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381.
Sheppard PR Speakman RJ Ridenour G Witten ML 《Environmental monitoring and assessment》2007,130(1-3):511-518
This paper describes the use of lichen chemistry to assess airborne tungsten and cobalt in Fallon, Nevada, where a cluster
of childhood leukemia has been on going since 1997. Lichens and their rock substrates were collected from Rattlesnake Hill
within Fallon as well as from four different rock outcrops located north, east, south, and west of Fallon and at least 20 km
away from the town center. In the lichens themselves, W and Co are significantly higher within Fallon than in the combined
control site outside of Fallon. In the rock substrates of the lichens, no differences exist in W and Co. The W and Co differences
in lichens cannot be attributed to substrate geochemistry. Fallon is distinctive in west central Nevada for high airborne
W and Co, and given its cluster of childhood leukemia, it stands to reason that additional biomedical research is in order
to test directly the leukogenicity of combined airborne W and Co. 相似文献
382.
Goebes MD Hildemann LM Kujundzic E Hernandez M 《Journal of environmental monitoring : JEM》2007,9(6):599-609
Aspergillus is a genus of mold that has strong indoor sources, including several species capable of acting as opportunistic pathogens. Previous studies suggest that Aspergillus could serve as an indicator for abnormal mold growth or moisture, making it an important genus for environmental monitoring. Here, a quantitative polymerase chain reaction (qPCR, or real-time PCR) assay is presented for Aspergillus. The assay shows good specificity for the genus, detecting all Aspergillus species tested, although a few non-Aspergillus species are also amplified. Sensitivity testing demonstrates that DNA representing one conidium can be detected. A validation study compared qPCR results against direct microscopy counts using A. fumigatus conidia aerosolized into a laboratory chamber. The assay was then used to quantify Aspergillus in indoor air samples, demonstrating its utility for environmental monitoring. Analysis of a small number of clinical sputum samples showed complete agreement with culturing results. 相似文献
383.
The potential for airborne emissions to undergo long-range transport or to be removed from the atmosphere is influenced by their physical-chemical properties. When perfluorooctanate (PFO) enters the environment, its physical-chemical properties can vary significantly, depending on whether it exists as an acid, a salt, or a dissociated ion. A summary of the physical-chemical properties of the three most likely environmental states: ammonium perfluorooctanoate (APFO), perfluorooctanoic acid (PFOA) and the dissociated perfluorooctanoate anion (PFO(-)) is presented to illustrate the distinct environmental properties of each. The most volatile species, PFOA, is shown to have a pH-dependent air-water partitioning coefficient (K(aw)). The variability of K(aw) with pH influences the potential for vapor formation from aqueous environments, including rain events. Using the pH-dependent K(aw) and measured rain and air concentrations, it is shown that vapor-phase PFOA is not likely to be present above measurable levels of 0.2 ng m(-3) (12 parts per quadrillion v/v) during a rain event. Because rain concentrations determined in this work are comparable to measurements in other parts of North America, it is unlikely that rain events are a significant source of vapor-phase PFOA for the general North American region. It is shown that PFOA exists primarily in the particle phase in ambient air near direct sources of emissions and is efficiently scavenged by rain droplets, making wet deposition an important removal mechanism for emissions originating as either PFOA or APFO. Washout ratios of particle-associated PFO were determined to range between 1 x 10(5) and 5 x 10(5), in the same range as other semi-volatile compounds for which wet deposition is an important mechanism for atmospheric removal and deposition onto soils and water bodies. 相似文献
384.
For the south central U.S., lower tropospheric ozone pollution has been a persistent and challenging problem. This paper provides long-term trends analyses of the ozone and precursor monitoring data collected over the past 20 years in four south central U.S. cities. The results of these analyses should be useful to air quality scientists, managers, planners, and modelers in assessing the effectiveness of ozone pollution control strategies being implemented or being planned for the future. Results of the data analyses show that all areas have monitored significant decreases in ozone and precursor concentrations over the past 20 years, especially in El Paso, Texas. Continuing challenges include the reduction of the percentage of time that monitors record 8 hour ozone concentrations over the U.S. 8 hour ozone standard, and the future control of highly reactive volatile organic compounds. 相似文献
385.
Harrad S Robson M Hazrati S Baxter-Plant VS Deplanche K Redwood MD Macaskie LE 《Journal of environmental monitoring : JEM》2007,9(4):314-318
The environmentally prevalent polybrominated diphenyl ether (PBDE) #47 and polychlorinated biphenyls (PCBs) #28 and #118 were challenged for 24 hours with a novel biomass-supported Pd catalyst (Bio-Pd(0)). Analysis of the products via GC-MS revealed the Bio-Pd(0) to cause the challenged compounds to undergo stepwise dehalogenation with preferential loss of the least sterically hindered halogen atom. A mass balance for PCB #28 showed that it is degraded to three dichlorobiphenyls (33.9%), two monochlorobiphenyls (12%), and biphenyl (30.7%). The remaining mass was starting material. In contrast, while PCB #118 underwent degradation to yield five tetra- and five trichlorinated biphenyls, no less chlorinated products or biphenyl were detected, and the total mass of degraded products was 0.3%. Although the Bio-Pd(0) material was developed for treatment of PCBs, a mass balance for PBDE #47 showed that the biocatalyst could prove a potentially useful method for treatment of PBDEs. Specifically, 10% of PBDE #47 was converted to identifiable lower brominated congeners, predominantly the tribrominated PBDE #17 and the dibrominated PBDE #4, 75% remained intact, while 15% of the starting mass was unaccounted for. 相似文献
386.
Fuzzy Sets and Threatened Species Classification 总被引:1,自引:0,他引:1
387.
388.
Jacobus C. Biesmeijer Mark G. L. van Nieuwstadt Saskia Lukács Marinus J. Sommeijer 《Behavioral ecology and sociobiology》1998,42(2):107-116
Social insect foragers have to make foraging decisions based on information that may come from two different sources: information
learned and memorised through their own experience (“internal” information) and information communicated by nest mates or
directly obtained from their environment (“external” information). The role of these sources of information in decision-making
by foragers was studied observationally and experimentally in stingless bees of the genus Melipona. Once a Melipona forager had started its food-collecting career, its decisions to initiate, continue or stop its daily collecting activity
were mainly based upon previous experience (activity on previous days, the time at which foraging was initiated the day(s)
before, and, during the day, the success of the last foraging flights) and mediated through direct interaction with the food
source (load size harvested and time to collect a load). External information provided by returning foragers advanced the
start of foraging of experienced bees. Most inexperienced bees initiated their foraging day after successful foragers had
returned to the hive. The start of foraging by other inexperienced bees was stimulated by high waste-removal activity of nest
mates. By experimentally controlling the entries of foragers (hence external information input) it was shown that very low
levels of external information input had large effect on the departure of experienced foragers. After the return of a single
successful forager, or five foragers together, the rate of forager exits increased dramatically for 15 min. Only the first
and second entry events had large effect; later entries influenced forager exit patterns only slightly. The results show that
Melipona foragers make decisions based upon their own experience and that communication stimulates these foragers if it concerns the
previously visited source. We discuss the organisation of individual foraging in Melipona and Apis mellifera and are led to the conclusion that these species behave very similarly and that an information-integration model (derived
from Fig. 1) could be a starting point for future research on social insect foraging.
Received: 16 April 1997 / Accepted after revision: 30 August 1997 相似文献
389.
390.
Summary. A diverse group of brown seaweeds produce bouquets of C11 metabolites, some of which act as pheromones that cue gamete release or attract sperm to eggs following release. We demonstrate
that these C11 metabolites and their degradation products also frequently and strongly deter feeding by the herbivorous amphipod Ampithoe longimana, but rarely by the herbivorous sea urchin Arbacia punctulata. Across the range of concentrations tested, seven of twelve C11 metabolites or mixtures that we tested deterred feeding by the amphipod, but only two of eleven deterred the sea urchin.
For those compounds where we could rigorously contrast the magnitude of deterrence against the amphipod with the magnitude
of deterrence against the urchin, the amphipod was deterred significantly more than the urchin by five of six metabolites.
Thus, C11 compounds were more frequently and more strongly deterrent to the amphipod than to the sea urchin. These findings for C11 metabolites conflict with previous investigations, where other classes of seaweed chemical defenses have been shown to deter
feeding by large mobile herbivores like urchins and fishes but to be relatively ineffective against mesograzers, especially
the species of amphipod that we used here. Our results suggest that C11 metabolites are unusual among the known seaweed chemical defenses in that they are especially effective against mesograzers,
which often consume seaweed spores, zygotes, and juveniles. The high concentrations of C11 metabolites in brown algal eggs could allow these defenses to be especially important in defending gametes, zygotes, or young
sporelings from herbivorous mesograzers.
Received 26 February 1998; accepted 9 April 1998. 相似文献