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571.
Journal of Polymers and the Environment - In this study, a novel bead form IPN type resin comprising poly (2-Dimethylaminoethyl) methacrylate and carboxymethyl chitosan networks with a high dye... 相似文献
572.
Y.F. Khalil 《Journal of Loss Prevention in the Process Industries》2013,26(1):96-103
This paper discusses the results of an experimental program carried out to determine dust cloud deflagration parameters of selected solid-state hydrogen storage materials, including complex metal hydrides (sodium alanate and lithium borohydride/magnesium hydride mixture), chemical hydrides (alane and ammonia borane) and activated carbon (Maxsorb, AX-21). The measured parameters include maximum deflagration pressure rise, maximum rate of pressure rise, minimum ignition temperature, minimum ignition energy and minimum explosible concentration. The calculated explosion indexes include volume-normalized maximum rate of pressure rise (KSt), explosion severity (ES) and ignition sensitivity (IS). The deflagration parameters of Pittsburgh seam coal dust and Lycopodium spores (reference materials) are also measured. The results show that activated carbon is the safest hydrogen storage media among the examined materials. Ammonia borane is unsafe to use because of the high explosibility of its dust. The core insights of this contribution are useful for quantifying the risks associated with use of these materials for on-board systems in light-duty fuel cell-powered vehicles and for supporting the development of hydrogen safety codes and standards. These insights are also critical for designing adequate safety features such as explosion relief venting and isolation devices and for supplementing missing data in materials safety data sheets. 相似文献
573.
Experimental and theoretical studies were conducted to investigate the pyrophoricity and water-reactivity risks associated with employing sodium alanate (NaAlH4) complex metal hydride in on-board vehicular hydrogen (H2) storage systems. The ignition and explosivity of NaAlH4 upon exposure to oxidizers in air or water were attributed to the spontaneous formation of stable hydroperoxyl intermediates on the NaAlH4 surface and/or H2 production, as well as the large driving force for NaAlH4 conversion to favorable hydroxide products predicted by atomic and thermodynamic modeling. The major products from NaAlH4 exposure to air: NaAl(OH)4, gibbsite and bayerite Al(OH)3, and Na2CO3 observed by XRD, were identified to be formed by surface-controlled reactions. The reactivity risks were significantly minimized, without compromising de-/re-hydrogenation cyclability, by compacting NaAlH4 powder into wafers to reduce the available surface area. These core findings are of significance to risk mitigation and H2 safety code and standard development for the safe use of NaAlH4 for on-board H2 storage in light-duty vehicles. 相似文献
574.
575.
Tan K Yang MX Radloff SE Hepburn HR Zhang ZY Luo LJ Li H 《Die Naturwissenschaften》2008,95(12):1165-1168
Although the structure of the dance language is very similar among species of honeybees, communication of the distance component
of the message varies both intraspecifically and interspecifically. However, it is not known whether different honeybee species
would attend interspecific waggle dances and, if so, whether they can decipher such dances. Using mixed-species colonies of
Apis cerana and Apis mellifera, we show that, despite internal differences in the structure of the waggle dances of foragers, both species attend, and act
on the information encoded in each other’s waggle dances but with limited accuracy. These observations indicate that direction
and distance communication pre-date speciation in honeybees. 相似文献
576.
Arsenic speciation for the phytoremediation by the Chinese brake fern, Pteris vittata 总被引:1,自引:0,他引:1
Arsenic (As) speciation for the phytoremediation by the Chinese brake fern was studied. In particular, the mechanism of how plants induce compounds containing thiol (SH) and proteins by As exposure in terms of the relationship between As and phosphate uptaken into plant cells was examined. Pteris vittata callus could efficiently reduce As(V) to As(III) by the rapid introduction of reductase and synthesize thiols leading to phytochelatins production. Furthermore, Pteris vittata could control phosphate concentration in the cells corresponding to the concentration of arsenite and arsenate. To our best knowledge, this is the first report to show the mechanisms of such high As tolerance of Pteris vittata using their callus in terms of in vitro approach for the analysis of As speciation and metabolism route. 相似文献
577.
Hourly concentrations of TSP, PM(10), PM(2.5) near the surface at Seoul city were examined from March 20 to March 25, 2001 (duststorm event) in order to investigate the effect of a duststorm generated in China on the local aerosol concentration in Korea, The ratios of fine to coarse particles such as TSP to PM(10), TSP to PM(2.5) and PM(10)-PM(2.5) to PM(2.5) showed that a great amount of dust transported from the origin of the duststorm was remarkable with a maximum ratio of 9.77 between TSP and PM(2.5). Back trajectories every 6 h showed the movement of dust particles in the lower atmosphere near 500 m to 1500 m (atmospheric boundary layer), which implied transport from Baotou in inner Mongolia of northern China to the direction of Seoul city in Korea and then the back trajectories passed near the southern border of Mongolia and Baotou through Zengzhou in the midlevels (3000 m) and low levels (500 m) of China, finally reaching Seoul city. So, the TSP concentration at Seoul city was partially influenced by the duststorm, under the prevailing westerly wind and the transported aerosols could influence high concentrations of pollutants of TSP, PM(10) and PM(2.5) in Seoul. The sudden high concentrations of TSP and PM(10) were found for a few hours, especially at 1500 to 1800 LST, March 22. At 1200 LST, before the passage of a cold front through the Korean peninsula, the convective boundary layer (CBL) near Seoul was not shallow, but at 1500 LST, under the frontal passage, the CBL was remarkably thinner (less than 300 m), due to the compression of the boundary layer by the intrusion of cold air. This resulted in the increase of the TSP concentration, even though the mixed layer above maintained almost the same depth. At 1800 LST shortly after the frontal passage, that is, near sunset, the nocturnal cooling of the ground caused air parcels to cool, thereby enhancing the shallower nocturnal surface inversion layer and producing the maximum concentration of TSP of 1388 microg/m(3) near Seoul city. 相似文献
578.
Chang BU Koh SM Kim YJ Seo JS Yoon YY Row JW Lee DM 《Journal of environmental radioactivity》2008,99(3):455-460
A Nationwide survey on the natural radioactivity in industrial raw mineral commodities (17 kinds of domestic and 18 kinds of imported) that are representative minerals used in production and consumption in South Korea was conducted. The target industrial minerals can be categorized into two groups. The first group covers non-metallic and metallic raw minerals with low levels of radioactivity such as clay, silica sand, carbonates, bituminous and anthracite coal, iron ores, ilmenite, rutile, and phosphate ore. The other group comprises minerals with high levels of radioactivity including zircon and monazite. One hundred and sixty-four domestic and imported samples were analysed by gamma-ray spectroscopy using an HPGe detector. The (40)K content ranges from <0.00131 to 2.69Bq g(-1), and (226)Ra and (232)Th range over <0.0006 to 0.630 and <0.0008 to 0.474Bq g(-1), respectively. There was no anthropogenic radioactive signal in any of the samples. 相似文献
579.
Vichot L Boyer C Boissieux T Losset Y Pierrat D 《Journal of environmental radioactivity》2008,99(10):1636-1643
In order to quantify tritium impact on the environmental, we studied vegetation continuously exposed to a tritiated atmosphere. We chose lichens as bio-indicators, trees for determination of past tritium releases of the Valduc Centre, and lettuce as edible vegetables for dose calculation regarding neighbourhood. The Pasquill and Doury models from the literature were tested to estimate tritium concentration in the air around vegetable for distance from the release point less than 500m. The results in tree rings show that organically bound tritium (OBT) concentration was strongly correlated with tritium releases. Using the GASCON model, the modelled variation of OBT concentration with distance was correlated with the measurements. Although lichens are recognized as bio-indicators, our experiments show that they were not convenient for environmental surveys because their age is not definitive. Thus, tritium integration time cannot be precisely determined. Furthermore, their biological metabolism is not well known and tritium concentration appears to be largely dependent on species. An average conversion rate of HTO to OBT was determined for lettuce of about 0.20-0.24%h(-1). Nevertheless, even if it is equivalent to values already published in the literature for other vegetation, we have shown that this conversion rate, established by weekly samples, varies by a factor of 10 during the different stages of lettuce development, and that its variation is linked to the biomass derivative. 相似文献
580.
Yu Sun Susanna T. Y. Tong Mao Fang Y. Jeffrey Yang 《Environment, Development and Sustainability》2013,15(6):1495-1515
The Las Vegas Valley metropolitan area is one of the fastest growing areas in the southwestern United States. The rapid urbanization has presented many environmental challenges. For instance, as population growth and urbanization continue, the supply of sufficient clean water will become a concern. In addition, the area is also experiencing the longest drought in history, and the volume of water storage in Lake Mead, the main fresh water supply for the entire region, has been reduced greatly. The water quality in the main stem of the Las Vegas Wash (LVW) and Lake Mead may also be significantly affected. In order to develop effective sustainable management plans, the very first step is to predict the plausible future urbanization and land use patterns. This paper presents an approach to predict the future land use pattern at the LVW watershed using a Markov cellular automata model. The multi-criteria evaluation was used to couple population density as a variable depicting the driving force of urbanization in the model. Moreover, landscape metrics were used to analyze land use changes in order to better understand the dynamics of urban development in the LVW watershed. The predicted future land use maps for the years 2030 and 2050 show substantial urban development in the area, much of which are located in areas sensitive to source water protections. The results of the analysis provide valuable information for local planners and policy makers, assisting their efforts in constructing alternative sustainable urban development schemes and environmental management strategies. 相似文献