Sources and Sinks of Phosphorus for a Perturbed Stream and the Effects of Mineral Deposits1

Effler, Steven W., Anthony R. Prestigiacomo, David A. Matthews, and Feng Peng, 2012. Sources and Sinks of Phosphorus for a Perturbed Stream and the Effects of Mineral Deposits. Journal of the American Water Resources Association (JAWRA) 48(2): 321‐335. DOI: 10.1111/j.1752‐1688.2011.00617.x Abstract: Patterns of concentrations and loading rates of multiple forms of phosphorus (P) are resolved and analyzed along Ninemile Creek, New York, a stream perturbed by a domestic waste discharge and residual effects of a closed industry. This analysis is based on biweekly monitoring of total, dissolved, and soluble reactive P (SRP) for 19 months at four sites that bracket each of these effects, and 15 years of biweekly measurements at the two sites that bound industrial deposits. The minerogenic particle populations of the stream and the surficial sediments along the reach with extensive CaCO₃ and clay mineral deposits are characterized with an individual particle analysis technique. Mass balance analyses depict: (1) increasing nonpoint inputs of particulate and dissolved organic P along the stream length; (2) input of P from a domestic waste facility, almost entirely in the form of SRP; and (3) a compensating downstream loss of SRP over the reach with the extensive industrial deposits of CaCO₃. The downstream sink process for SRP is attributed to sorption processes with minerogenic deposits. The domestic waste‐based source and the compensating industrial waste‐based sink are noteworthy fluxes relative to other prevailing loads received by downstream Onondaga Lake, for which a major rehabilitation program targeting cultural eutrophication is underway. The P source/sink conditions of this stream are considered in the context of this rehabilitation program.     

Observations and Modeling of Stream Plunging in an Urban Lake1

Owens, Emmet M., Steven W. Effler, Anthony R. Prestigiacomo, David A. Matthews, and Susan M. O’Donnell, 2012. Observations and Modeling of Stream Plunging in an Urban Lake. Journal of the American Water Resources Association (JAWRA) 48(4): 707‐721. DOI: 10.1111/j.1752‐1688.2012.00646.x Abstract: The plunging behavior of two tributaries in Onondaga Lake, New York, is quantified based on a program of monitoring, process studies, and modeling. The dynamics of buoyancy of the tributaries are resolved with hourly measurements of temperature (T), specific conductance (SC), and turbidity (Tn) at the mouths, and observations every 6 h in the lake. Negative buoyancy of the tributaries is found to diminish and change rapidly during runoff events compared to dry periods. In‐lake patterns of the transport of plunging inflow are resolved for dry weather conditions using a dye tracer, and following a runoff event through measurements of T, SC, and Tn. The hydrodynamic/transport model ELCOM (Estuary Lake and Coastal Ocean Model) is demonstrated to perform well in simulating these patterns. Analyses conducted with the model establish the importance of diurnal effects and in‐lake mixing mediated by wind, the need for temporally detailed measurements during runoff events, and modifications of the plunging behavior of the urban tributary as it passes through a harbor. The model provides critical information to support rehabilitation programs for the lake by quantifying the transport of the two largest tributaries, particularly the distribution of the loads between the upper waters and stratified layers. The model predicts that 10% of the urban tributary load enters the upper waters of the lake within 24 h for a dry weather period; this portion increases to 30% for a runoff event.     

Sediment influence on congener-specific PCB bioaccumulation by Mytilus edulis: a case study from an intertidal hot spot, Clyde Estuary, UK

An intertidal site in the Clyde Estuary, UK, was selected to evaluate the role of sediment geochemistry on the bioaccumulation of polychlorinated biphenyls (PCBs) by mussels (Mytilus edulis). The area had previously been identified as showing anomalously high levels of PCB contamination (over 1,500 microg kg(-1) total PCB in sediment, 22 congeners). Samples of surface sediment and M. edulis were collected from two closely located sites, one within the anomalous area and another representing typical PCB contamination in the estuary. Sediment samples were separated into grain size fractions and analysed for a range of biomarker compounds, PCBs and sediment mineralogy. The anomalous site showed an atypical association of PCBs with sediment properties, despite both locations showing influence of both petrogenic and pyrogenic organic contamination. Interrogation of data using correlation and principal component analysis showed that sediment mineralogy as well as organic matter composition influenced PCB congener distribution. One sediment source was found to control the PCB concentration in mussels at both locations and clay mineralogy appears to control PCB uptake by biota with preference for higher molecular weight congeners. Overall bioavailability is determined by sediment TOC.     

Economics-Oriented Discourse Strategies in Environmental Advocacy

Scholars and practitioners are engaging in a fierce debate over the implications of using market-based discourse in communicating environmental problems and solutions. However, there has been less attention to exactly who is using such economic discourse and how it is combined with other discourses. Prior researchers have proposed tripartite frameworks for categorizing discursive strategies around pro-economic, anti-economic, and non-economic metaphors, which are here applied to eight U.S. environmental advocacy organizations’ press releases. An original text-analytic dictionary of pro-economic, anti-economic, and non-economic discourse is used to distinguish between the proposed discourse strategies. This analysis indicates that economics-oriented discourse strategies are more complex and varied than previously suggested. A more nuanced framework is proposed.     

Increase in phosphorus losses from grassland in response to Olsen-P accumulation

The Olsen-P status of grazed grassland (Lolium perenne L.) swards in Northern Ireland was increased over a 5-yr period (March 2000 to February 2005) by applying different rates of P fertilizer (0, 10, 20, 40, or 80 kg P ha(-1) yr(-1)) to assess the relationship between soil P status and P losses in land drainage water and overland flow. Plots (0.2 ha) were hydrologically isolated and artificially drained to v-notch weirs, with flow proportional monitoring of drainage water and overland flow. Annually, the collectors for overland flow intercepted between 11 and 35% of the surplus rainfall. Single flow events accounted for up to 52% of the annual dissolved reactive phosphorus (DRP) load. The Olsen-P status of the soil influenced DRP and total phosphorus (TP) concentrations in land drainage water and overland flow. Annual TP loss was highly variable and ranged from 0.19 to 1.55 kg P ha(-1) yr(-1) for the plot receiving no P fertilizer and from 0.35 to 2.94 kg P ha(-1) yr(-1) for the plot receiving 80 kg P ha(-1) yr(-1). Despite the Olsen-P status in the soils ranging from 22 to 99 mg P kg(-1), after 5 yr of fertilizer P applications it was difficult to identify a clear Olsen-P concentration at which P losses increased. Any relationship was confounded by annual variability of hydrologic events and flows and by hydrologic differences between plots. Withholding P fertilizer for over 5 yr was not long enough to lower P losses or to have an adverse effect on herbage P concentrations.     

A longitudinal examination of role overload and work–family conflict: The mediating role of interdomain transitions

Through the lens of boundary theory, we examine whether the relationship between role overload and work–family conflict is explained by the use of interdomain transitions. With a sample of 250 working adults, we examined whether individuals respond to role overload by engaging in interdomain transitions and how the frequency of these transitions influences work–family conflict both concurrently and over time. Results support our expectation that at a given time, interdomain transitions function as an episodic coping mechanism with short‐term costs (greater work–family conflict) and benefits (less role overload). Also, engaging in interdomain transitions was an explanatory variable linking role overload and work–family conflict. We expected that, over time, engaging in interdomain transitions would function as a preventive coping mechanism, serving to reduce role overload. Interestingly though, several of the longitudinal hypotheses were counter to prediction. Our findings provide further evidence for the use of boundary theory in examinations of the work–family interface. Insights on areas within the literature that require further theoretical development are discussed, along with a consideration of the application of emerging methodologies within our empirical designs. Copyright © 2013 John Wiley & Sons, Ltd.     

Predicting support for non‐pharmaceutical interventions during infectious outbreaks: a four region analysis

Non‐pharmaceutical interventions (NPIs) are an important public health tool for responding to infectious disease outbreaks, including pandemics. However, little is known about the individual characteristics associated with support for NPIs, or whether they are consistent across regions. This study draws on survey data from four regions—Hong Kong, Singapore, Taiwan, and the United States—collected following the Severe Acute Respiratory Syndrome (SARS) outbreak of 2002–03, and employs regression techniques to estimate predictors of NPI support. It finds that characteristics associated with NPI support vary widely by region, possibly because of cultural variation and prior experience, and that minority groups tend to be less supportive of NPIs when arrest is the consequence of noncompliance. Prior experience of face‐mask usage also results in increased support for future usage, as well as other NPIs. Policymakers should be attentive to local preferences and to the application of compulsory interventions. It is speculated here that some public health interventions may serve as ‘gateway’ exposures to future public health interventions.     

Climate change impact on distribution and abundance of wildlife species: an analytical approach using GIS

An analytical approach to modelling the likely impact of climate change on the distribution and abundance of wildlife species is described using examples from Scotland. Data for present day distribution of wildlife and habitat are analysed using map data describing geographic variation in climatic factors. Climate data for the present day and under specified scenarios of change are themselves modelled within a GIS; climate modelling uses meteorological station data, climate change scenarios developed from GCMs and a variety of spatial interpolation techniques. The analytical procedure generates hypotheses defining ecological relationships between species distribution and climatic factors (monthly, seasonal and annual data). These relationships are then used to model the distribution of the species directly from climate and predict impacts of climate change. The analysis takes account of both direct impacts of climate on wildlife and indirect effects manifested through habitat response to climate change. The analytical procedure is implemented as a generic tool for inductive spatial analysis in GIS.     

Trace element analysis of soil samples from a stratified archaeological site

Thirty-eight soil samples from a sondage excavated through a 6- metre stratified tell (Gomoiava, in central Yugoslavia) have been analysed for nine biophile elements: Mg, Sr, Zn, Cu, Ni, Mn, Cr, Pb and B. The site was occupied from 7000 BC to 500 AD (calendar years). The results have been collated with earlier estimates of P and Ca, made on a larger series of samples from the same site. The results are discussed in terms of useful information, to supplement that given by phosphate analysis, about stratification and the relationship of the settlement to its environment.It is concluded that leaching probably distorts the results for Ca and Mg. The results for Mn may help to distinguish phosphate accumulation due to man from that due to farm livestock. There is significant accumulation of Sr and B, both of which have potential value, although some of the analytical results for the latter are suspect. The results for Zn, Cu and Ni are highly correlated, with sharp peaks which couid provide precise information about individual strata when more experience of interpretation has been gained. Only Cr and Pb appear to provide little useful information at this site.     

Impact of heating and air conditioning system operation and leakage on ventilation and intercompartment transport: studies in unoccupied and occupied Tennessee Valley homes

Forced-air heating and air conditioning (HAC) systems caused an average and maximum increase in air infiltration rates of 1.8- and 4.3-fold, respectively, during brief whole-house studies of tracer gas decay in 39 occupied houses. An average increase in air infiltration rate of 0.33 +/- 0.37 h-1 corresponded to an incremental air leak of 240 m3/h, based on approximate house volume. More detailed tracer gas decay studies were performed in basement, kitchen and bedroom locations of six homes with low air infiltration rates (i.e., less than 0.25 h-1). The HAC mixed the indoor air efficiently between measurement sites. HAC operation also caused 1.1- to 3.6-fold increases in air infiltration rates, corresponding to absolute increases of 0.02 to 0.1 h-1. In an unoccupied research house, three-fold increases in average air infiltration rate with HAC operation (i.e., from 0.13 to 0.36 h-1) were reduced to two-fold (i.e., from 0.10 to 0.18 h-1) by sealing the external HAC unit and crawlspace ductwork system. This sealing also resulted in a 30 percent reduction in crawlspace-to-indoor transport rates with the HAC turned on. Blower door tests indicated a less than 20 percent reduction in house leakage area.