Origin of major ions in monthly rainfall events at the Bamenda Highlands, North West Cameroon

Rainwater characteristics can reveal emissions from various anthropogenic and natural sources into the atmosphere. The physico-chemical characteristics of 44 monthly rainfall events （collected between January and December 2012） from 4 weather stations （Bamenda, Ndop plain, Ndawara and Kumbo） in the Bamenda Highlands （BH） were investigated. The purpose was to determine the sources of chemical species, their seasonal inputs and suitability of the rainwater for drinking. The mean pH of 5 indicated the slightly acidic nature of the rainwater. Average total dissolved solids （TDS） were low （6.7 mg/L）, characteristic of unpolluted atmospheric moisture/air. Major ion concentrations （mg/L） were low and in the order K＋ 〉 Ca2＋ 〉 Mg2~ 〉 Na＋ for cations and NO3 〉〉 HCO3 〉 SO] 〉 CI- 〉 PO3- 〉 F- for anions. The average rainwater in the area was mixed Ca-Mg-SO4-CI water type. The CI-/Na＋ ratio （1.04） was comparable to that of seawater （1.16）, an indication that N a＋ and CI originated mainly from marine （Atlantic Ocean） aerosols. High enrichments of Ca2＋, Mg2＋ and SO2- to Na＋ ratios relative to seawater ratios （constituting 44% of the total ions） demonstrated their terrigenous origin, mainly from Saharan and Sahelian arid dusts. The K＋/Na＋ ratio （2.24）, which was similar to tropical vegetation ash （2.38）, and NO3 was essentially from biomass burning. Light （〈 100 mm） pre-monsoon and post-monsoon convective rains were enriched in major ions than the heavy （〉 100 mm） monsoon rains, indicating a high contribution of major ions during the low convective showers. Despite the acidic nature, the TDS and major ion concentrations classified the rainwater as potable based on the WHO guidelines.     

Survey of polycyclic aromatic hydrocarbons (PAHs) in arterial street air of Hangzhou

ＩｎｔｒｏｄｕｃｔｉｏｎＰｏｌｙｃｙｃｌｉｃａｒｏｍａｔｉｃｈｙｄｒｏｃａｒｂｏｎｓ (ＰＡＨｓ)ａｒｅｗｉｄｅｓｐｒｅａｄｅｎｖｉｒｏｎｍｅｎｔａｌｐｏｌｌｕｔａｎｔｓｉｎｔｈｅａｔｍｏｓｐｈｅｒｅ.Ｔｈｅｙａｒｅｇｅｎｅｒａｔｅｄｉｎｔｈｅｃｏｍｂｕｓｔｉｏｎ .Ｔｈｅｍａｊｏｒｓｏｕｒｃｅｓｉｄｅｎｔｉｆｉｅｄｉｎｃｌｕｄｅｆｏｓｓｉｌｆｕｅｌｓ,ｖｅｈｉｃｕｌａｒｔｒａｆｆｉｃ,ｉｎｄｕｓｔｒｉａｌｐｒｏｃｅｓｓｅｓ,ｓｍｏｋｉｎｇａｎｄｄｏｍｅｓｔｉｃｈｅａｔｉｎｇ (Ｐｅｌｔｏｎｅｎ ,1995) .Ｔ…     

Modelling local and synoptic scale influences on ozone concentrations in a topographically complex region of Southern Italy

A modelling study with the on-line coupled Eulerian chemical-weather model WRF/Chem for the Southern Italian region around Cosenza (Calabria) was conducted to identify the influences of synoptic scale meteorology, local scale wind systems and local emissions on ozone concentrations in this orographically complex region. Four periods of 5–7 days were chosen, one from each season, which had wind pattern characteristics representative of typical local climatological conditions, in order to study the local versus non-local impacts on ozone transport and formation. To account for the complex terrain, the horizontal resolution of the smallest modelling domain was 3 km. Model results were compared with measurements to demonstrate the capability of the model to reproduce ozone concentrations in the region. The comparison was favourable with a mean bias of ?1.1 ppb. The importance of local emissions on ozone formation and destruction was identified with the use of three different emission scenarios. Generally the influence of regional emissions on the average ozone concentration was small. However during periods when mountain-sea wind systems were well developed and synoptic scale winds were weak, the influence of local emissions from the urban area was at its greatest. The maximum influence of local emissions on ozone concentrations was 18 ppb.     

Perceptions of air pollution during the work-related commute by adults in Queensland,Australia

BackgroundThis study examines perceived health effect risks from air pollution during the work-related commute by socio-demographic and travel mode variables.MethodsPopulation-representative survey data were collected by telephone from 745 adults from Queensland, Australia. Variables assessed included socio-demographics, usual work travel mode, commute perceptions, and perceived health effects associated with air pollution during the work-related commute.ResultsApproximately 45% of the sample perceived air pollution negatively affected health outcomes when commuting to/from work, yet only 13% recognised air pollution as a major barrier to walking or cycling to/from work. No relationships existed between usual travel mode to/from work and perceived health risks associated with air pollution. Those higher educated or living in major cities were more likely to recognise air pollution harmed their health during their work-related commute when compared to respective referent categories (p ≤ 0.05).ConclusionsRecognition of health risks from air pollution during the work-related commute was high, and awareness did not differ by travel mode. For the majority, air pollution was not a primary barrier for walking or cycling to/from work.     

Educating the next generation of atmospheric scientists within a European Network of Excellence

In order to promote the next generation of atmospheric scientists, the task Training and Education (T&E) in ACCENT, the European Network of Excellence in Atmospheric Composition Change (www.accent-network.org) has developed and implemented an Integrated Learning Environment (ILE). For school teachers and their students, the Internet-based “Global Change Magazine” provides up-to-date and freely accessible scientific material in English and five other languages. Additionally, T&E has produced online teaching material for early-career scientists. These e-learning modules are now being used in University Master's courses across Europe. T&E also organised training events for early-career scientists, combining scientific content with development in transferable skills, to focus on interdisciplinary collaboration, interaction with senior scientists, communication with stakeholders, and dissemination to the general public. Evaluation based on participant feedback evidences the effectiveness of these events, e.g., in terms of motivation to remain in the field. Methodologies and materials from T&E are being published in a Handbook on Best Practice, intended for both educators and scientists around the globe who are involved in education in the field of air quality and climate change science.     

A matter of approach: the retort's potential to reduce mercury consumption within small-scale gold mining settlements in Tanzania

The mercury-based gold extraction processes prevalent within small-scale mining are both efficient and harmful. While ensuring relatively high levels of gold recovery, they cause environmental and health problems for people living within mining settlements. This mercury consumption can be minimized by using a simple mercury recycling device known as a retort. While mining legislation in Tanzania dictates the use of retorts for gold recovery, virtually no miners use them, indicating the inadequacy of previous introduction attempts. During action research, retorts were introduced in two mining settlements through a thorough and participatory approach. Twenty miners were given retorts and their attitudes and receptiveness to them were studied. Of the recipients, 18 used the retorts over a period of five months, recycling 10 kilos of mercury. Less mercury was spilled into the environment and miners saved money normally spent on purchasing mercury. The findings have implications for the strategies of development interventions targeting mercury-instigated problems within small-scale gold mining.     

Estimating carbon in savanna ecosystems: rational distribution of effort

Minimising the cost of repeatedly estimating C (C) stocks is crucial to the financial viability of projects that seek to sell C credits. Depending on the price of C, this may imply less or more sampling effort than would be applied for science objectives. In systems with heterogeneous C pools, such as savannas, this translates into a variable-effort sampling strategy that maximises the marginal additional C that can be claimed per incremental unit of effort expended. Analysis of a savanna in north-eastern South Africa indicates relatively modest returns per hectare due to the small C quantities and low sequestration rates. Under these conditions, areas in excess of 1,000 ha and infrequent sampling frequencies of 5–10 years are required to make such projects financially viable. For such projects the sample variance, number of samples, cost per sample and establishment costs have negligible impacts on financial viability. It was also found that the soil-C pool contributes up to three times the net returns of the aboveground C pool and provides a strong argument to monitor soil C for certification and market trading. The financial viability estimates, however, do not include the management or opportunity costs incurred in changing the land use. The economies of scale identified in this study combined with the massive area covered by savannas indicate that these additional costs can be covered. Further research is recommended to quantify these costs and interrogate the feasibility of large scale (in excess of 10,000 ha) C-sink projects in savanna systems.     

Carbon accumulation through ecosystem recovery

A market has emerged for carbon sequestered through reforestation. The opportunity to restore ecosystems through this market rather than establish plantations is demonstrated by an Australian case study. In the state of Queensland there are vast areas that have been cleared relatively recently and could be restored to ecosystems with high resilience and important biodiversity values with appropriate management. In order to foster opportunities for carbon accumulation through ecosystem recovery spatially explicit information on sequestration rates, management recommendations, and clear definitions of ancillary biodiversity benefits need to be defined.     

Yield response of potato to spatially patterned nitrogen application

Although crop response to nitrogen fertilization has long been studied, classical experimental designs have led to inadequate accounting of spatial variability in field properties and yield response. Analytical methods to explicitly account for spatial variability now exist but the complementary modification of experimental design is still developing. There is a need to combine these analytical methods with non-traditional experimental design. A 2-year study was implemented to assess the response of potato (Solanum tuberosum cv. Kennebec) yield to nitrogen fertilizer rate. We used a transect-type plot design where four nitrogen treatments (0, 56, 112, and 280 kg N ha^?1) were applied systematically in a continuous sinusoidal pattern along longitudinal transects. Measured field properties included topography, soil texture, pre-application soil nitrate levels, and plant available soil water content. A random field linear model was used to simultaneously account for treatment effects and soil properties. The results showed that treatment effects were significantly different from each other; however, if spatially correlated errors were accounted for, these differences were smaller and significance levels lower. Nitrogen response functions varied widely throughout the field. Of the covariates, only clay content proved important in explaining spatial differences in response to N. The sinusoidal response pattern of N was similar over the 2 years but the amplitudes varied due to differences in weather. Interactions between uncharacteristically high rainfall and a sandy field soil may have minimized discernable effects of the other covariates. The results demonstrated how the statistical analysis of potato response to a patterned application of nitrogen fertilizer can take advantage of spatial correlations to understand the response of potato to nitrogen application over larger areas.