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51.
Mleczek Mirosław Magdziak Zuzanna Gąsecka Monika Niedzielski Przemysław Kalač Pavel Siwulski Marek Rzymski Piotr Zalicka Sylwia Sobieralski Krzysztof 《Environmental science and pollution research international》2016,23(20):20609-20618
Environmental Science and Pollution Research - The aim of the study was to (i) investigate the potential of edible mushroom Boletus badius (Fr.) Fr. to accumulate 53 elements from unpolluted acidic... 相似文献
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Stepnowski P Storoniak P 《Environmental science and pollution research international》2005,12(4):199-204
- Aims and Background. Ionic liquid application in industry will offer several excellent solutions, but it also means that they
will enter the environment sooner or later. Responsible product design should always take into consideration not only technological
demands, but also the risks arising out of possible toxicity and ecotoxicity. In our strategy we are aiming to understand
the fate of these entities through their life cycle in the environment as a complimentary element of their design. This paper
presents results on the lipophilicity of selected imidazolium ionic liquids, a parameter that plays a key role in environmental
and biological distribution. Additionally, the prediction of the most stable metabolite of a 1-butyl-3-methylimidazolium (BMIM)
cation – a congener representative of this group of compounds is presented.
Materials and Methods Lipophilicity was evaluated by means of reversed phase and immobilized artificial membrane chromatography and further compared
to calculated data. Theoretical prediction of lipophilicity was undertaken using fragmental methodology combined with manual
calculations of the geometric bond factor for quaternary ammonium and the electronic bond factor due to the presence of a
charge.
Results and Discussion All the substances studied are characterized by very low partition coefficients, and lipophilicity varies linearly with elongation
of the n-alkyl chain. Prediction of metabolic routes was based solely on thermodynamic data of the radical intermediates formed
during the reaction with the cytochrome P450 system. The energetically most stable radical structure is generated by hydrogen
abstraction from the gamma position of the BMIM cation.
Conclusions and Recommendations. The experimentally measured and theoretically estimated lipophilicity coefficients obtained for all the
compounds studied generally indicate a relatively low lipophilicity and thus preferable partition to the aqueous phase. By
means of thermodynamic data, it was also confirmed that the energetically most stable radical structure is generated by hydrogen
abstraction from the gamma position on the alkyl chain in the 1-alkyl-3-methylimidazolium cation, as a result of which the
C1 atom is preferentially oxidized.
- * The basis of this peer-reviewed paper is a presentation at the 9th FECS Conference on 'Chemistry and Environment', 29 August
to 1 September 2004, Bordeaux, France. 相似文献
55.
This paper examines the phenology and biometrics of Bluethroats staging in the Eilat region. This is of special interest because
of the extreme conditions with which this temperate zone breeding species has to contend because Eilat is a desert habitat
and is the last green area before the crossing of the deserts in autumn or after it in spring. Data were collected during
20 spring and 18 autumn migration seasons in the years 1984–2003, and a total of 7,464 Bluethroat were recorded. The number
of trapped birds was much higher in autumn than in spring. The majority of Bluethroats caught in both the autumn and spring
migrations were juveniles. We found differences in sex ratio in the individual age classes only in the autumn wherein among
both adults and juveniles, males were in greater numbers. We also found significant differences in the dates of ringed birds
from different sex–age classes in the spring and in autumn migrations. In spring, males from both age classes were caught
earlier than females. In autumn, adult birds arrived earlier than juveniles. We think that it is important to identify and
conserve the high quality stopover habitats such as Eilat wherein not only Bluethroats have been shown to stopover but also
several hundred other species. 相似文献
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Preliminary Studies on Converting Agricultural Waste into Biodegradable Plastics – Part III: Sawdust
Christopher?H.?SchillingEmail author Piotr?Tomasik David?S.?Karpovich Bruce?Hart Jagdeep?Garcha Paul?T.?Boettcher 《Journal of Polymers and the Environment》2005,13(2):177-183
Summary Hardwood sawdust was derivatized either by carboxymethylation, glutaration, maleiation, phthallation, or succination in order to produce anionic materials suitable for complexation with soy protein isolate. Blending each derivative with soy protein isolate resulted in instant precipitation of gels. Infrared spectroscopy and differential scanning calorimetry suggested that each derivative formed a complex with protein. Reaction products could be dried into pellets exhibiting tensile strengths between 0.9–2.4 MPa, suggested that these materials could be promising candidates for biodegradable structural materials. 相似文献
58.
Studies of the effect of simulated acid rain on the ecological equilibrium of the soil system 总被引:1,自引:0,他引:1
Zofia Fischer Marek Angiel Piotr Bieńkowski Andrzej DowgiaŁŁo Urszula Focht 《Environmental monitoring and assessment》1996,41(1):1-65
Introduction to the problem of environmental pollution caused by acid depositions. Presentation of principles of the six-year field experiment with simulated acid rain. Short characteristics of particular parts of the series of papers. 相似文献
59.
Ewa Rudnik Maciej Pierzynka Piotr Handzlik 《Journal of Material Cycles and Waste Management》2016,18(2):318-328
The paper concerns a hydrometallurgical method for selective recovery of copper from low-grade electric and electronic wastes. The following consecutive stages were proposed: smelting of the scraps to produce Cu–Zn–Ag alloy, leaching of the alloy in ammoniacal solution, and selective copper electrowinning. Cu–Zn–Ag alloy was a polymetallic and five-phase system. It was leached in chloride, carbonate, sulfate and thiosulfate solutions. This resulted in the separation of the metals, wherein metallic tin and silver as well as lead salts remained in the slimes, while copper and zinc were transferred to the electrolyte. Copper was selectively recovered from the ammoniacal solutions by the electrolysis, leaving zinc ions in the electrolyte. The best conditions of the alloy treatment were obtained in the ammonia–carbonate system, where the final product was copper of high purity (99.9 %) at the current efficiency of 60 %. Thiosulfate solution was not applicable for the leaching of the copper alloy due to secondary reactions of the formation of copper(I) thiosulfate complexes and precipitation of copper(I) sulfide, both inhibiting dissolution of the metallic material. 相似文献
60.
Piotr Minias 《Behavioral ecology and sociobiology》2014,68(5):851-859
It has long been suggested that habitat structure affects how colonial birds are distributed within their nesting aggregations, but this hypothesis has never been formally tested. The aim of this study was to test for a correlated evolution between habitat heterogeneity and within-colony distributions of Ciconiiformes by using Pagel’s general method of comparative analysis for discrete variables. The analysis indicated that central-periphery gradients of distribution (high-quality individuals occupying central nesting locations) prevail in species breeding in homogeneous habitats. These were mainly ground-nesting larids and spheniscids, where clear central-periphery patterns were recorded in ca. 80 % of the taxa. Since homogeneous habitats provide little variation in the physical quality of nest sites, central nesting locations should be largely preferred because they give better protection against predators by means of more efficient predator detection and deterrence. By contrast, central-periphery gradients tended to be disrupted in heterogeneous habitats, where 75 % of colonial Ciconiiform species showed uniform patterns of distribution. Under this model of distribution, edge nest sites of high physical quality confer higher fitness benefits in comparison to low-quality central sites, and thus, high-quality pairs are likely to choose nest sites irrespectively of their within-colony location. Breeding in homogeneous habitats and uniform distribution patterns were identified as probable ancestral states in Ciconiiformes, but there was a significant transition rate from uniform to central-periphery distributions in species occupying homogeneous habitats. 相似文献