Assessment of bioaccumulation of biphenyls in the trophic chain of a coastal area of Parana, Brazil

The presence of biphenyl was investigated in sediments and water in Paranagua Bay. Chemicals compounds like biphenyl can cause several effects on the ecosystems such as bioaccumulation. Biphenyl and similar compounds are subject to bioaccumulation, which in turn may harm the local ecosystem. The bioaccumulation in the local trophic chain was evaluated using a mathematical model based on toxicokinetic properties of the compound in the organisms. The results showed that even in water, the concentration of biphenyl was high, 0.82 ng/L. Also, in the fishes, the concentrations calculated by the model were higher than the maximum than the maximum allowed for human consumption.     

Inertization of hazardous dredging spoils

Vitrification and production of ceramics materials starting from sediment excavated from Venice lagoon is described. This sediment is classified as toxic waste because contains several heavy metal ions and organic pollutants and was successfully vitrified at 1200-1350 degrees C. Twenty weight percentage of glass cullet, coming from a community glass recycling program, was added to the raw materials, previously calcined at 900 degrees C, as a way of adjusting the variations of composition of the individual sediment batches. Chemical durability (leaching) tests showed that the optimized glass compositions are inert, and thus not only volume reduction but also inertization of the waste was obtained by this process. Moreover, the economics of the entire process was analysed. The valorization of the waste was accomplished by the subsequent processing of the glass derived from the inertization. Glass ceramic materials were produced by viscous phase sintering of pressed glass powders which crystallized during the densification process. Sintered glass ceramic products had good mechanical characteristics (HV = 7.5 GPa, bending strength 150 +/- 8 MPa), making them suitable for applications in the building industry.     

Assessment of a gelatine surface for fog droplet sampling

Some gelatine films were tested in order to evaluate their ability in collecting fog water droplets, and to calculate the magnification ratio (ratio between the size of the crater on the gelatine and the size of the original droplet). The films were prepared by industrial procedure, by a photographic material manufacturer, in order to assure uniformity of the gelatine layer and reproductibility of the chemical composition. An explanation is given for the behaviour and the characteristics of the different surfaces.     

Contribution of sugar-cane harvesting season to atmospheric contamination by polycyclic aromatic hydrocarbons (PAHs) in Araraquara city,Southeast Brazil

In Brazil, sugar-cane crops are burned to facilitate harvesting, and this causes environmental pollution from the large amounts of smoke and soot that are released into the atmosphere. The smoke and soot contain numerous organic compounds such as PAHs. In this study, PM₁₀ and PAH concentrations in the air of Araraquara (SE Brazil, with around 200,000 inhabitants and surrounded by sugar-cane plantations) were determined during the harvest and non-harvest seasons. The sampling strategy included two campaigns in each season, with 20 samples per season. PM₁₀ was collected using a Hi-vol sampler with Teflon? – coated glass fiber filters. PM₁₀ ranged from 41 to 181 μg m^?3 during the harvest season, and from 12 to 47 μg m^?3 during the non-harvest season. The mean total concentration of PAHs was 2.5 ng m^?3 (non-harvest season) and 11.6 ng m^?3 (harvest season). In all sampling periods, the most abundant polycyclic aromatic hydrocarbons were phenanthrene and fluoranthrene, and the least abundant was anthracene. The cluster analysis of the total PAH concentrations for each day of sampling and the corresponding meteorological data suggested that the atmospheric concentration of PAHs was independent of the differences in the weather between the seasons. For both sampling seasons, the statistical treatment (PCA, Varimax rotation and HCA) indicated the presence of vehicle sources (diesel, gasoline, and natural-gas engines); but for the harvest season, the main source was attributed to sugar-cane burning. The data generated by this study indicated the burning of sugar-cane as the main contributor to the high levels of PAHs detected in samples during the sugar-cane harvest season.     

Behavioural interference between ungulate species: roe are not on velvet with fallow deer

Interference is expected to occur at feeding areas between species with a similar diet, but few studies have tested this idea for wild ungulates. We analysed interactions between fallow deer, European roe deer and wild boar, in three sites, in a Mediterranean area. We expected that interference should be greater between deer than between them and wild boar. We documented the negative effects of behavioural interference by fallow on foraging behaviour of roe deer, under field conditions. Deer species built up 90% interference interactions, with fallow always dominant on roe, also through direct aggression. Although roe deer decreased feeding and increased vigilance levels in proximity (<50 m) of either fallow deer or wild boar, they were displaced significantly more often by the former than by the latter. Fallow deer were neither displaced nor alarmed by roe and rarely by wild boar. No deer species displaced wild boar. Interference was significantly greater on solitary roe deer, especially females, in spring and roe left the feeding ground most often in the smallest site (13 ha). Roe deer avoided areas where the local density of fallow deer was the highest. During our 4-year-study, roe deer density decreased whereas fallow deer numbers increased. Behavioural interference may explain how fallow deer outcompete roe deer through spatial exclusion from feeding sites and avoidance of areas with high densities of the former. Fallow deer evolved in semi-arid, relatively poor habitats of Asia Minor: interspecific defence of crucial resources could have developed as a beneficial tactic for its survival.     

Recycling potential of urban solid waste destined for sanitary landfills: the case of Indaiatuba, SP, Brazil.

The urban solid waste of the city of Indaiatuba (pop. 175 000), located in the state of S?o Paulo, was characterized, focusing on the recycling potential. For this purpose, collected waste was subdivided into 27 items, classified by mass and volume. About 90% of this waste was found to be potentially recyclable and only 10% requiring landfilling. The compostable organic matter, in the form of food and garden waste, both with high moisture content (51 and 41%, respectively), represents 54% in mass and 21% in volume. The most common type of plastic in this waste is high density polyethylene, whose estimated disposal is about 5000kgday(-1). A socio-economic analysis of the waste generation indicates that low-income neighbourhoods discard relatively less packaging and more food waste, shoes and construction debris than middle and high income ones, which may be due to low purchasing power and schooling. Our findings indicate that more aluminium and uncoloured polyethylene terephthalate is discarded in the warmest months of the year, probably due to a greater consumption of canned and bottled drinks.     

Downscaling species occupancy from coarse spatial scales

The measurement and prediction of species' populations at different spatial scales is crucial to spatial ecology as well as conservation biology. An efficient yet challenging goal to achieve such population estimates consists of recording empirical species' presence and absence at a specific regional scale and then trying to predict occupancies at finer scales. So far the majority of the methods have been based on particular species' distributional features deemed to be crucial for downscaling occupancy. However, only a minority of them have dealt explicitly with specific spatial features. Here we employ a wide class of spatial point processes, the shot noise Cox processes (SNCP), to model species occupancies at different spatial scales and show that species' spatial aggregation is crucial for predicting population estimates at fine scales starting from coarser ones. These models are formulated in continuous space and locate points regardless of the arbitrary resolution that one employs to study the spatial pattern. We compare the performances of nine models, calibrated at regional scales and demonstrate that a very simple class of SNCP, the Thomas process, is able to outperform other published models in predicting occupancies down to areas four orders of magnitude smaller than the ones employed for the parameterization. We conclude by explaining the ability of the approach to infer spatially explicit information from spatially implicit measures, the potential of the framework to combine niche and spatial models, and the possibility of reversing the method to allow upscaling.     

Modelling spatial distribution of the Croatian marine benthic habitats

Within the framework of the 3-year project “Mapping the habitats of the Republic of Croatia” the marine benthic habitats of the entire Croatian maritory were mapped. The supralittoral and the mediolittoral were mapped as a function of the coastal lithology and the presumed levels of human impact (both in scale of 1:100,000). The infralittoral was mapped on the basis of spatial modelling (using neural networks as a modelling tool, data about habitats collected by fieldwork as the independent variable for training and testing the model, and the digital bathymetrical model, the distance from coast, the second spectral channel of Landsat ETM+ satellite image and the sea bottom sea temperature, salinity and current magnitude, as dependent variables). The circalittoral and the bathyal were mapped by overlapping and reinterpretation of the existing spatial databases (bathymetry and lithology) within the framework of the raster-GIS.     

A laboratory study on the MSW mechanical behavior in triaxial apparatus

Shear strength characterization of MSW materials is a mandatory task when performing analyses related to landfill design and landfill geometry improvements. Despite the considerable amount of research focusing on MSW mechanical behavior there remain certain aspects which are not completely understood and deserve attention in particular the case of the undrained behavior of MSW. This paper presents the results of a comprehensive laboratory testing program using a large-scale triaxial apparatus at the Federal University of Bahia, Salvador, Brazil. The effect of factors such as confining pressure, unit weight, fiber content, rate of loading and over-consolidation on the MSW mechanical response were investigated. Tested samples presented typical MSW shear/strain curves (concave upward) in all the tests, despite the pore water pressure reaching levels almost equal to the confining pressure. The obtained results show that increasing confining stress, unit weight, loading rate, fiber content and over-consolidation lead to an increase in the MSW shear strength. The importance of the fibrous components in the waste behavior is highlighted and graphs showing the variation of the MSW shear strength with fiber content in different drainage conditions are shown. The authors believe these results could be of interest to many companies, especially considering the new trend of plastic material recycling (prior landfilling) for energy recovery purposes.