Performance evaluation of using evacuated tubes solar collector,perforated fins,and pebbles in a solar still – experimental study and CO2 mitigation analysis

Environmental Science and Pollution Research - The combination of various methods of increasing evaporation rate can highly impact the performance of solar desalination. This investigation aims to...     

Do transportation taxes promote pro-environmental behaviour? An empirical investigation

The transportation sector is a crucial driver of energy intensity and environmental degradation. Therefore, we aim to explore the nexus of transportation taxes, energy intensity, and CO₂ emissions for the BICS economies. The econometric approaches, CS-ARDL and PMG-ARDL, have been employed to compute the estimates. The long-run estimates of the green transportation tax variable are negatively significant in both energy intensity and CO₂ emissions models irrespective of the estimation technique. These findings imply that green transportation taxes help reduce energy intensity and CO₂ emissions in BICS economies. Conversely, in the short-run, the effects of transportation taxes on energy intensity and CO₂ emissions are mixed and inconclusive. Hence, transportation taxes are necessary to keep the polluters under control not only from the transport sector but also serve as a deterrent for other sectors as well.

     

Genetic diversity,clonality and connectivity in the scleractinian coral Pocillopora damicornis: a multi-scale analysis in an insular,fragmented reef system

Clonality and genetic structure of the coral Pocillopora damicornis sensu lato were assessed using five microsatellites in 12 populations from four islands of the Society Archipelago (French Polynesia) sampled in June 2008. The 427 analysed specimens fell into 132 multilocus genotypes (MLGs), suggesting that asexual reproduction plays an important role in the maintenance of these populations. A haploweb analysis of ITS2 sequences of each MLG was consistent with all of them being conspecific. Genetic differentiation was detected both between and within islands, but when a single sample per MLG was included in the analyses, the populations turned out to be nearly panmictic. These observations provide further evidence of the marked variability in reproductive strategies and genetic structure of P. damicornis throughout its geographic range; comparison with results previously obtained for the congeneric species Pocillopora meandrina underlines the importance of life history traits in shaping the genetic structure of coral populations.     

Green chemistry approach to analysis of formic acid and acetic acid in aquatic environment by headspace water-based liquid-phase microextraction and high-performance liquid chromatography

A simple and totally organic-free (green) method, viz. headspace water-based liquid-phase microextraction combined with high-performance liquid chromatography-ultraviolet detection has been successfully developed for analysis of formic acid and acetic acid in environmental water samples. A microdrop of an aqueous solution of sodium hydroxide was suspended from the tip of a microsyringe needle over the headspace of the stirred sample solution containing the analytes at pH 1.0 for a given time. The microdrop was then retracted into the microsyringe, diluted with HPLC mobile phase, and injected to HPLC. Optimum efficiency has been achieved for: 3.0 µL NaOH microdrop (0.1 mol L^?1) exposed for 15 min over the headspace of an aqueous sample of 6.5 mL at 55 °C, containing 15% w/v of Na₂SO₄, adjusted to pH = 1.0 and stirred at 750 rpm. Under these conditions, enrichment factors of 162 and 187, limits of detection of 0.3 and 0.1 µg L^?1 (S/N = 3) with dynamic linear ranges of 1–500 and 0.5–500 µg L^?1 were obtained for formic acid and acetic acid, respectively. A reasonable repeatability (5.8% ≤ RSD ≤ 8.8%, n = 6) and satisfactory linearity (r² ≥ 0.997) illustrated the performance of the method.     

An integrated multi criteria approach for landfill siting in a conflicting environmental, economical and socio-cultural area

Landfill site selection is a complicated multi criteria land use planning that should convince all related stakeholders with different insights. This paper addresses an integrating approach for landfill siting based on conflicting opinions among environmental, economical and socio-cultural expertise. In order to gain optimized siting decision, the issue was investigated in different viewpoints. At first step based on opinion sampling and questionnaire results of 35 experts familiar with local situations, the national environmental legislations and international practices, 13 constraints and 15 factors were built in hierarchical structure. Factors divided into three environmental, economical and socio-cultural groups. In the next step, the GIS-database was developed based on the designated criteria. In the third stage, the criteria standardization and criteria weighting were accomplished. The relative importance weights of criteria and subcriteria were estimated, respectively, using analytical hierarchy process and rank ordering methods based on different experts opinions. Thereafter, by using simple additive weighting method, the suitability maps for landfill siting in Marvdasht, Iran, was evaluated in environmental, economical and socio-cultural visions. The importance of each group of criteria in its own vision was assigned to be higher than two other groups. In the fourth stage, the final suitability map was obtained after crossing three resulted maps in different visions and reported in five suitability classes for landfill construction. This map indicated that almost 1224 ha of the study area can be considered as best suitable class for landfill siting considering all visions. In the last stage, a comprehensive field visit was performed to verify the selected site obtained from the proposed model. This field inspection has confirmed the proposed integrating approach for the landfill siting.     

Simultaneous derivatization and extraction of nitrophenols in soil and rain samples using modified hollow-fiber liquid-phase microextraction followed by gas chromatography–mass spectrometry

A simple and sensitive method based on a modified hollow-fiber liquid-phase microextraction followed by gas chromatography–mass spectrometry has been successfully developed for the extraction and simultaneous derivatization of some nitrophenols (NPs) in soil and rain samples. Microwave-assisted solvent extraction was used for the extraction of NPs from the soil, while the rain sample was directly applied to the previously mentioned method. Briefly, in this method, the analytes were extracted from aqueous samples into a thin layer of organic solvent (dodecane?+?10 % tri-n-octylphosphine oxide) sustained in the pores of a porous hollow fiber. Then, they were back-extracted using a small volume of organic acceptor solution (25 μl; 10 mg/L N-methyl-N-(trimethylsilyl)trifluoroacetamide, as derivatization reagent, in acetonitrile) that was located inside the lumen of the hollow fiber. Under the optimized extraction conditions, enrichment factors of 255 to 280 and limits of detection of 0.1 to 0.2 μg/L (S/N?=?3) with dynamic linear ranges of 1–100 μg/L were obtained for the analytes. The accuracy of the approach was tested by the relative recovery experiments on spiked samples, with results ranging from 93 to 113 %. The method was shown to be rapid, cost-effective, and potentially interesting for screening purposes.     

Effect of fertilizer application on soil heavy metal concentration

A large amount of chemicals is annually applied at the agricultural soils as fertilizers and pesticides. Such applications may result in the increase of heavy metals particularly Cd, Pb, and As. The objective of this study was to investigate the variability of chemical applications on Cd, Pb, and As concentrations of wheat-cultivated soils. Consequently, a study area was designed and was divided into four subareas (A, B, C, and D). The soil sampling was carried out in 40 points of cultivated durum wheat during the 2006–2007 periods. The samples were taken to the laboratory to measure their heavy metal concentration, soil texture, pH, electrical conductivity, cationic exchange capacity, organic matter, and carbonate contents. The result indicated that Cd, Pb, and As concentrations were increased in the cultivated soils due to fertilizer application. Although the statistical analysis indicates that these heavy metals increased significantly (P value < 0.05), the lead and arsenic concentrations were increased dramatically compared to Cd concentration. This can be related to overapplication of fertilizers as well as the pesticides that are used to replant plant pests, herbs, and rats.     

Mass transfer and bioremediation of aromatics from NAPL in a baffled roller bioreactor

A non-aqueous phase liquid (NAPL) containing dissolved naphthalene or phenol was used to simulate water insoluble contaminants which are produced during the processing of oil sands. Mass transfer and biodegradation of organic contaminants in the aqueous phase were studied in a baffled roller bioreactor. Mass transfer of both naphthalene and phenol from NAPL into the aqueous phase was completed in less than 60 min, by which time naphthalene reached its saturation concentration in the aqueous phase and phenol was completely transferred into the aqueous phase. Pseudomonas putida (ATCC 17484) was subsequently used in biodegradation experiments in the baffled bioreactor containing the model NAPL contaminant. The optimum loading of NAPL for biodegradation of naphthalene at 500 mg/L was found to be 40%. High biodegradation rates (136.4 mg/L h for naphthalene and 13.2 mg/L h for phenol based on the working volume of the bioreactor) were achieved. In the case of simultaneous biodegradation of naphthalene and phenol, the highest total biodegradation rate of 102.6 mg/L h was achieved.     

Investigating the Interdependence Between Non-Hydroelectric Renewable Energy,Agricultural Value Added,and Arable Land Use in Argentina

We examine the dynamic relationships between per capita carbon dioxide emissions, real gross domestic product (GDP), non-hydroelectric renewable energy (NHRE) consumption, agricultural value added (AVA), and agricultural land (AGRL) use for the case of Argentina over the period 1980–2013 by employing the autoregressive distributed lag bound approach to cointegration and Granger causality tests. The Fisher statistics of the Wald test are examined, and the existence of a long-run cointegration between variables is proved. There are long-run bidirectional causalities between all considered variables. The short-run Granger causality suggests bidirectional causality between AVA and agricultural land use, unidirectional causalities running from AGRL to NHRE and from NHRE to AVA. Long-run elasticity estimates suggest that increasing AGRL reduces carbon emissions; increasing AVA increases GDP and reduces pollution, AGRL, and NHRE; and increasing NHRE reduces AVA and AGRL. Thus, it seems that agriculture and renewable energy are substitute activities and compete for land use. We recommend that Argentina should continue to encourage agricultural production. The substitutability between agricultural and non-hydroelectric renewable energy productions, and their competition for agricultural land use, should be at least reduced or even stopped by encouraging research and development in second-generation (or even in third-generation) biofuel production and in new technologies for renewable energy and for agriculture more efficient in land use.

     

Effect of oil pollution on function of sandy soils in protected deserts and investigation of their improvement guidelines (case study: Kalmand area,Iran)

Soil pollution is one of the most dangerous sorts of environmental pollutions because of waste materials, fossil fuels, etc. Unfortunately in developing countries, there are very few arrangements to prevent soil pollution due to the fossil fuels and to improve polluted soil. In this research, influences of gas oil on properties of Kalmand protected area’s sandy soil near Yazd, Iran, were studied. It was found that gas oil constituted 5.25% of soil weight in the refueling station in the region. Therefore, cleaning and strengthening of the soil by adding cement rather than expensive and complicated methods were the most important goals of this research. First, the influence of gas oil on soil properties was studied, and to improve the soil, different percentages of ordinary portland cement were added to the polluted sand to study the improved soil properties using laboratory tests. It was found that unconfined compressive strength, cohesion, and angle of internal friction of sample with 16% cement and 8% gas oil after 28 days of curing were higher than those of the specimen of 6% cement and 14% gas oil, at 4.6, 5.4, and 1.3 times, respectively. Moreover, based on falling head tests it was observed that permeability of the stabilized specimens decreased substantially. From SEM tests, fewer voids were observed in the stabilized samples, which led to less pollutant penetration into the soil. According to EDX, although dangerous elements in the contaminated specimen made up 3.99% of the specimen total weight, addition of cement introduced considerable amounts of elements that are vital for pozzolanic reactions. Therefore, it can be concluded that addition of cement to the gas oil-polluted soil not only can improve geotechnical properties of the soil and reduce its permeability, but also is very efficient for environmental issues.