Global environmental consequences of increased biodiesel consumption in Switzerland: consequential life cycle assessment

This study assesses the direct and indirect environmental impacts to be expected if Switzerland should replace one percent of its current diesel consumption with imports of A) soybean methyl ester (SME) from Brazil, or B) palm methyl ester (PME) from Malaysia. In order to take into account possible future consequences, what-if scenarios were developed and assessed by means of a consequential LCA. In contrast to attributional LCA, the consequential approach uses system enlargement to include the marginal products affected by a change of the physical flows in the central life cycle. This means that the LCA considers all inputs and outputs which are linked to biodiesel production and that the product system is subsequently expanded to include the marginal products affected. Both future systems are assessed in comparison with the environmental scores of the fossil equivalent to biodiesel, i.e. diesel low in sulphur. The environmental burdens are measured by means of greenhouse gas emissions (GHG), land occupation and various non-aggregated and aggregated environmental impact indicators.In sum, the environmental impacts of an increased SME consumption depend on the environmental scores of the marginal replacement products on the world market, rather than on local production factors. In other words, the marginal products assumed to be affected are most important for the results obtained, i.e. in particular the marginal vegetable oil, fodder cake and land areas. In this study it is SME production increased at the expense of the available soybean oil which shifts the impacts associated with soybean oil production to the production of the marginal vegetable oils on the world market. In this perspective, it is not relevant in which country biodiesel production takes place, but rather which vegetable oil is involved. With respect to PME, the most relevant determining factor for the environmental impacts is the land area affected by the increased cultivation of oil palms. Currently, this expansion displaces primarily peat land and rain forest. This causes GHG emissions which are much higher than the emissions of the fossil reference. All in all, both PME from Malaysia and SME from Brazil cause more environmental impact than allowed by the Swiss tax redemption on agro-biofuels (max. 60% GHG emissions and 125% UBP of the fossil reference).     

Climate change mitigation in Austria and Switzerland: The pitfalls of federalism in greening decentralized building policies

The present paper analyses and compares how federalism in Austria and Switzerland affected climate change mitigation in the fully decentralized building sectors of the two countries during the Kyoto Period (1990–2012). This is of interest because the environmental significance of federal political systems is still contested. We first review the literature on federalism in the context of environmental and climate policymaking, and we show that the effects of federal political systems can be positive or negative (depending on interactions between politics and problem characteristics). We then summarize the two qualitative country studies. By analysing who initiated and coordinated respective policies at what time and why, we show that respective policy changes neither emerged bottom-up nor diffused between provinces/cantons, although the latter are fully responsible for building policies. While most policy changes were triggered by federal and/or European Union interventions, the provinces/cantons usually delayed and/or watered down policy changes to smallest common denominator solutions. Based on these findings we conclude that the building sectors of the two countries became more efficient despite, not because of federalism. Against this background we recommend centralizing building policies, or to engage sub-national actors in national target-setting early on.     

Perfluorochemicals in water reuse

Faced with freshwater shortages, water authorities are increasingly utilizing wastewater reclamation to augment supplies. However, concerns over emerging trace contaminants that persist through wastewater treatment need to be addressed to evaluate potential risks. In the present study, perfluorinated surfactant residues were characterized in recycled water from four California wastewater treatment plants that employ tertiary treatment and one that treats primary sewage in a wetland constructed for both treatment and wildlife habitat. Effluent concentrations were compared with surface and groundwater from a creek where recycled water was evaluated as a potential means to augment flow (Upper Silver and Coyote Creeks, San Jose, CA). In the recycled water, 90-470 ng/l perfluorochemicals were detected, predominantly perfluorooctanoate (PFOA; 10-190 ng/l) and perfluorooctanesulfonate (PFOS; 20-190 ng/l). No significant removal of perfluorochemicals was observed in the wetland (total concentration ranged 100-170ng/l across various treatment stages); in this case, 2-(N-ethylperfluorooctanesulfonamido) acetic acid (N-EtFOSAA), perfluorodecanesulfonate (PFDS), and PFOS were dominant. Though there is currently no wastewater discharge into the creeks, perfluorochemicals were found in the surface water and underlying groundwater at a total of 20-150 ng/l with PFOS and PFOA again making the largest contribution. With respect to ecotoxicological effects, perfluorochemical release via recycled water into sensitive ecosystems requires evaluation.     

Evaluation of septum-capped vials for storage of gas samples during air transport

In order to provide information on the suitability of commonly used gas storage vials for air transport, we tested two vial types on their ability to preserve defined nitrous oxide concentrations and excess pressure when exposed to low pressure, low temperature and puncture by needles. Unlike in Crimp Cap vials, in Exetainers no nitrous oxide loss following low pressure storage was detectable. Tightness of Exetainers following multiple puncture was best using a small needle diameter. Pressure loss following 5, 10, or 25 punctures was lowest in the Exetainers. We conclude that Exetainers are suitable for storing gas samples for an extended period of time during aircraft transport.     

The vertical integration of Lisbon and sustainable development strategies across the EU: How different governance architectures shape the European coherence of policy documents

In Europe, sustainable development (SD) is pursued with not one but two overarching strategies, i.e., the so-called Lisbon and SD strategies. While the Lisbon Strategy is a genuinely European response to global economic and social pressures, SD strategies are national efforts corresponding with international (mainly United Nations) guidance to better coordinate and integrate economic, social and, in particular, environmental policies. The present paper explores the vertical coordination and coherence of the two pan-European strategies. After reviewing the international background of SD strategies and the EU origins of the Lisbon strategy, the paper characterizes and compares the governance architectures of the two strategies. With a solid background on how vertical policy integration functions in the two processes, the paper then shows how this affects the coherence of respective strategy structures and monitoring indicators. Based on an extensive empirical stocktaking study of the objectives and indicators in Lisbon and SD strategies across Europe it is shown that, despite the stronger European coordination through the Open Method of Coordination, the Lisbon process entailed only slightly more coherent national strategies than international guidance did in the context of SD strategies. Thus, the paper concludes that the influence international organizations such as the UN and the OECD have on national policy-making must not be underestimated.     

Occurrence and source characterization of perfluorochemicals in an urban watershed

Perfluorochemicals (PFCs) are used in numerous applications, mainly as surfactants, and occur ubiquitously in the environment as complex mixtures. This study was undertaken to characterize the occurrence and sources of commonly detected PFC compounds in surface waters of the Marina catchment, a watershed that drains an urbanized section of Singapore. Of the 19 target PFCs, 13 were detected with perfluorooctanoic acid (PFOA) (5-31 ng L⁻¹) and perfluorooctane sulfonate (PFOS) (1-156 ng L⁻¹) being the dominant components. Other compounds detected included perfluoroalkyl carboxylates (C7-C12) and perfluoroalkyl sulfonates (C6 and C8). Sulfonamide compounds detected 2-(N-ethylperfluorooctanesulfonamido) acetic acid (N-EtFOSAA), 2-(N-methylperfluorooctanesulfonamido) acetic acid (N-MeFOSAA), perfluorooctanesulfonamido acetic acid (FOSAA) and perfluorooctanesulfonamide (FOSA) were putative transformation products of N-EtFOSE and N-MeFOSE, the N-ethylated and N-methylated ethyl alcohol derivatives, respectively. Surface water concentrations were generally higher during dry weather than during storm water flow: the median concentrations of total PFCs in dry and wet weather were 57 and 138 ng L⁻¹ compared to 42 and 79 ng L⁻¹, respectively, at Stamford and Alexandra canal, suggesting the presence of a continuous source(s) which is subject to dilution during storm events. In rain water, median concentrations were 6.4 ng L⁻¹, suggesting rain contributed from 12-25% to the total PFC load for non-point source sites. The longitudinal concentration profile along one of the canals revealed a point source of sulfonated PFCs (PFOS), believed to originate from aqueous film-forming foam (AFFF). Sources were characterized using principal component analysis (PCA) and by plotting PFHxS/PFOA against PFOS/PFOA. Typical surface waters exhibit PFOS/PFOA and PFHxS/PFOA ratios below 0.9 and 0.5, respectively. PCA plots reveal waters impacted by “non-typical” PFC sources in Alexandra canal.     

Land Degradation on Barren Hills: A Case Study in Northeast Vietnam

The term "barren hills" has been a keyword for land degradation in the uplands of Vietnam for over a decade. Nevertheless, the "barren" land is still not adequately ecologically characterized. In this work, we analyze land use-induced changes in vegetation and soil properties along a sequence of barren hills types formed on one physiotope. The study is undertaken in the Bac Kan province, one of the poorest upland regions where livestock plays an important role. A transition from an old-growth laurel forest to a sparse manmade grassland is characterized by a total of 177 species, rapid species turnover, and discrete dominants, and an overwhelming effect of disturbance history on both soil and vegetation patterning. Land degradation is most apparent in land use-induced maintenance of arrested successions, and the regeneration course is shifted towards drier formations. We hypothesize a conceptual model as an aid to understanding the process of early fallow differentiation in response to the patterned, fine-scale disturbances. The larger-scale implications of the observed trends in regeneration potentials deviation, and, in particular, the effect of water buffaloes in halting fallow successions, are discussed.     

Ableitungskriterien für Geringfügigkeitsschwellen zur Beurteilung von Grundwasserverunreinigungen

Ohne Zusammenfassung     

Occurrence of emerging organic contaminants in a tropical urban catchment in Singapore

The aim of this study was to test in a short term laboratory experiment the accumulation and physiological effects of As in the epiphytic lichen Xanthoria parietina. Arsenic content in treated samples increased progressively with increasing concentration in treatment solutions. Treatment of X. parietina thalli with 0.1, 1, 10 ppm As solutions caused significant decrease of viability, measured as intensity of respiratory activity, and damages to cell membranes, assessed by increase of electric conductivity of rinsing water and lipid peroxidation products. Soluble proteins content decreased and H₂O₂ content increased already at the lowest As concentration tested (0.01 ppm). Photosynthetic efficiency, measured in terms of F_V/F_M ratio, decreased significantly only at the highest As concentration (10 ppm). It was concluded that As exposure causes physiological stress both on the mycobiont and the photobiont and that cell membrane damage, expressed in terms of electric conductivity of rinsing water, is the parameter most affected by As treatment.     

Determination of clindamycin and its metabolite clindamycin sulfoxide in diverse sewage samples

In a research project on risk management of harmful substances in water cycles, clindamycin and 12 further antibiotics were determined in different sewage samples. In contrast to other antibiotics, an increase of the clindamycin concentration in the final effluent in comparison to the influent of the sewage treatment plant (STP) was observed. A back transformation from the main metabolite clindamycin sulfoxide to clindamycin during the denitrification process has been discussed. Therefore, the concentration of this metabolite was measured additionally. Clindamycin sulfoxide was stable in the STP and the assumption of back transformation of the metabolite to clindamycin was confuted. To explain the increasing clindamycin concentration in the STP, the ratio of clindamycin sulfoxide to clindamycin was observed. The ratio increased in dry spells with concentrated samples and with long dwell time in the sewer system. A short hydraulic retention in waste water system and diluted samples in periods of extreme rainfall lead to a lower ratio of clindamycin sulfoxide to clindamycin concentration. A plausible explanation of this behavior could be that clindamycin was adsorbed strongly to a component of the sewage during this long residence time and in the STP, clindamycin was released. In the common sample preparation in the lab, clindamycin was not released. Measurements of clindamycin and clindamycin sulfoxide in the influent and effluent of STP is advised for sewage monitoring.