4.46, respectively, than mean log BAFs of Mn, Zn, Cu and Ni, 4.03, 3.97, 3.74 and 3.61, respectively. In contrary, C. montagui shell plates were not a good matrix to monitor metal bioavailability in these coastal seawaters, with no significant correlations (p?0.05) between metal concentrations in the shell and in seawater. Regarding the high Zn concentrations obtained in the coastal seawaters and C. montagui soft tissues, all seawaters from northwest coast of Portugal should be classified as "moderately/remarkably polluted". 相似文献
166.
Manuela C Francesco T Tiziana C Assunta C Lara S Nadia N Giorgia A Barbara S Maria F Carlotta C Valeria DG Pia SM Gianfranco T Angela S 《Journal of environmental monitoring : JEM》2012,14(6):1542-1550
To evaluate exposure to benzene in urban and rural areas, an investigation into personal exposure to benzene in traffic policemen, police drivers and rural (roadmen) male outdoor workers was carried out. Personal samples and data acquired using fixed monitoring stations located in different areas of the city were used to measure personal exposure to benzene in 62 non-smoker traffic policemen, 22 police drivers and 57 roadmen. Blood benzene, urinary trans-trans muconic acid (t,t-MA) and S-phenyl-mercapturic acid (S-PMA) were measured at the end of work shift in 62 non-smoker traffic policemen, 22 police drivers and 57 roadmen and 34 smoker traffic policemen, 21 police drivers and 53 roadmen. Exposure to benzene was similar among non-smoker traffic policemen and police drivers and higher among non-smoker urban workers compared to rural workers. Blood benzene, t,t-MA and S-PMA were similar among non-smoker traffic policemen and police drivers; blood benzene and t,t-MA were significantly higher in non-smoker urban workers compared to rural workers. Significant increases in t,t-MA were found in smokers vs. non-smokers. In non-smoker urban workers airborne benzene and blood benzene, and t,t-MA and S-PMA were significantly correlated. This study gives an evaluation of the exposure to benzene in an urban area, comparing people working in the street or in cars, to people working in a rural area. Benzene is a certain carcinogen for humans. The results we showed should lead to more in-depth studies about the effects on health of these categories of workers. 相似文献
167.
Maria Virgínia Alves Martins Fabrizio Frontalini Lazaro L. M. Laut Frederico S. Silva João Moreno Silvia Sousa Noureddine Zaaboub Monia El Bour Fernando Rocha 《Environmental monitoring and assessment》2014,186(12):8875-8897
Ria de Aveiro, which is located in the centre of Portugal (40° 38′ N, 8° 45′ W), is a well-mixed and complex coastal lagoon that is separated from the sea by a sandy barrier and connects with the Atlantic through an artificial inlet. Tidal currents are the main factor controlling the lagoon’s hydrodynamics and, to a great extent, the sedimentary dynamic. The inner lagoonal zones receive input from several rivers and experience the pressure caused by the accumulation of organic matter and pollutants (namely, trace metals) from diverse anthropic activities. This paper is the first piece of work aiming to recognize, characterize and explain the main benthic foraminiferal biotopes in Ria de Aveiro. To provide a broad overview of this kind of setting, our results are compared to those of previous published studies conducted in similar transitional environments. The research is based on an investigation of 225 sites spread throughout this ecosystem. Utilizing a statistical approach, this study analyses the details of dead benthic foraminiferal assemblages composed of 260 taxa, the texture and composition (mineralogical and geochemical) of the sediment and physicochemical data. On the basis of the results of R-mode and Q-mode cluster analyses, several different biotopes can be defined as marsh biotope/near-marsh biotope; marginal urban/marginal urban mixing biotope; inner-outer lagoon biotope or enclosed lagoon; outer lagoon biotope, mixed sub-biotope; and outer lagoon, marine sub-biotope. These biotopes are related to foraminifera assemblages and substrate type and are influenced by local currents, water depth, chemical and physicochemical conditions, river or oceanic proximity, and anthropogenic impact, as evidenced by the mapping of the six factor loadings of the principal component analysis conducted herein. Based on a similar methodology of analysis as that applied in previous studies in the Lagoon of Venice, comparable biotypes were identified in Lagoon of Aveiro. 相似文献
168.
The main objective of this work was to assess the potential use of goose barnacle Pollicipes pollicipes as biomonitor of metal contamination in northwest (NW) coast of Portugal. The concentrations of Cd, Cr, Cu, Fe, Mn, Ni and Zn were determined in coastal seawaters and tissues of P. pollicipes, which allowed establishing correlations between metals in coastal seawaters and P. pollicipes and calculating metal bioaccumulation factors (BAFs). The results of this study showed that P. pollicipes soft tissues can be used for monitoring metal contamination in these coastal seawaters: (1) there were significant correlations (p?0.05) between metals in soft tissues and their concentrations in seawaters, except for Zn (p?>?0.05); (2) soft tissues were sensitive to spatial variations of metal bioavailabilities and their concentrations ranged 0.70-2.22?mg?Cd?kg(-1), 0.49-1.40?mg?Cr?kg(-1), 1.37-2.07?mg?Ni?kg(-1), 2.4-3.3?mg?Cu?kg(-1), 5-59?mg?Mn?kg(-1), 134-578?mg?Fe?kg(-1)and 728-1,854?mg?Zn?kg(-1); (3) mean logarithmic bioaccumulation factors (log BAF) of Fe, Cd and Zn were higher, 5.57, 5.47 and 4.41, respectively, than mean log BAFs of Cr, Mn, Cu and Ni, 4.18, 4.14, 3.98 and 3.51, respectively. In contrary, P. pollicipes shell plates were not considered ideal material to monitor metal bioavailabilities in these coastal seawaters. Regarding the very high concentrations of Zn obtained in the coastal seawaters and P. pollicipes soft tissues, the NW coast of Portugal should be classified as "Class III/IV - Remarkably/Highly Polluted". 相似文献
169.
Brázová T Hanzelová V Miklisová D Salgovičová D Turčeková L 《Environmental monitoring and assessment》2012,184(11):6553-6561
The distribution and concentrations of polychlorinated biphenyls (PCBs) were determined in fish species (European perch Perca fluviatilis, northern pike Esox lucius, pike perch Sander lucioperca, wels catfish Silirus glanus, common carp Cyprinus carpio, European eel Anguilla anguilla, freshwater bream Abramis brama, goldfish Carassius auratus, and roach Rutilus rutilus) in a heavily polluted water reservoir Zemplínska ?írava (Slovakia). The study performed at two different time points 5?years apart (2004 and 2009) revealed serious PCB contamination of fish muscle tissue and significant interspecies as well as tissue-specific differences in PCB uptake by fish. Total PCBs broadly correlated with the trophic position of individual fish species within a food chain (P?0.01). The concentrations were particularly high in predatory fish species, perch, pike, and pike perch (108.0, 90.1, and 113.0?mg?kg(-1) lipid wt, respectively), but comparable PCB values were also found in non-predatory detrivorous freshwater bream (128.0?mg?kg(-1) lipid wt). The lowest PCB values were surprisingly assessed in European eel (17.1?mg?kg(-1) lipid wt). Tissue analysis showed the highest storage capacity of the liver (hepatopancreas in cyprinids) with maximum concentrations recorded found in northern pike (214.0?mg?kg(-1) lipid wt) and freshwater bream (163.0?mg?kg(-1) lipid wt). Negative correlations, mostly not significant, between the total PCB concentrations and fish weight were observed (P?>?0.05). The study has shown that the kind of fish, its feeding habit, and specific conditions of the habitat are mutually interrelated factors that are responsible for significant variations in fish body burdens. A tendency to PCB biomagnification was also proved in some fish species of this water reservoir. 相似文献
170.
Multivariate analysis of mixed contaminants (PAHs and heavy metals) at manufactured gas plant site soils 总被引:1,自引:0,他引:1
Principal component analysis (PCA) was used to provide an overview of the distribution pattern of polycyclic aromatic hydrocarbons
(PAHs) and heavy metals in former manufactured gas plant (MGP) site soils. PCA is the powerful multivariate method to identify
the patterns in data and expressing their similarities and differences. Ten PAHs (naphthalene, acenapthylene, acenaphthene,
fluorene, phenanthrene, anthracene, fluoranthene, pyrene, chrysene, benzo[a]pyrene) and four toxic heavy metals — lead (Pb), cadmium (Cd), chromium (Cr) and zinc (Zn) — were detected in the site soils.
PAH contamination was contributed equally by both low and high molecular weight PAHs. PCA was performed using the varimax
rotation method in SPSS, 17.0. Two principal components accounting for 91.7% of the total variance was retained using scree
test. Principle component 1 (PC1) substantially explained the dominance of PAH contamination in the MGP site soils. All PAHs,
except anthracene, were positively correlated in PC1. There was a common thread in high molecular weight PAHs loadings, where
the loadings were inversely proportional to the hydrophobicity and molecular weight of individual PAHs. Anthracene, which
was less correlated with other individual PAHs, deviated well from the origin which can be ascribed to its lower toxicity
and different origin than its isomer phenanthrene. Among the four major heavy metals studied in MGP sites, Pb, Cd and Cr were
negatively correlated in PC1 but showed strong positive correlation in principle component 2 (PC2). Although metals may not
have originated directly from gaswork processes, the correlation between PAHs and metals suggests that the materials used
in these sites may have contributed to high concentrations of Pb, Cd, Cr and Zn. Thus, multivariate analysis helped to identify
the sources of PAHs, heavy metals and their association in MGP site, and thereby better characterise the site risk, which
would not be possible if one uses chemical analysis alone. 相似文献