Comparative study of measured and modelled number concentrations of nanoparticles in an urban street canyon

This study presents a comparison between measured and modelled particle number concentrations (PNCs) in the 10–300 nm size range at different heights in a canyon. The PNCs were modelled using a simple modelling approach (modified Box model, including vertical variation), an Operational Street Pollution Model (OSPM) and Computational Fluid Dynamics (CFD) code FLUENT. All models disregarded any particle dynamics. CFD simulations have been carried out in a simplified geometry of the selected street canyon. Four different sizes of emission sources have been used in the CFD simulations to assess the effect of source size on mean PNC distributions in the street canyon. The measured PNCs were between a factor of two and three of those from the three models, suggesting that if the model inputs are chosen carefully, even a simplified approach can predict the PNCs as well as more complex models. CFD simulations showed that selection of the source size was critical to determine PNC distributions. A source size scaling the vehicle dimensions was found to better represent the measured PNC profiles in the lowest part of the canyon. The OSPM and Box model produced similar shapes of PNC profile across the entire height of the canyon, showing a well-mixed region up to first ≈2 m and then decreasing PNCs with increased height. The CFD profiles do correctly reproduce the increase from road level to a height of ≈2 m; however, they do not predict the measured PNC decrease higher in the canyon. The PNC differences were largest between idealised (CFD and Box) and operational (OSPM) models at upper sampling heights; these were attributed to weaker exchange of air between street and roof-above in the upper part of the canyon in the CFD calculations. Possible reasons for these discrepancies are given.     

Adaptive urban governance: new challenges for the second generation of urban adaptation strategies to climate change

The task of adapting cities to the impacts of climate change is of great importance—urban areas are hotspots of high risk given their concentrations of population and infrastructure; their key roles for larger economic, political and social processes; and their inherent instabilities and vulnerabilities. Yet, the discourse on urban climate change adaptation has only recently gained momentum in the political and scientific arena. This paper reviews the recent climate change adaptation strategies of nine selected cities and analyzes them in terms of overall vision and goals, baseline information used, direct and indirect impacts, proposed structural and non-structural measures, and involvement of formal and informal actors. Against this background, adaptation strategies and challenges in two Vietnamese cities are analyzed in detail, namely Ho Chi Minh City and Can Tho. The paper thereby combines a review of formalized city-scale adaptation strategies with an empirical analysis of actual adaptation measures and constraints at household level. By means of this interlinked and comparative analysis approach, the paper explores the achievements, as well as the shortcomings, in current adaptation approaches, and generates core issues and key questions for future initiatives in the four sub-categories of: (1) knowledge, perspectives, uncertainties and key threats; (2) characteristics of concrete adaptation measures and processes; (3) interactions and conflicts between different strategies and measures; (4) limits of adaptation and tipping points. In conclusion, the paper calls for new forms of adaptive urban governance that go beyond the conventional notions of urban (adaptation) planning. The proposed concept underlines the need for a paradigm shift to move from the dominant focus on the adjustment of physical structures towards the improvement of planning tools and governance processes and structures themselves. It addresses in particular the necessity to link different temporal and spatial scales in adaptation strategies, to acknowledge and to mediate between different types of knowledge (expert and local knowledge), and to achieve improved integration of different types of measures, tools and norm systems (in particular between formal and informal approaches).     

Regional carbon footprints of households: a German case study

Households are either directly or indirectly responsible for the highest share of global anthropogenic greenhouse gas emissions. Hence, programs helping to improve human consumption habits have been identified as a comparatively cost-effective way to reduce household emissions significantly. Recently, various studies have determined strong regional differences in household carbon footprints, yet a case study for Germany has not been conducted. Local information and policies directed at household consumption in Germany thus devoid of any foundation. In this paper, we analyze the impact of different criteria such as location, income and size on household carbon footprints in Germany and demonstrate how the impact of GHG mitigation opportunities varies for different population segments. We use a multi-region input output hybrid LCA approach to developing a regionalized household carbon footprint calculator for Germany that considers 16 sub-national regions, 15 different household sizes, and eight different income and age categories. The model reveals substantial regional differences in magnitude and composition of household carbon footprints, essentially influenced by two criteria: income and size. The highest income household is found to emit 4.25 times as much CO₂e than the lowest. We identify indirect emissions from consumption as the largest share of household carbon footprints, although this is subject to fluctuation based on household type. Due primarily to local differences in vehicle availability, income and nutrition, an average household in Baden-Wuerttemberg is found to have 25 % higher carbon footprint than its Mecklenburg-West Pomeranian counterpart. Based on the results of this study, we discuss policy options for household carbon mitigation in Germany.     

Acute and chronic toxicity of benzotriazoles to aquatic organisms

Purpose

Resulting from their intensive use as corrosion inhibitors in aircraft deicing and anti-icing fluids (ADAF) and for silver protection in dishwasher detergents benzotriazoles (BTs) are widespread in European surface waters. The current study aimed on an ecotoxicological characterization of 1H-benzotriazole (1H-BT) and 5-methyl-1H-benzotriazole (5MBT).

Methods

Acute and chronic OECD guideline tests were conducted with primary producers (Desmodesmus subspicatus, Lemna minor) and two daphnia species (Daphnia magna, Daphnia galeata) to characterize the hazard of these chemicals. Additionally, the estrogenic activity of both BTs was analyzed in vitro using a recombinant yeast estrogen screen (YES).

Results

Both BTs revealed significant effects in acute and chronic experiments, but exhibited no estrogenic activity in the YES. The algal growth test displayed an inhibited cell number increase with effect concentration (EC) values of EC₁₀ 1.18 and 2.86?mg?l^-1 for 1H-BT and 5MBT, respectively. In the Lemna test, EC₁₀ values were 3.94?mg?l^-1 (1H-BT) and 2.11?mg?l^-1 (5MBT). D. magna was also affected with EC₅₀ (48?h) values of 107?mg?l^-1 for 1H-BT and 51.6?mg?l^-1 for 5MBT. D. galeata was more sensitive with an EC₅₀ (48?h) of 14.7?mg 1H-BT l^-1 and 8.13?mg 5MBT l^-1. In the 21-day reproduction tests with D. magna, the EC₁₀ for 5MBT was 5.93?mg?l^-1 while 1H-BT showed no adverse effects. D. galeata turned out to be more sensitive in the chronic study with EC₁₀ values of 0.97?mg?l^-1 for 1H-BT and 0.40?mg?l^-1 for 5 MBT.

Conclusion

Because BTs are regularly found in the aquatic environment at lower ??g l^-1 concentrations reflecting their persistence and poor elimination during wastewater treatment processes, a preliminary risk assessment was conducted. There is little indication that BTs pose a risk for aquatic ecosystems at current exposure levels during most of the year. However, it cannot be excluded that in winter with a higher usage of ADAFs environmental concentrations may well exceed the level that is considered safe for aquatic organisms.     

Armed conflict distribution in global drylands through the lens of a typology of socio-ecological vulnerability

Motivated by an inconclusive debate over implications of resource scarcity for violent conflict, and common reliance on national data and linear models, we investigate the relationship between socio-ecological vulnerability and armed conflict in global drylands on a subnational level. Our study emanates from a global typology of smallholder farmers’ vulnerability to environmental and socioeconomic stresses in drylands. This typology is composed of eight typical value combinations of variables indicating environmental scarcities, resource overuse, and poverty-related factors in a widely subnational spatial resolution. We investigate the relationships between the spatial distribution of these combinations, or vulnerability profiles, and geocoded armed conflicts, and find that conflicts are heterogeneously distributed according to these profiles. Four profiles distributed across low- and middle-income countries comprise all drylands conflicts. Comparing models for conflict incidence using logit regression and receiver operator characteristic analysis based on (1) the set of all seven indicators as independent variables and (2) a single, only vulnerability profile-based variable proves that the nonlinear typology-based variable is the better explanans for conflict incidence. Inspection of the profiles’ value combinations makes this understandable: A systematic explanation of conflict incidence and absence across all degrees of natural resource endowments is only reached through varying importance of poverty and resource overuse depending on the level of endowment. These are nonlinear interactions between the explaining variables. Conflict does not generally increase with resource scarcity or overuse. Comparison with conflict case studies showed both good agreement with our results and promise in expanding the set of indicators. Based on our findings and supporting literature, we argue that part of the debate over implications of resource scarcity for violent conflict in drylands may be resolved by acknowledging and accounting for nonlinear processes.     

Where can cone penetrometer technology be applied? Development of a map of Europe regarding the soil penetrability

Over the past decades, significant efforts have been invested in the development of push-in technology for site characterization and monitoring for geotechnical and environmental purposes and have especially been undertaken in the Netherlands and Germany. These technologies provide the opportunity for faster, cheaper, and collection of more reliable subsurface data. However, to maximize the technology both from a development and implementation point of view, it is necessary to have an overview of the areas suitable for the application of this type of technology. Such an overview is missing and cannot simply be read from existing maps and material. This paper describes the development of a map showing the feasibility or applicability of Direct Push/Cone Penetrometer Technology (DPT/CPT) in Europe which depends on the subsurface and its extremely varying properties throughout Europe. Subsurface penetrability is dependent on a range of factors that have not been mapped directly or can easily be inferred from existing databases, especially the maximum depth reachable would be of interest. Among others, it mainly depends on the geology, the soil mechanical properties, the type of equipment used as well as soil-forming processes. This study starts by looking at different geological databases available at the European scale. Next, a scheme has been developed linking geological properties mapped to geotechnical properties to determine basic penetrability categories. From this, a map of soil penetrability is developed and presented. Validating the output by performing field tests was beyond the scope of this study, but for the country of the Netherlands, this map has been compared against a database containing actual cone penetrometer depth data to look for possible contradictory results that would negate the approach. The map for the largest part of Europe clearly shows that there is a much wider potential for the application of Direct Push Technology than is currently seen. The study also shows that there is a lack of large-scale databases that contain depth-resolved data as well as soil mechanical and physical properties that can be used for engineering purposes in relation to the subsurface.     

Assessment of the natural attenuation of chlorinated ethenes in an anaerobic contaminated aquifer in the Bitterfeld/Wolfen area using stable isotope techniques, microcosm studies and molecular biomarkers

The in situ degradation of chlorinated ethenes was assessed in an anaerobic aquifer using stable isotope fractionation approaches, microcosm studies and taxon specific detection of specific dehalogenating groups of bacteria. The aquifer in the Bitterfeld/Wolfen region in Germany contained all chlorinated ethenes, benzene and toluene as contaminants. The concentrations and isotope composition of the chlorinated ethenes indicated biodegradation of the contaminants. Microcosm studies confirmed the presence of in situ microbial communities capable of the complete dechlorination of tetrachloroethene. Taxon specific investigation of the microbial communities indicated the presence of various potential dechlorinating organisms including Dehalococcoides, Desulfuromonas, Desulfitobacterium and Dehalobacter. The integrated approach, using metabolite spectra, molecular marker analysis and isotope studies, provided several lines of evidence for natural attenuation of the chlorinated ethenes.     

Variability of pesticide exposure in a stream mesocosm system: macrophyte-dominated vs. non-vegetated sections

For flowing water bodies no information is available about patterns of contaminant distribution in flowing water compared to macrophyte-dominated structures. The aim of the study was to examine temporal dynamic and spatial cross-channel variability of pulse exposure of the insecticide thiacloprid in outdoor stream mesocosms. Two distinct cross-channel sections have been considered: macrophyte-dominated littoral and non-vegetated midstream. Median disappearance time ranged from 17 to 43 h (water phase, midstream). We showed that during the exposure pulse (10h) thiacloprid concentrations in the macrophyte-dominated section were 20-60% lower than those in the non-vegetated section. This suggests that spatial variability in contaminant concentrations, particularly in streams containing macrophytes, should be taken into account to enable a more realistic assessment of (i) exposure and associated effects and (ii) mass transport of pesticides and other chemicals into river systems (e.g. losses with surface runoff).     

Formation of oxidation by-products of the iodinated X-ray contrast medium iomeprol during ozonation

The present work describes the investigation of the formation of oxidation by-products of the iodinated X-ray contrast medium (ICM) iomeprol during ozonation in water treatment. Bench-scale investigations revealed that ICM can be partly oxidized during ozonation processes, whereas the ionic diatrizoic acid showed the lowest reactivity. Iomeprol, as a representative of ICM, was not fully mineralized during ozonation. Thus, unknown oxidation by-products were formed. Aqueous solutions of iomeprol were treated by ozonation in order to assess the formation of oxidation by-products. The by-products were characterized by different liquid chromatography methods including detection of single-stage mass spectra, product ion mass spectra, and induced in-source fragmentation for analysis of iodine containing oxidation by-products. Aldehyde and carbonyl containing compounds were proposed to be among the stable by-products. A derivatization step confirms that the aldehyde and carbonyl moieties are major functional groups in oxidation by-products of iomeprol. Furthermore, oxidation by-products of iomeprol were detected at the outlet of an ozone reactor at a full-scale waterworks. However, the toxicological relevance of the by-products is a major future research tasks.