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371.
Studies of the impact of El Niño periods on marine species have usually focused on negative, highly visible effects, e.g., decreasing growth rates or increasing mortality due to a decline in primary productivity in typically nutrient rich upwelling zones; but positive effects related to elevated water temperature are also known. This study examined how the growth rate of juvenile white seabass, Atractoscion nobilis, responded to changes in ocean temperature in an El Niño period (1997–1998) in the northern portion of the Southern California Bight, USA. Growth rates of juvenile white seabass during their first 4 years of life were estimated as the slopes of linear relationships between body mass and age (from otoliths) of 800 fish collected at 11 stations throughout the bight. Growth rates differed significantly among cohorts hatched in 1996–2001. Specifically, white seabass that hatched in 1996 and 1997 grew significantly faster than those that hatched in 1998, 1999, and 2001. These differences in growth rates of cohorts appeared to be driven by variation in sea-surface temperature (SST). Growth rates averaged over the first three or 4 years of life were significantly positively correlated to average daily SST during the first 1–4 years of life. Increased growth of juvenile white seabass during the warm El Niño period likely provided a number of benefits to this warm-temperate species. This study demonstrated that some species will benefit from these warm-water periods despite reduced system-wide primary production.  相似文献   
372.
Occurrence and fate of 45 pesticides and 40 pesticide degradates were investigated in four contrasting agricultural settings--in Maryland, Nebraska, California, and Washington. Primary crops included corn at all sites, soybeans in Maryland, orchards in California and Washington, and vineyards in Washington. Pesticides and pesticide degradates detected in water samples from all four areas were predominantly from two classes of herbicides--triazines and chloroacetanilides; insecticides and fungicides were not present in the shallow ground water. In most samples, pesticide degradates greatly exceeded the concentrations of parent pesticide. In samples from Nebraska, the parent pesticide atrazine [6-chloro-N-ethyl-N'-(1-methylethyl)-1,3,5-triazine-2,4-diamine] was about the same concentration as the degradate, but in samples from Maryland and California atrazine concentrations were substantially smaller than its degradate. Simazine [6-chloro-N,N'-diethyl-1,3,5-triazine-2,4-diamine], the second most detected triazine, was detected in ground water from Maryland, California, and Washington. Metolachlor [2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl)acetamide] rarely was detected without its degradates, and when they were detected in the same sample metolachlor always had smaller concentrations. The Root-Zone Water-Quality Model was used to examine the occurrence and fate of metolachlor at the Maryland site. Simulations accurately predicted which metolachlor degradate would be predominant in the unsaturated zone. In analyses of relations among redox indicators and pesticide variance, apparent age, concentrations of dissolved oxygen, and excess nitrogen gas (from denitrification) were important indicators of the presence and concentration of pesticides in these ground water systems.  相似文献   
373.
Physical, chemical, hydrologic, and biologic factors affecting nitrate (NO3(-)) removal were evaluated in three agricultural streams draining orchard/dairy and row crop settings. Using 3-d "snapshots" during biotically active periods, we estimated reach-level NO3(-) sources, NO3(-) mass balance, in-stream processing (nitrification, denitrification, and NO3(-) uptake), and NO3(-) retention potential associated with surface water transport and ground water discharge. Ground water contributed 5 to 11% to stream discharge along the study reaches and 8 to 42% of gross NO3(-) input. Streambed processes potentially reduced 45 to 75% of ground water NO3(-) before discharge to surface water. In all streams, transient storage was of little importance for surface water NO3(-) retention. Estimated nitrification (1.6-4.4 mg N m(-2) h(-1)) and unamended denitrification rates (2.0-16.3 mg N m(-2) h(-1)) in sediment slurries were high relative to pristine streams. Denitrification of NO3(-) was largely independent of nitrification because both stream and ground water were sources of NO3(-). Unamended denitrification rates extrapolated to the reach-scale accounted for <5% of NO3(-) exported from the reaches minimally reducing downstream loads. Nitrate retention as a percentage of gross NO3(-) inputs was >30% in an organic-poor, autotrophic stream with the lowest denitrification potentials and highest benthic chlorophyll a, photosynthesis/respiration ratio, pH, dissolved oxygen, and diurnal NO3(-) variation. Biotic processing potentially removed 75% of ground water NO3(-) at this site, suggesting an important role for photosynthetic assimilation of ground water NO3(-) relative to subsurface denitrification as water passed directly through benthic diatom beds.  相似文献   
374.
Typical top-down regional assessments of CO2 storage feasibility are sufficient for determining the maximum volumetric capacity of deep saline aquifers. However, they do not reflect the regional economic feasibility of storage. This is controlled, in part, by the number and type of injection wells that are necessary to achieve regional CO2 storage goals. In contrast, the geomechanics-based assessment workflow that we present in this paper follows a bottom-up approach for evaluating regional deep saline aquifer CO2 storage feasibility. The CO2 storage capacity of an aquifer is a function of its porous volume as well as its CO2 injectivity. For a saline aquifer to be considered feasible in this assessment it must be able to store a specified amount of CO2 at a reasonable cost per ton of CO2. The proposed assessment workflow has seven steps that include (1) defining the storage project and goals, (2) characterizing the geology and developing a geomechanical model of the aquifer, (3) constructing 3D aquifer models, (4) simulating CO2 injection, (5,6) evaluating CO2 injection and storage feasibility (with and without injection well stimulation), and (7) determining whether it is economically feasible to proceed with the storage project. The workflow was applied to a case study of the Rose Run sandstone aquifer in the Eastern Ohio River Valley, USA. We found that it is feasible in this region to inject 113 Mt CO2/year for 30 years at an associated well cost of less than US $1.31/t CO2, but only if injectivity enhancement techniques such as hydraulic fracturing and injection induced micro-seismicity are implemented.  相似文献   
375.
376.
Simultaneous size distributions and Fourier transform infrared (FTIR) extinction spectra have been measured for several representative components of mineral dust aerosol (quartz, calcite, and dolomite) in the fine particle size mode (D=0.1–1 μm). Optical constants drawn from the published literature have been used in combination with the experimentally determined size distributions to simulate the extinction spectra. In general, Mie theory does not accurately reproduce the peak position or band shape for the prominent IR resonance features in the 800–1600 cm−1 spectral range. The resonance peaks in the Mie simulation are consistently blue shifted relative to the experimental spectra by 20–50 cm−1. Spectral simulations, derived from a simple Rayleigh-based analytic theory for a “continuous distribution of ellipsoids” particle shape model, better reproduce the experimental spectra, despite the fact that the Rayleigh approximation is not strictly satisfied in these experiments. These results differ from our previous studies of particle shape effects in silicate clay mineral dust aerosols where a disk-shaped model for the particles was found to be more appropriate.  相似文献   
377.
Levee failure and overtopping as a result of Hurricane Katrina caused major flooding of New Orleans, Louisiana. Floodwaters, which were contaminated with heavy metals, organic chemicals, and fecal coliform bacteria (FCB), were pumped into neighboring Lake Pontchartrain during dewatering. The impact of levee failure on water and benthic sediment concentrations in the lake was investigated by applying a numerical water quality model coupled to a three-dimensional, numerical hydrodynamic model. The model was used to compute water and benthic sediment concentrations throughout the lake for lead, arsenic, benzo(a)pyrene (BaP), and 1,1-dichloro-2,2-bis(p-chlorophenyl)ethylene (DDE), and water concentrations for FCB. Computed concentrations resulting from actual pumped discharges with levee failure and overtopping were compared to computed concentrations resulting from pumped discharges without levee failure or overtopping, and concentrations from both sets of conditions were compared to ecological water and sediment quality screening guideline values. The model indicated that incremental increases above pre-Katrina benthic sediment concentrations are about a factor of 10 greater with dewatering of the floodwaters than with dewatering of storm water without flooding. However, these increases for the metals are small relative to pre-Katrina concentrations. The results showed that the ecological screening-level sediment quality guideline values were exceeded for BaP and DDE in areas near the south shoreline of the lake as a result of floodwater pump-out, whereas, this was not the case for storm water removal without flooding. The model showed that lake water column concentrations should be about the same during both dewatering conditions regardless of whether there is flooding or not.  相似文献   
378.
Research suggests that characteristics of local government land-use planners help determine the priority that local communities place on flood hazard mitigation. However, research has not examined the significance of land-use planners' values and role orientations for flood hazard mitigation. Multiple regression analysis is used to examine the influence that land-use planners' values and role orientations have on flood hazard mitigation in a national sample of New Urbanist development projects. Findings indicate that land-use planners' values and role orientations have significant implications for flood hazard mitigation in these projects. The paper recommends that local governments adopt a land-use planning approach to flood hazard mitigation that relies on land-use planners to help direct development away from hazardous portions of development sites.  相似文献   
379.
Nitrogen Dioxide (NO2) is a common urban air pollutant that results from the combustion of fossil fuels. It causes serious human health effects, is a precursor to the formation of ground level ozone, another serious air pollutant, and is one of the six criteria air pollutants established by the United States (U.S.) Clean Air Act (CAA). Ogawa Passive Sampling Devices (PSDs) for NO2 were collocated and operated at six NO2 Federal Reference Method (FRM) monitor locations in the El Paso, Texas area for the 2004 calendar year. Passive samples were taken at 2-week, 3-week, and 4-week intervals and compared against the continuously operating FRM monitors. Results showed that the collective NO2 annual arithmetic mean for all passive monitors was identical to the NO2 mean for all FRM monitors. Of the individual locations, three passive annual NO2 means were identical to their corresponding FRM means, and three passive annual NO2 means differed from their corresponding FRM means by only one part per billion (ppb). Linear correlation analysis between all readings of the individual NO2 PSDs and FRM values showed an average absolute difference of 1.2 ppb with an r 2 of 0.95. Paired comparison between high and low concentration annual NO2 sites, seasonal considerations, and interlab quality control comparisons all showed excellent results. The ease of deployment, reliability, and the cost-savings that can be realized with NO2 PSDs could make them an attractive alternative to FRM monitors for screening purposes, and even possibly an equivalent method for annual NO2 monitoring. More tests of the Ogawa NO2 PSD are recommended for different ecosystem and climate regimes.  相似文献   
380.
Most of the world's children live in resource-poor countries where people are at a relatively high risk of exposure to catastrophic situations arising from conflict and natural disasters.(6) Given the potential social, psychological and psychiatric consequences of exposure to disaster, mental health and psychosocial support programmes are increasingly part of humanitarian aid. A minimum standard on mental and social aspects of health is included in the recently revised Humanitarian Charter and Minimum Standards in Disaster Response (Sphere Handbook) (Sphere Project, 2004). Most recommendations for mental health and psychosocial interventions in guidance documents are based on expert opinion rather than research. Consequently, interventions are being implemented without full understanding of their potential benefit or harm. This paper offers a child-focused review of the evidence for each of the interventions described as indicators for the Sphere standard on mental and social aspects of health. It suggests some, but limited, support for each of them. However, the evidence base needs substantial strengthening.  相似文献   
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