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101.
Ana Victoria Marta-Sanchez Sergiane Souza Caldas Antunielle Schneider Sónia Maria Vaz Sanches Cardoso Ednei Gilberto Primel 《Environmental science and pollution research international》2018,25(15):14460-14470
Parabens have been widely used as antimicrobial agents, mainly in food products, pharmaceuticals, and cosmetics. Although they are known as safe preservatives, they also cause some harm to human health, which has been discussed lately. Therefore, the aim of this study was to evaluate the occurrence of nine parabens (including isomers) in mineral and drinking waters, besides in drinking water treatment sludge (DWTS) samples with determination by liquid chromatography tandem mass spectrometry (LC-MS/MS). Both methods solid phase extraction (SPE) and QuEChERS were validated. Calibration curves showed a correlation coefficient of 0.99 for all compounds. LOQ values ranged from 0.04 to 4 μg L?1 in aqueous matrices and from 5 to 500 ng g?1 in DWTS. Recoveries between 70 and 115% were reached with RSD below 20% for all compounds in SPE whereas recoveries between 62 and 119% were found with RSD below 20% for almost all compounds in QuEChERS. Matrix effect had low values (<?20%); it was only above 20% for methylparaben in the SPE and for pentylparaben in the QuEChERS. Using a quick and simple extraction procedures with SPE, QuEChERS, and LC-MS/MS analyses, these methods proved to be selective and sensitive. They were successfully applied to real samples (treated water, mineral water, and sludge), and methylparaben was detected at concentration levels below 0.242 μg L?1 in mineral and treated water samples and 10 ng g?1 in DWTS samples. 相似文献
102.
Paula Ribao Maria J. Rivero Inmaculada Ortiz 《Environmental science and pollution research international》2018,25(35):34893-34902
This work aimed to optimize high-performance photocatalysts based on graphene oxide/titanium dioxide (GO/TiO2) nanocomposites for the effective degradation of aqueous pollutants. The catalytic activity was tested against the degradation of dichloroacetic acid (DCA), a by-product of disinfection processes that is present in many industrial wastewaters and effluents. GO/TiO2 photocatalysts were prepared using three different methods, hydrothermal, solvothermal, and mechanical, and varying the GO/TiO2 ratio in the range of 1 to 10%. Several techniques were applied to characterize the catalysts, and better coupling of GO and TiO2 was observed in the thermally synthesized composites. Although the results obtained for DCA degradation showed a coupled influence of the composite preparation method and its composition, promising results were obtained with the photocatalysts compared to the limited activity of conventional TiO2. In the best case, corresponding to the composite synthesized via hydrothermal method with 5% of GO/TiO2 weight ratio, an enhancement of 2.5 times of the photocatalytic degradation yield of DCA was obtained compared to bare TiO2, thus opening more efficient ways to promote the application of photocatalytic remediation technologies. 相似文献
103.
Małgorzata Dżugan Monika Wesołowska Grzegorz Zaguła Mateusz Kaczmarski Maria Czernicka Czesław Puchalski 《Environmental monitoring and assessment》2018,190(2):101
The aim of the study was to investigate the transfer of toxic metals from honeybee workers (Apis mellifera L.) to bee honey in relation to the ecological state of the environment. The materials of the study consisted of samples of honeybee bodies and varietal honeys taken from the same apiary located in three areas: R1—urbanized (16), R2—ecologically clean (16) and R3—industrialized (15) of south-eastern Poland. The contents of 14 elements in all tested samples, including toxic metals (Cd, Pb, Hg, Al, Ni, Tl) as well as bioelements (K, Mg, Ca, Mn, Fe, Zn, Cu, Se), were analysed by the ICP-OES method with prior microwave mineralization. The concentrations of the majority of the studied elements, excluding aluminum and lead, were significantly higher in bee bodies than in honey samples (P?<?0.05). The pollution of bee bodies by toxic metals was dependent on the environmental cleanliness, and the most pollution was observed in the industrialized area. The bee body was the most effective barrier for Cd and Tl transfer to the honey, while the level of Ni was similar in both tested materials. The Al concentration was significantly higher in honey than bee bodies (14.81?±?24.69 and 6.51?±?5.83 mg kg?1, respectively), which suggests the possibility of secondary contamination of honey. The greatest sensitivity to heavy metal pollution was observed in honeydew honey compared to nectar honeys (P?<?0.05). It was proved for the first time that bees work as biofilters for toxic metals and prevent honey contamination. 相似文献
104.
Marcelo Felix Alonso Karla Maria Longo Saulo R. Freitas Rafael Mello da Fonseca Virginie Marécal Michel Pirre Laura Gallardo Klenner 《Atmospheric environment (Oxford, England : 1994)》2010,44(39):5072-5083
This work describes the development of an urban vehicle emissions inventory for South America, based on the analysis and aggregation of available inventories for major cities, with emphasis on its application in regional atmospheric chemistry modeling. Due to the limited number of available local inventories, urban emissions were extrapolated based on the correlation between city vehicle density and mobile source emissions of carbon monoxide (CO) and nitrogen oxides (NOx). Emissions were geographically distributed using a methodology that delimits urban areas using high spatial resolution remote sensing products. This numerical algorithm enabled a more precise representation of urban centers. The derived regional inventory was evaluated by analyzing the performance of a chemical weather forecast model in relation to observations of CO, NOx and O3 in two different urban areas, São Paulo and Belo Horizonte. The gas mixing ratios simulated using the proposed regional inventory show good agreement with observations, consistently representing their hourly and daily variability. These results show that the integration of municipal inventories in a regional emissions map and their precise distribution in fine scale resolutions are important tools in regional atmospheric chemistry modeling. 相似文献
105.
Miglena Zhiyanski Maria Sokolovska Alexandros Clouvas Viktor Badulin 《Journal of environmental radioactivity》2010,101(10):864-868
This study focuses on the cesium-137 (137Cs) contamination in grass and in different compartments of oak trees growing in ecosystems, located in the zone with sub-mediterranean climate in South Bulgaria, characterized with high summer temperatures, low precipitation and often periods of drought. In 2008, three experimental sites - PP1, PP2, PP3 - were sampled in oak ecosystems from Maleshevska Mountain at 900 m above sea level. Samples from grass species and oak tree leaves, branches with different diameter, wood disks and bark were analyzed for 137Cs activity with γ-spectrometry. The soil-to-plant transfer factor (TF) values for 137Cs were estimated differentiating different tree compartments. Our findings showed relatively high activity concentrations of 137Cs in oak trees even 22 years after the Chernobyl accident. The grass under oak was less contaminated compared with the oak trees. The different organs of oak trees could be distinguished according to the 137Cs contamination as follows: bark > branches (d < 1 cm) > leaves > branches (d > 3 cm) > wood. The relatively higher contamination of bark compared with the new-formed biomass suggested that a significant part of 137Cs was accumulated as a result of direct adsorption at the time of the main contamination event. The TF values obtained and the presence of 137Cs in the branches, leaves and in the wood formed after 1986 confirmed that 22 years after the contamination, the main mechanism of 137Cs entrance in tree biomass was the root uptake. 相似文献
106.
Distribution of polycyclic aromatic hydrocarbons in urban stormwater in Queensland, Australia 总被引:1,自引:0,他引:1
Lars Herngren Godwin A. Ayoko Maria M.M. Mostert 《Environmental pollution (Barking, Essex : 1987)》2010,158(9):2848-2856
This paper reports the distribution of Polycyclic Aromatic Hydrocarbons (PAHs) in wash-off in urban stormwater in Gold Coast, Australia. Runoff samples collected from residential, industrial and commercial sites were separated into a dissolved fraction (<0.45 μm), and three particulate fractions (0.45-75 μm, 75-150 μm and >150 μm). Patterns in the distribution of PAHs in the fractions were investigated using Principal Component Analysis. Regardless of the land use and particle size fraction characteristics, the presence of organic carbon plays a dominant role in the distribution of PAHs. The PAHs concentrations were also found to decrease with rainfall duration. Generally, the 1- and 2-year average recurrence interval rainfall events were associated with the majority of the PAHs and the wash-off was a source limiting process. In the context of stormwater quality mitigation, targeting the initial part of the rainfall event is the most effective treatment strategy. The implications of the study results for urban stormwater quality management are also discussed. 相似文献
107.
Maria Sassine Laurence Burel Barbara D'Anna Christian George 《Atmospheric environment (Oxford, England : 1994)》2010,44(40):5468-5475
The kinetics of the heterogeneous reaction between gaseous HCHO and TiO2/SiO2 mineral coatings were investigated using a coated-wall flow tube to mimic HCHO loss on mineral aerosol and TiO2 coated depolluting urban surfaces. The measured uptake kinetics were strongly enhanced when the flow tube was irradiated with 340–420 nm UV light with an irradiance of 1.45 mW cm?2. The associated BET uptake coefficients ranged from (3.00 ± 0.45) × 10?9 to (2.26 ± 0.34) × 10?6 and were strongly dependent on HCHO initial concentration, relative humidity, temperature, and TiO2 content in the mineral coating, which ranged from 3.5 to 32.5 ppbv, 6–70%, 278–303 K, and 1–100 %wt, respectively. The measured kinetics were well described using a Langmuir–Hinshelwood type formalism. The estimated uptake coefficients were used to discuss the importance of heterogeneous HCHO surface loss, in terms of deposition lifetimes, as compared to major homogeneous gas-phase losses such as OH reaction and photolysis. It is found that deposition may compete with gas-phase removal of HCHO in a dense urban environment if more than 10% of the urban surface is covered with TiO2 treated material. 相似文献
108.
A Generic Bio-Economic Farm Model for Environmental and Economic Assessment of Agricultural Systems 总被引:2,自引:0,他引:2
Janssen S Louhichi K Kanellopoulos A Zander P Flichman G Hengsdijk H Meuter E Andersen E Belhouchette H Blanco M Borkowski N Heckelei T Hecker M Li H Oude Lansink A Stokstad G Thorne P van Keulen H van Ittersum MK 《Environmental management》2010,46(6):862-877
Bio-economic farm models are tools to evaluate ex-post or to assess ex-ante the impact of policy and technology change on agriculture, economics and environment. Recently, various BEFMs have been developed, often for one purpose or location, but hardly any of these models are re-used later for other purposes or locations. The Farm System Simulator (FSSIM) provides a generic framework enabling the application of BEFMs under various situations and for different purposes (generating supply response functions and detailed regional or farm type assessments). FSSIM is set up as a component-based framework with components representing farmer objectives, risk, calibration, policies, current activities, alternative activities and different types of activities (e.g., annual and perennial cropping and livestock). The generic nature of FSSIM is evaluated using five criteria by examining its applications. FSSIM has been applied for different climate zones and soil types (criterion 1) and to a range of different farm types (criterion 2) with different specializations, intensities and sizes. In most applications FSSIM has been used to assess the effects of policy changes and in two applications to assess the impact of technological innovations (criterion 3). In the various applications, different data sources, level of detail (e.g., criterion 4) and model configurations have been used. FSSIM has been linked to an economic and several biophysical models (criterion 5). The model is available for applications to other conditions and research issues, and it is open to be further tested and to be extended with new components, indicators or linkages to other models. 相似文献
109.
What makes neighborhood different from home and city? Effects of place scale on place attachment 总被引:2,自引:0,他引:2
Several years ago Hidalgo and Hernandez reported a curvilinear, U-shaped, relationship between scale of place (apartment, neighborhood, city) and strength of attachment to the place. In this paper four studies are presented, carried out in four Central-European cities, that (1) confirmed the reported curvilinear relationship using five places (apartment, building, neighborhood, city district, city) in three out of four cities and for five items of the Place Attachment Scale, (2) revealed a consistent curvilinear, inverse U-shaped relationship between scale of place and percentage of variance of place attachment predicted by three groups of factors: physical (type of housing, size of building, upkeep and personalization of house precincts, etc.), social (neighborhood ties and sense of security in the residence place), and socio-demographic (age, education, gender, length of residence, family size), and (3) identified strength of direct and indirect effects of the three groups of predictors on attachment to the five types of places. The curvilinear relationship between place scale and place attachment was particularly strong in highly attractive cities and in those scale items that described people's emotional reactions to places whereas a linear relationship was obtained in the least attractive city and in the items that referred to sense of security, amount of control and knowledge of place. In all four cities the best predicted variable was attachment to middle ranges of the place scale (building and neighborhood). The overall best direct predictor of place attachment was neighborhood ties, followed by direct and indirect effects of length of residence, building size, and type of housing. In conclusion it is argued that the usual choice of predictors of place attachment is biased by researchers' interest in the middle scales of place (neighborhood) at the expense of other place scales. In the paper a claim is made that attachments to smaller (apartments, homes) and larger (city) scales of place along with their unique predictors deserve more attention from environmental psychologists. 相似文献
110.
João Carrola Nádia Santos Maria J. Rocha António Fontainhas-Fernandes Miguel A. Pardal Rogério A. F. Monteiro Eduardo Rocha 《Environmental science and pollution research international》2014,21(9):6057-6068
Fish are bioindicators of water pollution, and an increased rate of their erythrocyte nuclear morphological abnormalities (ENMAs)—and particularly of erythrocyte micronuclei (EMN)—is used as a genotoxicity biomarker. Despite the potential value of ENMAs and MN, there is scarce information about fish captured in Iberian estuaries. This is the case of the Portuguese estuaries of the Mondego, Douro and Ave, suffering from different levels of environmental stress and where chemical surveys have been disclosing significant amounts of certain pollutants. So, the aim of this study was to evaluate genotoxicants impacts and infer about the exposure at those ecosystems, using the grey mullet (Mugil cephalus) as bioindicator and considering the type and frequency of nuclear abnormalities of erythrocytes as proxies of genotoxicity. Sampling of mullets was done throughout the year in the important Mondego, Douro and Ave River estuaries (centre and north-western Portugal). The fish (total n?=?242) were caught in campaigns made in spring–summer and autumn–winter, using nets or fishing rods. The sampled mullets were comparable between locations in terms of the basic biometric parameters. Blood smears were stained with Diff-Quik to assess the frequencies of six types of ENMAs and MN (given per 1,000 erythrocytes). Some basic water physicochemical parameters were recorded to search for fluctuations matching the ENMAs. Overall, the most frequent nucleus abnormality was the polymorphic type, sequentially followed by the blebbed/lobed/notched, segmented, kidney shaped, vacuolated, MN and binucleated. The total average frequency of the ENMAs ranged from 73?‰ in the Mondego to 108?‰ in the Ave. The polymorphic type was typically ≥50 % of the total ENMAs, averaging about 51?‰, when considering all three estuaries. The most serious lesion—the MN—in fish from Mondego and Douro had a similar frequency (≈0.38?‰), which was significantly lower than that in the Ave (0.75?‰). No significant seasonal differences existed as to the MN rates and seasonal differences existed almost only in the Douro, with the higher values in AW. In general, the pattern of ENMAs frequencies was unrelated with the water physicochemical parameters. Considering the data for both the total ENMAs and for each specific abnormality, and bearing in mind that values of MN in fish erythrocytes >0.3?‰ usually reflect pollution by genotoxicants, it is suggested that mullets were likely being chronically exposed to such compounds, even in the allegedly less polluted ecosystem (Mondego). Moreover, data supported the following pollution exposure gradient: Mondego?<?Douro?<?Ave. The scenario and inferences nicely agree with the published data from chemical monitoring. 相似文献