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51.
Heterogeneous and homogeneous catalytic ozonation of benzothiazole promoted by activated carbon: kinetic approach 总被引:5,自引:0,他引:5
Ozone oxidation combined with activated carbon adsorption (O(3)/AC) has recently started to be developed as a single process for water and wastewater treatment. While a number of aspects of aqueous ozone decomposition are well understood, the importance and relationship between aqueous ozone decomposition and organic contaminant degradation in the presence of activated carbon is still not clear. This study focuses on determining the contribution of homogeneous and heterogeneous reactions to organic contaminants removal in O(3)/AC system. Benzothiazole (BT) was selected as a target organic pollutant due to its environmental concern. A reactor system based on a differential circular flow reactor composed by a 19 cm(3) activated carbon fixed bed column and 1 dm(3) storage tank was used. Ozone was produced from pure and dry oxygen using an Ozocav ozone generator rated at 5 g O(3)h(-1). Experimental results show that BT removal rate was proportional to activated carbon dosage. Activated carbon surface contribution to BT oxidation reactions with ozone, increased with pH in absence of radical scavengers. The radical reaction contribution within the pH range 2-11 accounted for 67-83% for BT removal in O(3)/AC simultaneous treatment. Results suggest that at pH higher than the pH of the point of zero charge of the activated carbon dissociated acid groups such as carboxylic acid anhydrides and carboxylic acids present on activated carbon surface could be responsible for the observed increase in the ozone decomposition reaction rate. A simplified mechanism and a kinetic scheme representing the contribution of homogeneous and heterogeneous reactions on BT ozonation in the presence of activated carbon is proposed. 相似文献
52.
This study was conducted in the Swedish sub-Arctic, near Abisko, in order to assess the direction and scale of possible vegetation
changes in the alpine–birch forest ecotone. We have re-surveyed shrub, tree and vegetation data at 549 plots grouped into
61 clusters. The plots were originally surveyed in 1997 and re-surveyed in 2010. Our study is unique for the area as we have
quantitatively estimated a 19% increase in tree biomass mainly within the existing birch forest. We also found significant
increases in the cover of two vegetation types—“birch forest-heath with mosses” and “meadow with low herbs”, while the cover
of snowbed vegetation decreased significantly. The vegetation changes might be caused by climate, herbivory and past human
impact but irrespective of the causes, the observed transition of the vegetation will have substantial effects on the mountain
ecosystems. 相似文献
53.
Pérez-Parada A González J Pareja L Geis-Asteggiante L Colazzo M Niell S Besil N González G Cesio V Heinzen H 《Journal of environmental science and health. Part. B》2010,45(8):796-803
In order to evaluate the extraction of pesticide residues that are transferred to the brew during mate drinking process of P.U.1 yerba mate leaves (Ilex paraguariensis), a special device to simulate the way in which mate is drunk in Uruguay was developed. The transfer to the brew of 12 organophosphates, 5 synthethic pyrethroids and one organochlorine pesticide from spiked samples was studied. The relationship between the transfer data thus obtained and physicochemical properties like water solubility (Ws), octanol-water coefficient (Kow) and Henry's constant (H) was evaluated. The extractability of the pesticide residues from yerba mate can be correlated with log Ws and log Kow. These transfer values allowed the calculation of ARLs (acceptable residue level) for the pesticides following Food and Agriculture Organization (FAO), World Health Organizaion (WHO) guidelines. These results can help the future establishment of maximum residue levels (MRLs). 相似文献
54.
Oleksandra Ganzenko Nihal Oturan Ignasi Sirés David Huguenot Eric D. van Hullebusch Giovanni Esposito Mehmet A. Oturan 《Environmental Chemistry Letters》2018,16(1):281-286
Cytostatic drugs are a troublesome class of emerging pollutants in water owing to their potential effects on DNA. Here we studied the removal of 5-fluorouracil from water using the electro-Fenton process. Galvanostatic electrolyses were performed with an undivided laboratory-scale cell equipped with a boron-doped diamond anode and a carbon felt cathode. Results show that the fastest degradation and almost complete mineralization was obtained at a Fe2+ catalyst concentration of 0.2 mM. The absolute rate constant for oxidation of 5-fluorouracil by hydroxyl radicals was 1.52 × 109 M?1 s?1. Oxalic and acetic acids were initially formed as main short-chain aliphatic by-products, then were completely degraded. After 6 h the final solution mainly contained inorganic ions (NH4 +, NO3 ? and F?) and less than 10% of residual organic carbon. Hence, electro-Fenton constitutes an interesting alternative to degrade biorefractory drugs. 相似文献
55.
Polymer biodegradation: mechanisms and estimation techniques 总被引:2,自引:0,他引:2
Within the frame of the sustainable development, new materials are being conceived in order to increase their biodegradability properties. Biodegradation is considered to take place throughout three stages: biodeterioration, biofragmentation and assimilation, without neglect the participation of abiotic factors. However, most of the techniques used by researchers in this area are inadequate to provide evidence of the final stage: assimilation. In this review, we describe the different stages of biodegradation and we state several techniques used by some authors working in this domain. Validate assimilation (including mineralisation) is an important aspect to guarantee the real biodegradability of items of consumption (in particular friendly environmental new materials). The aim of this review is to emphasise the importance of measure as well as possible, the last stage of the biodegradation, in order to certify the integration of new materials into the biogeochemical cycles. Finally, we give a perspective to use the natural labelling of stable isotopes in the environment, by means of a new methodology based on the isotopic fractionation to validate assimilation by microorganisms. 相似文献
56.
57.
Toral MI Beattie A Santibañez C Richter P 《Environmental monitoring and assessment》2002,76(3):263-274
A first derivative spectrophotometric method has been developedfor the determination of parathion and p-nitrophenol in vegetabletissues. Ethanol was used as solvent for extracting the compoundsfrom the tissues and subsequently the samples were evaluated against a vegetable tissue blank, directly by derivative spectrophotometry. The simultaneous determination of these compounds can be carried out using the zero-crossing approach for parathion at 253.0 nm and for p-nitrophenol at 273.1 nm. In the samples each analyte was determined in the presence of one another in the ranges between 4.9 to 3883.5 g g-1 forparathion and 4.9 to 3285.3 g g-1 for p-nitrophenol.The detection limits (3) were found to be 1.5 and 1.4 g g-1 for parathion and p-nitrophenol, respectively. The relative standard deviations were in all instances less than1.8%. The proposed method was applied to the determination ofthe analytes in spiked leafs of corn. The results show a goodrecovery and they are in agreement with those obtained bypolarography. 相似文献
58.
Giant reed for selenium phytoremediation under changing climate 总被引:1,自引:0,他引:1
Hassan R. El-Ramady Neama Abdalla Tarek Alshaal Ahmed S. Elhenawy Mohamed S. Shams Salah E.-D. A. Faizy El-Sayed B. Belal Said A. Shehata Mohamed I. Ragab Megahed M. Amer Miklós Fári Attila Sztrik József Prokisch Dirk Selmar Ewald Schnug Elizabeth A. H. Pilon-Smits Samia M. El-Marsafawy Éva Domokos-Szabolcsy 《Environmental Chemistry Letters》2015,13(4):359-380
59.
60.
(Z)-Dodec-3-en-1-ol has been identified as the major component of the trail-following pheromone of nine species of Kalotermitidae
belonging to six different genera, suggesting that this compound represents a common signal in this family of termites. The
homogeneous nature of trail-following pheromones of Kalotermitidae well agrees with the monophyly of this family. It also
supports the postulated position of this family as a sister group of the Rhinotermitidae and Termitidae, which also secrete
C12-alcohols as trail-following pheromones. The significance of a trail pheromone in termites of the ‘one-piece’ life type,
which spend their whole life within the same piece of wood, is discussed. 相似文献