The impact of ozone on a salt marsh cordgrass (Spartina alterniflora)

Spartina alterniflora plants were collected from salt marshes within New Jersey, South Carolina, and Georgia USA and shipped to The Pennsylvania State University. New plants were grown from rhizomes in six open-top field chambers. Three chambers received charcoal-filtered air, and three received charcoal-filtered air plus 80 ppb ozone, 8 h/day for 65 days. Flower, leaf, and shoot number per plant were recorded weekly. Photosynthetic rates were measured in week 5, and foliar injury was assessed during week 9. Final dry weight of roots, shoots, and rhizomes were determined. While ozone-treated plants from all states expressed symptoms of ozone injury, plants from South Carolina exhibited no effect of ozone on any other measured variable. Plants from the Georgia site showed ozone-induced reductions in all measured variables except leaf dry weight. Ozone-treated plants from New Jersey showed reductions in photosynthetic rate, leaf and shoot number, and root dry weights. Only plants from New Jersey produced flowers, with ozone treatment causing delay in flowering and reduction in the number of flower spikes produced.     

Nitrate movement in shallow ground water from swine-lagoon-effluent spray fields managed under current application regulations

Rapid increases in the swine (Sus scrofa domestica) population in the 1990s and associated potential for nitrate N pollution of surface waters led the state of North Carolina to adopt stringent waste management regulations in 1993. Our objectives were to characterize (i) nitrate N movement from waste application fields (WAFs) in shallow ground water, and (ii) soil, hydrologic, and biological factors influencing the amount of nitrate N in the adjacent stream. A ground water monitoring study was conducted for 36 mo on a swine farm managed under new regulations. Water table contours and lack of vertical gradients indicated horizontal flow over most of the site. Nitrate N concentrations in water from shallow wells in WAFs averaged 30 +/- 19 mg L(-1) and delta15N ratios for nitrate N were between +20 and +25 per mil. Nitrate N concentration decreased from field-edge to streamside wells by 22 to 99%. Measurement of delta18O and delta15N enrichment of nitrate in ground water throughout the WAF-riparian system indicated that denitrification has not caused significant 15N enrichment of nitrate. Over a 24-mo period, delta15N ratios for nitrate N in the stream approached delta15N ratios for nitrate N in ground water beneath WAFs indicating delivery of some waste-derived nitrate N to the stream in shallow ground water. Nitrate N concentrations in the stream were relatively low, averaging 1 mg L(-1). Dilution of high nitrate N water in shallow horizontal flow paths with low nitrate N water from deeper horizontal flow paths at or near the stream, some denitrification as ground water discharges through the stream bottom, and some denitrification in riparian zone contributed to this low nitrate N concentration.     

Visitor impact on backcountry campsites in the Great Smoky Mountains

Over the last decade the Great Smoky Mountains National Park (GSMNP) has experienced a tremendous increase in visitation, especially in backcountry camping. In 1976 there were an estimated 117,500 backcountry visitor nights, with a peak of 16,865 visitor nights in April. The high use season extends from March to October. Visitation tends to be concentrated in certain sections of the park and at specific sites. The Appalachian Trail, which includes about 8 percent of the maintained trail mileage, carried 32 percent of the visitor nights in 1976.Campsite disturbance is also concentrated in specific sites and sections of the park. Maximum camping disturbance per km of maintained trail was 3,400 m² for the sites on the Appalachian Trail. Shelter sites have more visitation per site and more total disturbance per site than open campsites, but shelters tend to have less intensive disturbance, such as bare soil, because they concentrate trampling impacts. Visitation levels were strongly correlated with disturbances such as bare soil at open campsites. Visitation was significantly correlated to the number of firepits at shelter sites but not to other types of disturbance. Regressions indicate that for each additional visitor night at a site (annual average), one can expect an additional 9 m² of total disturbance and 1 m²of bare soil. The distance of a site from the nearest road was not significantly correlated with damage or visitation. Elevation was correlated to visitation levels, especially in the case of the shelters. More legal sites and large illegal sites are in mesic forest types. Illegal camping accounted for 10 percent of the total camping disturbance.The data imply that the suggested removal of shelters will require redistribution of visitor use or replacement developments, such as tent platforms, in order to mitigate damage. Zone camping is a possible alternative but presents difficulties because campers may concentrate in certain plant communities and topographic positions.     

Distribution of chromium contamination and microbial activity in soil aggregates

Biogeochemical transformations of redox-sensitive chemicals in soils can be strongly transport-controlled and localized. This was tested through experiments on chromium diffusion and reduction in soil aggregates that were exposed to chromate solutions. Reduction of soluble Cr(VI) to insoluble Cr(II) occurred only within the surface layer of aggregates with higher available organic carbon and higher microbial respiration. Sharply terminated Cr diffusion fronts develop when the reduction rate increases rapidly with depth. The final state of such aggregates consists of a Cr-contaminated exterior, and an uncontaminated core, each having different microbial community compositions and activity. Microbial activity was significantly higher in the more reducing soils, while total microbial biomass was similar in all of the soils. The small fraction of Cr(VI) remaining unreduced resides along external surfaces of aggregates, leaving it potentially available to future transport down the soil profile. Using the Thiele modulus, Cr(VI) reduction in soil aggregates is shown to be diffusion rate- and reaction rate-limited in anaerobic and aerobic aggregates, respectively. Thus, spatially resolved chemical and microbiological measurements are necessary within anaerobic soil aggregates to characterize and predict the fate of Cr contamination. Typical methods of soil sampling and analyses that average over redox gradients within aggregates can erase important biogeochemical spatial relations necessary for understanding these environments.     

Influence of arsenic co-contamination on DDT breakdown and microbial activity

The impacts of arsenic co-contamination on the natural breakdown of 1,1,l1-trichloro-2,2-bis(4-chlorophenyl)ethane (DDT) in soil are investigated in a study of 12 former cattle dip sites located in northeastern NSW, Australia. This study examines the relationship between the intrinsic breakdown of DDT to 1,1 -dichloro-2,2-bis(4-chlorophenyl)ethane (DDD) and 1,l-dichloro-2,2-bis(4-chlorophenyl)ethylene (DDE), and the impacts of arsenic co-contamination on this breakdown. Between-site analysis demonstrated that arsenic at 2000 mg/kg gave a 50% reduction in the concentration of DDD compared to background arsenic of 5 mg/kg.Within-site analysis also showed the ratio of DDT:DDD increased in soils as arsenic concentrations increased. This within-site trend was also apparent with the DDT:DDE ratio, suggesting inhibition of DDT breakdown by arsenic co-contamination. Microbial activity was inhibited as residues of total DDTs and arsenic increased. Hence arsenic co-contamination and high concentrations of DDT in soil may result in an increased persistence of DDT in the environment studied.     

Gaseous and particulate emissions from a DC arc melter

Tests treating soils contaminated with metal compounds and radionuclide surrogates were conducted in a DC arc melter. The soil melted, and glassy or ceramic waste forms with a separate metal phase were produced. Tests were run in the melter plenum with either air or N2 purge gases. In addition to nitrogen, the primary emissions of gases were CO2, CO, oxygen, methane, and oxides of nitrogen (NO(x)). Although the gas flow through the melter was low, the particulate concentrations ranged from 32 to 145 g/m3. Cerium, a nonradioactive surrogate for plutonium and uranium, was not enriched in the particulate matter (PM). The PM was enriched in cesium and highly enriched in lead.     

Prediction of the fate of radioactive material in the South Pacific Ocean using a global high-resolution ocean model

We investigate the release of radioactive contaminants from Moruroa Atoll in a global high-resolution off-line model. The spread of tracer is studied in a series of simulations with varying release depths and time-scales, and into ocean velocity fields corresponding to long-term annual mean, seasonal, and interannually varying scenarios. In the instantaneous surface release scenarios we find that the incorporation of a seasonal cycle greatly influences tracer advection, with maximum concentrations still found within the French Polynesia region after 10 years. In contrast, the maximum trace is located in the southeast Pacific when long-term annual mean fields are used. This emphasizes the importance of the seasonal cycle in models of pollution dispersion on large scales. We further find that during an El Ni?o/Southern Oscillation (ENSO) event reduced currents in the region of Moruroa Atoll result in increased concentrations of radioactive material in French Polynesia, as direct flushing from the source is reduced. In terms of the sensitivity to tracer release time-rates, we find that a gradual input results in maximum concentrations in the near vicinity of French Polynesia. This contrasts the instantaneous-release scenarios, which see maximum concentrations and tracer spread across much of the South Pacific Ocean. For example, in as little as seven years radioactive contamination can reach the east coast of Australia diluted by only a factor of 1,000 of the initial concentration. A comparison of results is made with previous studies. Overall, we find much higher concentrations of radionuclides in the South Pacific than has previously been predicted using coarser-resolution models.     

STATIC WATER LEVEL MAPPING IN EAST CENTRAL MICHIGAN1

ABSTRACT: This paper presents a methodology for preparing a static water level map using a sample of water level measurements obtained from the well log records of private wells that are finished in glacial drift. The test was conducted in Tyrone Township, located in east central Michigan. A variety of selection criteria were examined and the resulting maps were compared with a ground truth map that was prepared from water level measurements obtained in the field. The map prepared from a random sample of wells at a density of two points per section best approximates the ground truth map. Using a sample of records from the Michigan Statewide Groundwater Database to create static water levels that are used in community ground water vulnerability analyses will provide a more accurate map than using the complete dataset or other selection criteria based on temporal groupings or seasonality.     

The Roles of Photooxidation and Biodegradation in Long-term Weathering of Crude and Heavy Fuel Oils

Although spilled oil is subject to a range of natural processes, only combustion, photooxidation and biodegradation destroy hydrocarbons and remove them from the biosphere. We present laboratory data that demonstrate the molecular preferences of these processes, and then examine some oil residues collected from previously documented releases to confirm the important roles that these processes play in removing spilled oil from both marine and terrestrial environments.     

MULTISCALE INFLUENCES ON PHYSICAL AND CHEMICAL STREAM CONDITIONS ACROSS BLUE RIDGE LANDSCAPES1

ABSTRACT: Streams integrate biogeochemical processes operating at broad to local spatial scales and long term to short term time scales. Humans have extensively altered those processes in North America, with serious consequences for aquatic ecosystems. We collected data on Upper Tennessee River tributaries in North Carolina to: (1) compare landuse and landscape geomorphology with respect to their ability to explain variation in water quality, sedimentation measures, and large woody debris; (2) determine if landscape change over time contributed significantly to explaining present stream conditions; and (3) assess the importance of spatial scale in examining landuse influences on streams. Stream variables were related to both landuse and landscape geomorphology. Forest cover accounted for the most variation in nearly all models, supporting predictions of nutrient enrichment, thermal pollution, and sedimentation caused by landscape disturbance. Legacy effects from past catchment disturbance were apparent in sedimentation measures. Nitrogen and phosphorus concentrations, as well as stream temperature, were lower where riparian buffers had reforested. Models of stream physicochemistry fit better when predictors were catchment wide rather than more localized (i.e., within 2 km of a site). Cumulative impacts to streams due to changes in landuse must be managed from a watershed perspective with quantitative models that integrate across scales.