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为寻找新的浸矿细菌,从江西城门山矿区硫化矿矿坑水中使用平板分离法得到了一株能够浸矿的细菌,命名为CMS.经电镜和生理生化试验,鉴定该菌株为革兰氏阴性细菌,短杆状,菌体大小为(0.4±0.1)靘祝±0.5)靘, 最适生长温度为25~30 ℃,最适pH值为2.0,化能自养型,能利用亚铁、单质硫和葡萄糖生长,不能利用硫代硫酸钠、蛋白胨生长.16S rRNA系统发育树的结果表明,CMS菌株与嗜酸氧化亚铁硫杆菌(Acidithiobacillus ferrooxidans,简称A.f)AFY菌株位于系统发育树一个同的分支中,相似度99.72%.克隆其代谢系统关键基因亚铁氧化酶(Iro protein)基因并测定其序列,与其他相关菌株比对,结果显示编码区的核酸序列与报道序列完全一致.另外,其铁闪锌矿(ZnFe)S摇瓶浸出试验显示,在浸出28 d后,含菌株的摇瓶的锌离子质量浓度即达到615.50 mg·L-1,而无菌浸出仅有392.25 mg·L-1. 相似文献
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城市景观河流夏季污染状况及营养水平动态分析--以天津市津河为例 总被引:4,自引:0,他引:4
以CODMn、氨氮、总氮、总磷和叶绿素a等为主要指标。对天津市一条典型的景观河流——津河进行了调查分析。结果表明,津河水质介于地表水环境标准(GB3838—2002)的Ⅳ和Ⅴ类之间,营养状态为重富营养。且在多个采样点出现蓝藻水华。水体中的各项指标的变化趋势为,CODMn与叶绿素a都是在7月达到最高,随后逐渐降低。总溶解性氮夏季变化曲线呈倒“S’形。7月最低。8月最高。河道上游总溶解性磷一直比较稳定,而下游在8月上旬急剧升高。藻类演替过程大致为粉末微囊藻-皮状席藻-多种蓝藻。与改造之初相比。水质状况有所改善。 相似文献
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对2015—2016年盐城市城区4个空气质量自动监测国控站点的O_3监测数据进行分析,探讨盐城市O_3污染水平、时空分布特征及其与前体物、气象因子之间的关系。结果表明,各站点O_3污染水平较为接近,2016年各站点O_3-8h第90百分位数超标天数较2015年分别下降了43.5%,50.0%,8.7%和43.6%;全年O_3逐月值大致呈双峰分布,高ρ(O_3)主要集中在4—10月;O_3日变化曲线呈明显的单峰分布,一般在05:00—07:00最低,13:00—15:00达到峰值;不同季节的O_3日变化情况有所差异,午后O_3峰值与O_3日变化幅度均在春季最大,冬季最低;NO、NO_2和CO的日变化曲线均呈现出早晚双峰分布,受早高峰影响,一般在07:00左右达到一日中的最大值;O_3与NO_x等前体物均显著负相关,高ρ(O_3)往往出现在高ρ(CO)/ρ(NO_2)时;总体上各站点的ρ(O_3)随风速的增大而增大。 相似文献
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采用连续通入废水和臭氧的方式,利用臭氧氧化法深度处理焦化废水生化出水(COD为151~183 mg/L、pH约为8),并通过添加羟基自由基抑制剂叔丁醇探究了臭氧氧化的机理。在不调节废水pH、臭氧投加量12.15mg/L、废水流量2 mL/min的最佳条件下,COD去除率达54.5%,出水COD达到GB 16171—2012《炼焦化学工业污染物排放标准》。稳定运行时,降解1 kg COD需投加臭氧741.1 mg。臭氧氧化过程中,臭氧自身氧化和羟基自由基氧化同时存在,且以羟基自由基氧化为主。反应过程符合准一级动力学模型,反应速率常数为0.01 min~(-1)。 相似文献
539.
Weihua Zhang Xinchen Huang Yanming Jia Frederic Rees Daniel C. W. Tsang Rongliang Qiu Hong Wang 《Environmental geochemistry and health》2017,39(2):379-389
Pyrolyzing sludge into biochar is a potentially promising recycling/disposal solution for municipal wastewater sludge, and the sludge-derived biochar (SDBC) presents an excellent sorbent for metal immobilization. As SDBC is composed of both mineral oxides and carbonized organic compartment, this study therefore compared the sorption behaviour of Pb and Zn on SDBC to those of individual and mixture of activated carbon (AC) and amorphous aluminium oxide (Al2O3). Batch experiments were conducted at 25 and 45 °C, and the metal-loaded sorbents were artificially aged in the atmosphere for 1–60 days followed by additional sorption experiments. The Pb sorption was generally higher than Zn sorption, and the co-presence of Pb reduced Zn sorption on each studied sorbent. Higher sorption capacities were observed at 45 °C than 25 °C for SDBC and AC, while the opposite was shown for Al2O3, indicating the significance of temperature-dependent diffusion processes in SDBC and AC. Nevertheless, metal sorption was more selective on Al2O3 that showed a greater affinity towards Pb over Zn under competition, correlating with the reducible fraction of sequential extraction. Furthermore, significant amounts of Pb and Zn were additionally sorbed on SDBC following 30-day ageing. The X-ray diffraction revealed the formation of metal-phosphate precipitates, while the X-ray photoelectron spectroscopy showed a larger quantity of metal–oxygen bonding after 30-day ageing of metal-loaded SDBC. The results may imply favourable long-term transformation and additional sorption capacity of SDBC. In conclusion, SDBC resembles the sorption characteristics of both organic and mineral sorbents in different aspects, presenting an appropriate material for metal immobilization during soil amendment. 相似文献
540.
Occurrence and removal of endocrine-disrupting chemicals in wastewater treatment plants in the Three Gorges Reservoir area, Chongqing, China 总被引:1,自引:0,他引:1
Ye X Guo X Cui X Zhang X Zhang H Wang MK Qiu L Chen S 《Journal of environmental monitoring : JEM》2012,14(8):2204-2211
Concentrations of six endocrine-disrupting compounds (EDCs), bisphenol A (BPA), estrone (E(1)), 17β-estradiol (E(2)), estriol (E(3)), 17α-ethynylestradiol (EE(2)) and diethylstilbestrol (DES), were assessed in influents, effluents and excess sludge in ten municipal wastewater treatment plants (WWTPs) in the Three Gorges Reservoir (TGR) area, Chongqing, China. Three types of activated sludge treatment processes, oxidation ditch (OD), reversed anaerobic-anoxic-oxic (rA(2)/O) technology and sequential batch reactor (SBR), were used in the surveyed WWTPs. These WWTPs were all combined landfill leachate-sewage treatment plants. All analytes were extracted by solid-phase extraction (SPE) in the dissolved phase and by accelerated solvent-based extraction (ASE) in sludge. Gas chromatography-mass spectrometry (GC-MS) was employed for the analysis of EDCs. Among these EDCs, BPA was the most frequently detected and abundant compound (100.0-10566.7 ng L(-1), 15.5-1210.7 ng L(-1) and 85.0-2470.4 ng g(-1) with respect to the influents, effluents and excess sludge samples). The greatest levels of steroidal estrogens in municipal influents were observed in E(3) which were all >100 ng L(-1), followed by E(1) (42.2-110.7 ng L(-1)) and E(2) (7.4-32.7 ng L(-1)), and in the effluents and sludge were E(1) > E(3) > E(2) which were all <31 ng L(-1) and 105 ng g(-1), respectively. Regarding synthetic estrogens, EE(2) was frequently detected in the influents, occurring below 50 ng L(-1), while DES was not detected at all. A high correlation coefficient was observed between the leachate-sludge ratio and concentrations of influent EDCs, and it was statistically significant (i.e., R > 0.65, P < 0.05), but removal efficiency of the EDCs did not show significant differences with OD, rA(2)/O and SBR processes. Furthermore, modification of treatment technology as well as operational parameters, such as hydraulic retention time (HRT), sludge retention time (SRT) and disinfection process (DP), were recommended to further eliminate the residual EDCs. 相似文献