Characterization and control of odorous gases at a landfill site: a case study in Hangzhou, China

Municipal solid waste (MSW) landfills are one of the major sources of offensive odors potentially creating annoyance in adjacent communities. At the end of May 2007, an odor pollution incident occurred at the Tianziling landfill site, Hangzhou, China, where the residents lodged complaints about the intense odor from the landfill, which drew a significant attention from the government. In this study, ambient air monitoring was conducted at the Tianziling landfill site. The main odor composition of the gas samples collected on June 1st 2007 and the reduction of various odorous gases from the samples collected on June 1st 2009 due to the applied odor control techniques were determined using gas chromatography-mass spectrometry (GC-MS). In addition, variations of primary odorous gaseous (NH₃ and H₂S) concentrations at different locations in the landfill site from July 2007 to June 2009 were also investigated by using classical spectrophotometric methods. Results showed that a total of 68 volatile compounds were identified among which H₂S (56.58-579.84 μg/m³) and NH₃ (520-4460 μg/m³) were the notable odor components contributing to 4.47-10.92% and 83.91-93.94% of total concentrations, respectively. Similar spatial and temporal shifts of H₂S and NH₃ concentrations were observed and were significantly affected by environmental factors including temperature, air pressure and wind direction. Odor pollution was worse when high temperature, high humidity, low air pressure, and southeast, northeast or east wind appeared. Moreover, the environmental sampling points of the dumping area and the leachate treatment plant were found to be the main odor sources at the Tianziling landfill site. The odor control technologies used in this project had a good mitigating effect on the primary odorous compounds. This study provides long-term valuable information concerning the characteristics and control of odors at landfill sites in a long run.     

EGSB出水回流对EGSB—SBR工艺处理果汁废水的影响

采用EGSB—SBR工艺处理实际果汁废水(COD 2 608~6 500 mg/L,p H 5.0~7.0)。在EGSB反应器成功启动及驯化完成的情况下,连续运行49 d。实验结果表明:第25天起,控制EGSB回流比为3.00∶1,EGSB反应器可在无须添加Na HCO3的条件下稳定运行,从而降低了废水处理成本;第25天起,平均进水COD,BOD5,SS分别为5 968,2 130,1 020 mg/L,平均出水COD,BOD5,SS分别降至131,11,50 mg/L,平均COD,BOD5,SS去除率分别为98%,99%,95%;组合工艺对该实际果汁废水具有良好的处理效果。     

我国劳动防护鞋存在的问题及改进建议

我国劳动防护鞋在防护功能和技术要求上存在一些问题,降低了鞋的安全防护效果,在生产和销售等方面也受到相关国际标准的制约和国外产品的冲击。因此,掌握劳动防护鞋在防护功能和技术要求上存在的问题和差距,将有助于改进和提高我国劳动防护鞋的安全性能乃至整体性能,更有效地保护劳动者的健康和安全,增强我国防护鞋生产企业的国际竞争力。     

Spectral Characterization of Four Kinds of Biodegradable Plastics: Poly (Lactic Acid), Poly (Butylenes Adipate-Co-Terephthalate), Poly (Hydroxybutyrate-Co-Hydroxyvalerate) and Poly (Butylenes Succinate) with FTIR and Raman Spectroscopy

Fourier transform infrared microscope and confocal Raman spectroscope were employed in this study to investigate four kinds of biodegradable plastics: poly(lactic acid),poly(butylenes adipate-co-terephthalate), poly(butylenes succinate) and poly(hydroxybutyrate-co-hydroxyvalerate), which are used more and more popularly in everyday life but can not be identified easily with other instruments. Infrared and Raman spectra of the plastics were tentatively interpreted. The indicative peaks to characterize the four polymers were also summarized. The result in this study can help the forensic scientists discriminate the plastics accurately when they occurred as trace evidences in cases, it also offers the producer and environment scientists an effective, non-invasive and fast method to characterize and identify these four polymers.     

事故二叉树计算机算法

根据《数据结构》中的二叉树算法,结合事故树算法的特点,提出事故二叉树算法。该算法是对事故树求解算法的有益补充和发展,具有广阔的应用前景和现实意义     

均压防灭火定量分析技术研究及其应用

均压是防治煤矿自然发火的主要措施之一。针对均压应用中的定性分析方法及两点式均压方法的不足,提出了均压防灭火定量分析技术并开发了与采空区相连两个工作面间均压的计算机摸拟计算程序。阐述了程序均压原理、内容及应用实例。这项技术具有创新性和应用推广价值,可以提高均压防灭火技术应用的经济性和安全性     

发挥环保监督网络作用 搞好“一控双达标”

介绍了新余发电有限责任公司建立环保监督网络和开展环保技术监督，做好“一控双达标”工作的具体做法。     

太湖流域主要城市洪涝灾害生态风险评价

太湖流域有上海，苏州，无锡，常州，镇江，杭州，嘉兴，湖州八个大中城市，是我国产业最集中，工农业最发达的地区之一，但该地区洪涝灾害频繁，这不仅制约了流域中各城市经济的发展，还严重威胁到该地区城市的生存平衡，本文根据生存风险评价原理，结合太湖流域的自然特点，提出成因分析法的指标模型。并通过分析太湖流域八个大中城市的汛期降雨量和地形地貌因子对洪涝灾害生态风险的影响度，得出各个城市洪涝灾害的生态风险度，最后还根据各城市风险度的大小及其主导因素的不同，提出了如何管理洪涝灾害生态风险的建议。     

Copper ultrastructural localization, subcellular distribution, and phytotoxicity in Hydrilla verticillata (L.f.) Royle

Laboratory experiments were conducted to investigate copper (Cu) subcellular distribution and toxicity in Hydrilla verticillata. Fronds were subjected to different concentrations (15, 75, and 150 μM) of Cu for 7 days. Cu grains were found in cell walls, plasmodesmata, and within the nuclei and chloroplasts using the autometallographic technique. Subcellular fractionation of Cu-containing tissues indicated that in leaves subjected to high Cu concentrations, 59–65 % of the element was located in the cell wall fraction, followed by cell organelles (21–30 %) and the soluble fraction (10–14 %). The levels of K, P, Zn, and Mg declined under all Cu concentrations, but Ca, Mn, and Fe contents reached their peak at 15 μM Cu and decreased thereafter. F _v/F _m, F ₀, and F _m fell significantly in line with the decrease in pigment content. Cu exposure also caused significant damage to the chloroplasts, mitochondria, and nuclei, including disintegration of the chloroplasts and vacuolization of the mitochondria and nuclei, all of which suggested that Cu hastened plant senescence. The Cu maximum permissible concentration for H. verticillata was 10 μM, which was less than the existing general water quality standard. This suggested that H. verticillata could be used to assess Cu phytotoxicity.     

典型南方水源溶解性有机物荧光特性变化与去除

于2014年4-9月,研究我国一典型南方水源溶解性有机物(DOM)的荧光特性变化与去除情况,同时分析了DOM荧光组分与三氯乙醛生成势(CHFP)的相关性。结果表明,该水源DOM主要以芳香性蛋白质类物质组成,溶解性微生物代谢产物类物质、富里酸类物质和腐殖酸类物质含量逐渐增加;5个荧光区域的积分体积(ΦⅠ,n、ΦⅡ,n、ΦⅢ,n、ΦⅣ,n和ΦⅤ,n)所占总体积(ΦT,n)平均比例依次为:13.55%、27.53%、25.00%、16.02%和17.91%;原水DOM的CHFP范围为27.06~81.20μg/L,平均值为46.60μg/L,三氯乙醛(CH)前体物含量与水体中溶解性微生物代谢产物类物质相关性最好;与常规处理工艺相比,O3/BAC深度处理工艺对于溶解性微生物代谢产物类物质的去除率大幅提高,更有利于CH的控制。