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81.
Schröder W Hornsmann I Pesch R Schmidt G Markert B Fränzle S Wünschmann S Heidenreich H 《Environmental monitoring and assessment》2007,133(1-3):495-505
The study was conducted to test the hypothesis that the regional variability of nitrogen (N) and metal accumulations in terrestrial ecosystems are due to historical and recent ways of landuse. To this end, two regions of Central Europe were selected for investigation: the Weser-Ems Region (WER) and the Euro Region Nissa (ERN). They were assumed to have land use-specific accumulation profiles. Thus, the metal and N accumulations in both regions were examined by means of geostatistically based comparative moss analysis. The sampling and chemical analysis of mosses were conducted in accordance with the convenient guidelines and methods, respectively. The spatial representativity of the sampling sites was computed by means of a land classification which was calculated for Europe by means of classification trees and GIS-techniques. The differences of deposition loads were tested for statistical significance with regard to time and space. The measurement values corroborated the decline of metal accumulation observed since the beginning of the European Metals in Mosses Surveys in 1990. The metal loads of the mosses in the ERN exceeded those in the WER significantly. The opposite holds true for the N concentrations: those in the WER were significantly higher than those in the ERN. The reduction of emissions from power plants, factories and houses was strongly correlated with the decline of deposition and bioaccumulation of metals. As proved by the European Metals in Mosses Surveys, this tendency is due to successful environmental policies. But no such success could be verified by monitoring the accumulation of N in mosses. 相似文献
82.
Organic pollutants in compost and digestate. Part 1. Polychlorinated biphenyls, polycyclic aromatic hydrocarbons and molecular markers 总被引:1,自引:0,他引:1
Brändli RC Bucheli TD Kupper T Furrer R Stahel WA Stadelmann FX Tarradellas J 《Journal of environmental monitoring : JEM》2007,9(5):456-464
In Europe, 9.3 x 10(6) t(dry weight (dw)) of compost and digestate are produced per year. Most of this is applied to agricultural land, which can lead to considerable inputs of organic pollutants, such as polychlorinated biphenyls (PCB) and polycyclic aromatic hydrocarbons (PAH) to soil. This paper presents an inventory of the pollutant situation in source-separated composts, digestates and presswater in Switzerland by a detailed analysis of over 70 samples. PCB concentrations ( summation PCB 28, 52, 101, 118, 138, 153, 180) were significantly higher in urban (median: 30 microg kg(-1)dw, n = 52) than in rural samples (median: 14 microg kg(-1)dw, n = 16). Together with low concentrations in general, this points to aerial deposition on compost input material as the major contamination pathway. Enantiomeric fractions of atropisometric PCB were close to racemic. Median PAH concentration was 3010 microg kg(-1)dw( summation 15PAH, n = 69), and one quarter of the samples exhibited concentrations above the relevant Swiss guide value for compost (4000 microg kg(-1)dw). The levels were influenced by the treatment process (digestate > compost), the season of input material collection (spring-summer > winter > autumn), the particle size (coarse-grained > fine-grained), and maturity (mature > less mature). The main source of PAH in compost was pyrogenic, probably influenced mainly by liquid fossil fuel combustion and some asphalt abrasion, as suggested by multiple linear regression. This study, together with a companion paper reporting on other organic contaminates including emerging compound classes, provides a starting point for a better risk-benefit estimation of the application of compost and digestate to agricultural soil in Switzerland. 相似文献
83.
Chemical composition of the slippery epicuticular wax blooms on Macaranga (Euphorbiaceae) ant-plants
Claus Markstädter Walter Federle Reinhard Jetter Markus Riederer Bert Hölldobler 《Chemoecology》2000,10(1):33-40
Summary. The stems of many Macaranga ant-plants (Euphorbiaceae) are covered by epicuticular wax crystals rendering the surface very slippery for most insects.
These wax blooms act as selective barriers protecting the symbiotic ant partners, which are specialized “wax-runners”, against
the competition of other ants. Glaucous stems occur almost exclusively among the ant-plants of the genus Macaranga (). We analyzed the cuticular lipids of 16 Macaranga species by GC-MS and investigated the wax crystal morphology using SEM. Presence of crystalline wax blooms was strongly correlated
with high concentrations (52%–88%) of triterpenoids. In contrast epicuticular waxes of glossy Macaranga surfaces contained only 0% to 36% of these dominant components. Therefore we conclude that triterpenoids are responsible
for the formation of the thread-like Macaranga wax crystals. In all Macaranga ant-plants investigated, the principal components were epitaraxerol and taraxerone accompanied by smaller portions of taraxerol,
β-amyrin and friedelin. Only in the case of the non-myrmecophytic M. tanarius did β-amyrin predominate. Moreover, we found that only in M. tanarius, the dense wax crystal lacework is torn into large mosaic-like pieces in the course of secondary stem diameter growth. Both
chemical and macroscopic differences may contribute to a reduced slipperiness of M. tanarius stems and appear to be functionally important. The distribution of wax crystals and their composition amongst different sections
of the genus suggests that glaucousness is a polyphyletic character within Macaranga.
Received 7 October 1999; accepted 3 December 1999 相似文献
84.
The correlation of data on the elements obtained by instrumental chemical analysis of highly representative plant samples led to the establishment of a first Biological System of Elements (BSE) in 1994. Including other physiological parameters like availability of chemical elements, transport, storage, etc. it is clear, that aside from the bioinorganic aspects of coordination chemistries of given elements, features of essentiality or toxicity depend on their interference with enzymatic processes. Notably, the latter are not to be considered as purely catalytic transformations, but are instead related to the reproduction of organisms in a direct or indirect manner — as autocatalytic: a process whereby a protein containing some metal or burdened in function by its presence is indirectly involved in its own reproduction. Stoichiometric Network Analysis (SNA) explicitly deals with the general dynamics of such autocatalytic systems. Given there is a relationship between the kinds of metal or metalloid species and the key biological/biochemical transformations to be promoted using them — a relationship which is the topic of bioinorgnaic chemistry-, and that biochemistry is in effect about systems which can reproduce and thus behave autocatalytically, one can expect SNA to yield statements on the basic features of biology and biochemistry as well. 相似文献
85.
The variability of magnesium, strontium and calcium concentrations in the two skeleton types (sclerites and axis) of the
red coral (Corallium rubrum) was assessed by using X-ray fluorescence spectroscopy and microprobe analysis as a prerequisite for their use as ecological
indicators. Axis cross sections showed light and dark circular growth bands corresponding to fast and slow growth, respectively.
Using microprobe analyses the Mg and Sr concentrations ranged from 2.8 to 3.0% and from 0.21 to 0.29%, respectively, in the
sclerites and from 2.4 to 3.0% and from 0.1 to 0.28%, respectively, in the axis. Mg/Ca and Sr/Ca ratios varied within sclerites
(average, 12% for both ratios) and within the axis of single colonies (average, 20% for Mg/Ca and 48% for Sr/Ca). Sr/Ca ratios
in the axis were lower in fast-growing branch tips than in older, more basal parts of the colonies, whereas the Mg/Ca ratio
did not differ significantly between colony regions. Mg/Ca and Sr/Ca ratios in the axis decreased significantly with depth,
and we estimated an increase of the Mg/Ca ratio of 0.004–0.006 per degree Celsius. In all depth layers, Sr/Ca ratios showed
a significant direct relationship with skeleton density in axis cross sections, whereas there was no significant relationship
for Mg/Ca. Overall, our data indicate that temperature promotes the incorporation of Mg in C. rubrum as in other calcite skeletons, whereas Sr concentrations are inversely related to growth rate. This preliminary study suggests
that Mg and Sr concentrations in the axis of the red coral have a strong potential as ecological indicator for temperature
and growth rate.
Received: 3 March 2000 / Accepted: 30 August 2000 相似文献
86.
Oviposition of carrot fly (Psila rosae) in response to foliage and leaf surface extracts of host plants 总被引:1,自引:0,他引:1
Summary. Foliage of twelve host and two non-host species and surrogate leaves treated with the respective leaf extracts were presented
to laboratory populations of the carrot fly (Psila rosae) in oviposition choice assays. The stimulatory activity of dichloromethane surface extracts and the diethyl ether fraction
of hot water extracts did not reflect accurately the differences in acceptability observed among intact leaves. A better correlation
was found using hexane extracts prepared in a microwave oven. Two out of five fractions of this crude hexane extract obtained
by silica gel column chromatography stimulated oviposition. The diethyl ether fraction, which contained the previously identified
oviposition stimulants (propenylbenzenes, furanocoumarins, polyacetylenes), could account for only a minor part of the variation
in the acceptability of host leaves. The preference hierarchy for intact leaves corresponded better to the ranking of species
according to activity of the methanolic fraction, which apparently contains unknown stimulatory compounds.? The water fractions
of the hot water extracts were shown to reduce egg-laying underneath surrogate leaves treated with a stimulatory extract.
This oviposition-deterring effect was particularly strong with the non-preferred species Pimpinella major, which is also highly resistant in the field. Hence, unidentified inhibitory compounds may also contribute to differential
accept ability of host plants. It is concluded that antixenotic (non-preference) resistance of host plants to carrot fly attack
depends on complex mixtures of semiochemicals.
Received 11 June 1997; accepted 26 November 1997. 相似文献
87.
K. Håkan Olsén J. Torbjörn Järvi Ian Mayer Erik Petersson Frederieke Kroon 《Chemoecology》1998,8(1):9-17
Summary. In the present experiment the behaviour and endocrine status of males of the brown trout, Salmo trutta L., (Salmoniformes: Salmonidae) were studied when males were kept in a stream tank with a nest digging female. Groups of
mature adult males and precocious intact or anosmic male parr were placed with the nesting female so that the group resembled
a natural spawning situation with big anadromous fish acting as dominant males and precocious parr acting as “sneakers”. A
control experiment was also run with only males without a female present. In intact parr there were significant positive correlations
between the per cent of the total observation time spent with a female, milt volume, and plasma concentration of 17α, 20β-dihydroxy-4-pregnen-3-one.
Anosmic parr had significantly lower volumes of strippable milt and gonadal steroid hormone levels compared with intact parr.
However, no differences were found in the control experiment. Significantly fewer anosmic parr attended and courted the nesting
female and those anosmic fish that attended the female had significantly lower plasma levels of gonadal hormones. Intact parr
also displayed a greater number of agonistic acts against other parr without any difference in fighting ability. No differences
in aggression occured in the control experiment. In adult males together with a female, post-experimental gonadal steroid
hormone levels were higher than pre-experimental levels. Positive correlations between aggression and androgen hormone levels
were observed in adult males. No differences in plasma hormone levels were observed between adult males and intact precocious
males. The results show that olfactory occlusion results in low steroid hormone levels and milt volumes in precocious males
placed in a spawning situation. The courting behaviour was also affected by anosmia. Odours from the nesting female may have
caused the enhanced plasma hormone levels and stimulated the males to attend the female.
Received 15 May 1997; accepted 29 June 1997. 相似文献
88.
Wiessner A Kuschk P Jechorek M Seidel H Kästner M 《Environmental pollution (Barking, Essex : 1987)》2008,155(1):125-131
Sulphur cycling and its correlation to removal processes under dynamic redox conditions in the rhizosphere of helophytes in treatment wetlands are poorly understood. Therefore, long-term experiments were performed in laboratory-scale constructed wetlands treating artificial domestic wastewater in order to investigate the dynamics of sulphur compounds, the responses of plants and nitrifying microorganisms under carbon surplus conditions, and the generation of methane. For carbon surplus conditions (carbon:sulphate of 2.8:1) sulphate reduction happened but was repressed, in contrast to unplanted filters mentioned in literature. Doubling the carbon load caused stable and efficient sulphate reduction, rising of pH, increasing enrichment of S(2-) and S(0) in pore water, and finally plant death and inhibition of nitrification by sulphide toxicity. The data show a clear correlation of the occurrence of reduced S-species with decreasing C and N removal performance and plant viability in the experimental constructed wetlands. 相似文献
89.
Nyyssönen M Piskonen R Itävaara M 《Environmental pollution (Barking, Essex : 1987)》2008,154(2):192-202
The development of biological treatment technologies for contaminated environments requires tools for obtaining direct information about the biodegradation of specific contaminants. The potential of functional gene array analysis to monitor changes in the amount of functional marker genes as indicators of contaminant biodegradation was investigated. A prototype functional gene array was developed for targeting key functions in the biodegradation of naphthalene, toluene and xylenes. Internal standard probe based normalization was introduced to facilitate comparison across multiple samples. Coupled with one-colour hybridization, the signal normalization improved the consistency among replicate hybridizations resulting in better discrimination for the differences in the amount of target DNA. During the naphthalene biodegradation in a PAH-contaminated soil slurry microcosm, the normalized hybridization signals in naphthalene catabolic gene probes were in good agreement with the amount of naphthalene-degradation genes and the production of 14CO2. Gene arrays provide efficient means for monitoring of contaminant biodegradation in the environment. 相似文献
90.
Niinemets Ülo Kahru Anne Nõges Peeter Tuvikene Arvo Vasemägi Anti Mander Ülo Nõges Tiina 《Regional Environmental Change》2017,17(7):2079-2096
Regional Environmental Change - Globally increasing temperature and modifications in precipitation patterns induce major environmental alterations in aquatic ecosystems. Particularly profound... 相似文献