全文获取类型
收费全文 | 3359篇 |
免费 | 30篇 |
国内免费 | 174篇 |
专业分类
安全科学 | 107篇 |
废物处理 | 205篇 |
环保管理 | 290篇 |
综合类 | 595篇 |
基础理论 | 780篇 |
环境理论 | 3篇 |
污染及防治 | 1139篇 |
评价与监测 | 241篇 |
社会与环境 | 190篇 |
灾害及防治 | 13篇 |
出版年
2023年 | 17篇 |
2022年 | 71篇 |
2021年 | 40篇 |
2020年 | 24篇 |
2019年 | 38篇 |
2018年 | 117篇 |
2017年 | 51篇 |
2016年 | 79篇 |
2015年 | 86篇 |
2014年 | 90篇 |
2013年 | 268篇 |
2012年 | 94篇 |
2011年 | 160篇 |
2010年 | 142篇 |
2009年 | 154篇 |
2008年 | 160篇 |
2007年 | 190篇 |
2006年 | 143篇 |
2005年 | 124篇 |
2004年 | 145篇 |
2003年 | 141篇 |
2002年 | 115篇 |
2001年 | 243篇 |
2000年 | 144篇 |
1999年 | 71篇 |
1998年 | 40篇 |
1997年 | 47篇 |
1996年 | 34篇 |
1995年 | 40篇 |
1994年 | 43篇 |
1993年 | 41篇 |
1992年 | 30篇 |
1991年 | 35篇 |
1990年 | 27篇 |
1989年 | 32篇 |
1988年 | 20篇 |
1987年 | 17篇 |
1986年 | 18篇 |
1985年 | 15篇 |
1984年 | 18篇 |
1983年 | 22篇 |
1982年 | 22篇 |
1981年 | 16篇 |
1980年 | 11篇 |
1979年 | 13篇 |
1978年 | 12篇 |
1977年 | 8篇 |
1975年 | 12篇 |
1973年 | 9篇 |
1972年 | 10篇 |
排序方式: 共有3563条查询结果,搜索用时 15 毫秒
951.
Bioaccumulation of Hg, Cu, and Zn in the Azores triple junction hydrothermal vent fields food web 总被引:2,自引:0,他引:2
In this work, mercury (Hg), copper (Cu) and zinc (Zn) concentrations and tissue distribution are determined in seven benthic invertebrates species (the key species) from the Mid Atlantic Ridge (MAR) hydrothermal vent fields. The samples were collected from three hydrothermal vent fields – Menez Gwen, 840 m; Lucky Strike, 1700 m and Rainbow, 2300 m – near the Azores Triple Junction. These fields are characterized by different depths, geological context and chemical composition of the hydrothermal fluid, particularly the metal content, which is reflected by the metal concentrations in the organisms. Indeed, our results show that organisms from Menez Gwen presented the highest Hg concentrations, while those from Lucky Strike and Rainbow were richer in Cu and Zn. The potential transfer of these metals through two trophic links are also evaluated and include (1) the mussel Bathymodiolus azoricus and the commensal worm Branchipolynoe seepensis, and (2) three different species of shrimps and the crab Segonzacia mesatlantica. No evidence of Hg biomagnification in either of the vent food chains is clearly observed but an increase in Hg accumulation from prey to predator in the crustacean food chain. The same pattern was observed for Cu and Zn, even though these metals are not known to be generally biomagnified in food chains. 相似文献
952.
Relationship between chlorine consumption and chlorination by-products formation for model compounds 总被引:1,自引:0,他引:1
The objective of this research is to investigate the relationship between chlorine decay and the formations of disinfection by-products (DBP), including trichloromethane (TCM) and chloroacetic acid (CAA) in the presence of four model compounds, i.e., resorcinol, phloroglucinol, p-hydroxybenzoic acid, and m-hydroxybenzoic acid. The chlorine degradation in model compounds with OH and/or COOH functional groups were rapid after chlorination. The TCM yields of carboxylic group substituted compounds (3-hydroxybenzoic acid [3-HBA], 4-hydroxybenzoic acid [4-HBA]) were found to be lower than that of the m-dihydroxy substituted compounds. Phloroglucinol, with one more OH substitution group than resorcinol, tends to form significant amounts of CAA after chlorination. However, it was observed that with the COOH substitution of 3-HBA and 4-HBA tend to exhibit more CAA formation potential than resorcinol. The developed parallel second and first-order reaction model for chlorine demand has been successfully utilized for TCM, CAA and DBP formation modeling. A high correlation between CAA and TCM was observed for the model compounds. 相似文献
953.
Accumulation and distribution of polycyclic aromatic hydrocarbons in rice (Oryza sativa) 总被引:6,自引:0,他引:6
Tao S Jiao XC Chen SH Liu WX Coveney RM Zhu LZ Luo YM 《Environmental pollution (Barking, Essex : 1987)》2006,140(3):406-415
Various tissues of rice plants were sampled from a PAH contaminated site in Tianjin, China at different growth stages of the ripening period and analyzed for PAHs. PAHs were much higher in roots than in the exposed tissues. Grains and internodes accumulated much smaller amounts of PAHs than leaves, hulls or ear axes. No specific gradient trends along roots, stem, ear axes, and grains were observed, suggesting that systematic translocation among them is unlikely. Over the ripening period, PAH concentrations were increased in rice roots and decreased in most above-ground tissues. Significant correlations between PAH and lipid contents can only be observed during full mature stage. The spectra of individual PAH compounds in rice organs including roots were similar to those in air, rather than those in soil. There was also a significant correlation between bioconcentration factor (BCF, plant over air) and octanol/air partitioning coefficient (Koa). 相似文献
954.
Distributions and concentrations of PAHs in Hong Kong soils 总被引:19,自引:0,他引:19
Zhang HB Luo YM Wong MH Zhao QG Zhang GL 《Environmental pollution (Barking, Essex : 1987)》2006,141(1):107-114
Surface soil (0-10 cm) samples from 53 sampling sites including rural and urban areas of Hong Kong were collected and analyzed for 16 EPA priority polycyclic aromatic hydrocarbons (PAHs). Total PAH concentrations were in the range of 7.0-410 microg kg(-1) (dry wt), with higher concentrations in urban soils than that in rural soils. The three predominant PAHs were Fluoranthene, Naphthalene and Pyrene in rural soils, while Fluoranthene, Naphthalene and Benzo(b + k)fluoranthene dominated the PAHs of urban soils. The values of PAHs isomer indicated that biomass burning might be the major origin of PAHs in rural soils, but vehicular emission around the heavy traffic roads might contribute to the soil PAHs in urban areas. A cluster analysis was performed and grouped the detectable PAHs under 4 clusters, which could be indicative of the PAHs with different origins and PAHs affected by soil organic carbon contents respectively. 相似文献
955.
Effects of inoculation of plant growth-promoting rhizobacteria on metal uptake by Brassica juncea 总被引:8,自引:0,他引:8
A greenhouse study was carried out with Brassica juncea to critically evaluate effects of bacterial inoculation on the uptake of heavy metals from Pb-Zn mine tailings by plants. Application of plant growth-promoting rhizobacteria, including nitrogen-fixing bacteria and phosphate and potassium solubilizers, might play an important role in the further development of phytoremediation techniques. The presence of these beneficial bacteria stimulated plant growth and protected the plant from metal toxicity. Inoculation with rhizobacteria had little influence on the metal concentrations in plant tissues, but produced a much larger above-ground biomass and altered metal bioavailability in the soil. As a consequence, higher efficiency of phytoextraction was obtained compared with control treatments. 相似文献
956.
Moon HS Kahng HY Kim JY Kukor JJ Nam K 《Environmental pollution (Barking, Essex : 1987)》2006,140(3):536-545
Biodegradation potentials of polycyclic aromatic hydrocarbons (PAHs) were determined with soil samples collected from various depths of a PAH-contaminated site and of a site nearby where PAHs were not found. Putative dioxygenase genes were amplified by a primer set specific for initial dioxygenases and identified by web-based database homology search. They were further categorized into several groups of which four dioxygenases were selected as probes for DNA hybridization. The hybridization signals according to the presence of putative dioxygenases were positively related to the extent of PAH contamination. However, the signal intensities varied depending on the probes hybridized and moreover were not consistent with PAH biodegradation activities determined by CO2 evolution. Despite widely accepted advantages of molecular biodegradation assessment, our data clearly present the variations of assessment results depending on the genetic information used and suggest that the methodology may tend to underestimate the real biodegradation capacity of a site probably due to the limited dioxygenase database available at the moment. Therefore, the molecular assessment of biodegradation potential should involve a very careful primer and probe design and an extensive microbiological examination of a site of interest to accurately delineate the biodegradation potential of the site. 相似文献
957.
Studies of mercury pollution in a lake due to a thermometer factory situated in a tourist resort: Kodaikkanal, India 总被引:2,自引:0,他引:2
Karunasagar D Balarama Krishna MV Anjaneyulu Y Arunachalam J 《Environmental pollution (Barking, Essex : 1987)》2006,143(1):153-158
Kodaikkanal, India, suffered mercury contamination due to emissions and waste from a thermometer factory. Kodai Lake is situated to the north of the factory. The present study determined mercury in waters, sediment and fish samples and compared the values with those from two other lakes, Berijam and Kukkal. Total mercury (Hg(T)) of 356-465 ng l(-1), and 50 ng l(-1) of mercury in methyl mercury form were seen in Kodai waters while Berijam and Kukkal waters showed significantly lower values. Kodai sediment showed 276-350 mg/kg Hg(T) with about 6% methyl mercury. Berijam and Kukkal sediments showed Hg(T) of 189-226 mg/kg and 85-91 mg/kg and lower methylation at 3-4% and 2%, respectively. Hg(T) in fish from Kodai lake ranged from 120 to 290 mg/kg. The results show that pollution of the lake has taken place due to mercury emissions by the factory. 相似文献
958.
The effect of the presence of photosensitizers, methylene blue (MB) and rose Bengal (RB), on the degradation of carbofuran (2,3-dihydro-2,2-dimethylbenzofuran-7-yl methylcarbamate) in water in a solar photocatalytic system was investigated. It was found that as compared to MB, RB generally showed a stronger effect on the decomposition of carbofuran under comparable conditions. Among the conditions studied, adding 2 x 10(-6) M of RB, that corresponding to 2% of the initial concentration of carbofuran solution in the system, rendered the most effective degradation of carbofuran. As a result, a carbofuran removal percentage of 69.9%, a mineralization efficiency of 28.0%, and a microtoxicity reduction of 65.0% could be achieved. The degradation and mineralization of carbofuran was found to follow the pseudo-first order reaction kinetics. The decomposition mechanism of carbofuran was further investigated through identification of the intermediates to elaborate the influence of dye photosensitizer on the solar photocatalysis of carbofuran in water. On the basis of the intermediates identified, including carbofuran phenol, 3-hydroxy carbofuran phenol, and substituted alcohols (3-phenoxy 1-propanol, 2-ethyl 1-hexanol, 2-butoxyl ethanol), it appears that hydrolysis and hydroxylation were the two key mechanisms for decomposing carbofuran during the process of solar photocatalysis with the aid of dye photosensitizer. 相似文献
959.
Asawasinsopon R Prapamontol T Prakobvitayakit O Vaneesorn Y Mangklabruks A Hock B 《Environment international》2006,32(4):554-559
It is now known that many organochlorines (OCs) act as endocrine disruptors, causing harmful effects on wildlife and humans. Several field and laboratory animal studies have reported that OCs cause adverse effects on thyroid hormone status. However, data regarding their effects on thyroid hormone status in humans are inconclusive. Because a developing fetus is especially sensitive to hormonal disruption by exposure to OCs, the adverse health effects on infants are of concern. The present study aimed to investigate the association between OC levels in maternal and cord serum, and the association between OC and thyroid hormone levels in cord serum. The study was performed with 39 mother-infant pairs from Mae Rim District of Chiang Mai Province, northern Thailand, who had normal delivery and full term gestation. Maternal blood was collected for measuring OCs and total lipids. Umbilical cord blood was collected for measuring OCs, total lipids, and thyroid hormones, including total thyroxine (TT(4)), free thyroxine (FT(4)), and thyroid stimulating hormone (TSH). 1,1-dichloro-2,2-di(4-chlorophenyl)ethylene (p,p'-DDE) had the highest level in all serum samples with a geometric mean of 1,191 ng/g lipids in maternal serum and 742 ng/g lipids in cord serum. The second highest level was that for 1,1,1-trichloro-2,2-di(4-chlorophenyl)ethane (p,p'-DDT), followed by 1,1-dichloro-2,2-di(4-chlorophenyl)ethane (p,p'-DDD). Levels of p,p'-DDE, p,p'-DDT, p,p'-DDD, and dieldrin in maternal serum were positively associated with levels in cord serum (r = 0.86, 0.77, 0.66, and 0.60, respectively; P<0.001). The important findings were that cord serum TT(4) levels were negatively associated with cord serum levels of p,p'-DDE (r = -0.37, P = 0.024), p,p'-DDT.3 (r = -0.33, P = 0.048), and 1,1-dichloro-2-(2-chlorophenyl)-2-(4-chlorophenyl)ethylene (o,p'-DDE) (r = -0.76, P = 0.019). These results therefore suggest that exposure to DDT and its metabolites during fetal development may cause some effects on thyroid hormonal status in infants. 相似文献
960.
McClellan Y August RA Gosz JR Gann S Parmenter RR Windsor M 《Journal of environmental radioactivity》2006,86(2):199-211
Vertical soil characterization and migration of radionuclides were investigated at four radioactively contaminated sites on Kirtland Air Force Base (KAFB), New Mexico to determine the vertical downward migration of radionuclides in a semi-arid environment. The surface soils (0-15 cm) were intentionally contaminated with Brazilian sludge (containing (232)Thorium and other radionuclides) approximately 40 years ago, in order to simulate the conditions resulting from a nuclear weapons accident. Site grading consisted of manually raking or machine disking the sludge. The majority of the radioactivity was found in the top 15 cm of soil, with retention ranging from 69 to 88%. Two models, a compartment diffusion model and leach rate model, were evaluated to determine their capabilities and limitations in predicting radionuclide behavior. The migration rates of actinium were calculated with the diffusion compartment and the leach rate models for all sites, and ranged from 0.009 to 0.1 cm/yr increasing with depth. The migration rates calculated with the leach rate models were similar to those using the diffusion compartment model and did not increase with depth (0.045-0.076, 0.0 cm/yr). The research found that the physical and chemical properties governing transport processes of water and solutes in soil provide a valid radionuclide transport model. The evaluation also showed that the physical model has fewer limitations and may be more applicable to this environment. 相似文献