Removal of Pb(II) ions from aqueous solution and industrial effluent using natural biosorbents

Purpose

The purpose of the research is to investigate the applicability of the low-cost natural biosorbents for the removal of Pb(II) ions from aqueous solution and effluent from battery industry.

Methods

Six different biosorbents namely rice straw, rice bran, rice husk, coconut shell, neem leaves, and hyacinth roots have been used for the removal of Pb(II) ions from aqueous solution in batch process. All the biosorbents were collected from local area near Kolkata, West Bengal, India. The removal efficiency was determined in batch experiments for each biosorbent.

Results

The biosorbents were characterized by SEM, FTIR, surface area, and point of zero charge. The sorption kinetic data was best described by pseudo-second-order model for all the biosorbents except rice husk which followed intraparticle diffusion model. Pb(II) ions adsorption process for rice straw, rice bran, and hyacinth roots were governed predominately by film diffusion, but in the case of rice husk, it was intraparticle diffusion. Film diffusion and intraparticle diffusion were equally responsible for the biosorption process onto coconut shell and neem leaves. The values of mass transfer coefficient indicated that the velocity of the adsorbate transport from the bulk to the solid phase was quite fast for all cases. Maximum monolayer sorption capacities onto the six natural sorbents studied were estimated from the Langmuir sorption model and compared with other natural sorbents used by other researchers. The Elovich model, the calculated values of effective diffusivity, and the sorption energy calculated by using the Dubinin?CRadushkevich isotherm were indicated that the sorption process was chemical in nature. The thermodynamic studies indicated that the adsorption processes were endothermic. FTIR studies were carried out to understand the type of functional groups responsible for Pb(II) ions binding process. Regeneration of biosorbents were carried out by desorption studies using HNO₃. Battery industry effluents were used for the application study to investigate applicability of the biosorbents.

Conclusion

The biosorbents can be utilized as low-cost sorbents for the removal of Pb(II) ions from wastewater.     

Effect of vermicomposting on calcium,sulphur and some heavy metal content of different biodegradable organic wastes under liming and microbial inoculation

A study was conducted to evaluate the changes in total calcium and sulphur and some heavy metal (Zn, Cu, and Pb) concentration of different organic wastes affected by liming and microorganism inoculation. Vermicomposting was an effective technology for disposal of organic substrates like municipal solid wastes (MSW), possessing comparatively higher concentration of heavy metals. The addition of lime in initial organic substrates significantly (P ≤ 0.05) increased total calcium and total sulphur content of vermicomposts. Inoculation of microorganisms significantly (P ≤ 0.05) reduced the heavy metal content of final products as compared to control. Fungal strains were comparatively more effective in detoxification of heavy metals than B. polymyxa.     

Accident Due to Release of Hydrogen Sulphide in a Manufacturing Process of Cobalt Sulphide – Case Study

An accident occurs during the manufacture of cobalt sulphide unit due to liberation of hydrogen sulphide. Problems associated with the hydrogen sulphide and the recommended preventives measured have been discussed.     

An alternative approach to reconstructing organic matter accumulation with contrasting watershed disturbance histories from lake sediments

A number of proxies, including carbon to nitrogen ratio (C:N) and stable isotopes (delta(13)C and delta(15)N), have been used to reconstruct organic matter (OM) profiles from lake sediments and these proxies individually or in combination cannot clearly discriminate different sources. Here we present an alternative approach to elucidate this problem from lake sediments as a function of watershed scale land use changes. Stable isotope signatures of defined OM sources from the study watersheds, Shawnigan Lake (SHL) and Elk Lake (ELL), were compared with sedimentary proxy records. Results from this study reveal that terrestrial inputs and catchment soil coinciding with the watershed disturbances histories probably contributed in recent trophic enrichment in SHL. In contrast, cultural eutrophication in ELL was partially a result of input from catchment soil (agricultural activities) with significant input from lake primary production as well. Results were consistent in both IsoSource (IsoSource version 1.2 is a Visual Basic program used for source separation, (http://www.epa.gov/wed/pages/models/isosource/isosource.htm) and discriminant analysis (statistical classification technique).     

Rooting response in stem cuttings from five species of mangrove trees: effect of auxins and enzyme activities

An experiment was conducted to optimise rooting in stem cuttings of the mangrove tree species Bruguiera parviflora, Cynometra iripa, Excoecaria agallocha, Heritiera fomes and Thespesia populnea. Cuttings were girdled or non-girdled and treated with the auxins indole-3-acetic acid (IAA), indole-3-butyric acid (IBA) and naphthalene-acetic acid (NAA) and amylase, IAA-oxidase, peroxidase and polyphenol oxidase activities were measured. The best rooting performance (in terms of root number) was in stem cuttings of E. agallocha followed by C. iripa and H. fomes when treated with IBA + NAA. IAA and IBA combinations were more effective in T. populnea and B. parvifolia. Variations in rooting response were markedly reflected in amylase, IAA-oxidase, peroxidase and polyphenol oxidase activities. Sharp increases in amylase and polyphenol-oxidase activities were associated with enhanced rooting in E. agallocha, C. iripa and H. fomes. On the contrary, lowered IAA-oxidase and peroxidase activities favoured rooting in T. populnea and B. parviflora. A higher number of roots occurred in pre-girdled cuttings in comparison to non-girdled cuttings. Received: 30 March 1999 / Accepted: 6 October 1999     

<Emphasis Type="Bold">Tracing lead contamination in foods in the city of Kolkata,India</Emphasis>

Lead isotopic ratios (LIR) of eight common food items, street dust, coal, diesel, sediments, lead ore and rainwater from India have been reported for the first time in this paper. This study characterized the source and extent of lead pollution in the different foodstuff consumed in Kolkata, a major metropolis of eastern India. The atmospheric lead input to the food items, sold openly in busy roadside markets of the city, has been quantified. The mean 207/206 and 208/206 LIRs of the eight food items ranged from 0.8847 to 0.8924 and 2.145 to 2.167, respectively. Diesel had the highest mean 207/206 and 208/206 values of 0.9015 and 2.1869, respectively, apart from the lead ore. The food items had a mean lead concentration between 3.78 and 43.35 mg kg^?1. The two ratio scatter plots of all the different environmental matrices were spread linearly between the uncontaminated Ichapur sediment and diesel. The 207/206 LIRs of the coal with a mean of 0.8777 did not fall in the linear trend, while the street dust and food samples overlapped strongly. The rainwater sample had a 207/206 LIR of 0.9007. Contaminated sediments in Dhapa, the repository of the city’s municipal garbage, had a mean 207/206 LIR of 0.8658. The corresponding value obtained from the sewage-fed vegetable grown there was 0.8058. The present study indicated that diesel was one of the main contributor to Pb pollution. The atmospheric lead contribution to the food items was in the range of 68.48–86.66 %.     

Characterization and cadmium-resistant gene expression of biofilm-forming marine bacterium Pseudomonas aeruginosa JP-11

Biofilm-forming marine bacterium Pseudomonas aeruginosa JP-11 was isolated from coastal marine sediment of Paradeep Port, Odisha, East Coast, India, which resisted up to 1,000 ppm of cadmium (Cd) as cadmium chloride in aerobic conditions with a minimal inhibitory concentration of 1,250 ppm. Biomass and extracellular polymeric substances (EPS) secreted by the cells effectively removed 58.760?±?10.62 and 29.544?±?8.02 % of Cd, respectively. The integrated density of the biofilm-EPS observed under fluorescence microscope changed significantly (P?≤?0.05) in the presence of 50, 250, 450, 650 and 850 ppm Cd. ATR-FTIR spectroscopy showed a peak at 2,365.09/cm in the presence of 50, 250, 450 and 650 ppm Cd which depicts the presence of sulphydryl group (–SH) within the EPS, whereas, a peak shift to 2,314.837/cm in the presence of 850 ppm Cd suggested the major role of this functional group in the binding with cadmium. On exposure to Cd at 100, 500 and 1,000 ppm, the expression profiles of cadmium resistance gene (czcABC) in the isolate showed an up-regulation of 3.52-, 17- and 24-fold, respectively. On the other hand, down-regulation was observed with variation in the optimum pH (6) and salinity (20 g l^?1) level. Thus, the cadmium resistance gene expression increases on Cd stress up to the tolerance level, but an optimum pH and salinity are the crucial factors for proper functioning of cadmium resistance gene.     

A semi-automated tool for identifying agricultural roadway crashes in crash narratives

Objective: Crash reports contain precoded structured data fields and a crash narrative that can be a source of rich information not included in the structured data. The narrative can be useful for identifying vulnerable roadway users, such as agricultural workers. However, using the narratives often requires manual reviews that are time consuming and costly. The objective of this research was to develop a simple and relatively inexpensive, semi-automated tool for screening crash narratives and expediting the process of identifying crashes with specific characteristics, such as agricultural crashes.

Methods: Crash records for Louisiana from 2010 to 2015 were obtained from the Louisiana Department of Transportation (LaDOTD). Records with narratives were extracted and stratified by vehicle type. The majority of analyses focused on a vehicle type of farm equipment (Type T). Two keyword lists, an inclusion list and an exclusion list, were created based on the published literature, subject-matter experts, and findings from a pilot project. Next, a semi-automated tool was developed in Microsoft Excel to identify agricultural crashes. Lastly, the tool’s performance was assessed using a gold standard set of agricultural narratives identified through manual review.

Results: The tool reduced the search space (e.g., number of narratives that need manual review) for narratives requiring manual review from 6.7 to 59.4% depending on the research question. Sensitivity was high, with 96.1% of agricultural crash narratives being correctly classified. Of the gold standard agricultural narratives, 58.3% included an equipment keyword and 72.8% included a farm equipment brand.

Conclusion: This article provides information on how crash narratives can supplement structured crash data. It also provides an easy-to-implement method to facilitate incorporating narratives into safety research along with keyword lists for identifying agricultural crashes.     

Essential oils and their bioactive compounds as eco-friendly novel green pesticides for management of storage insect pests: prospects and retrospects

Environmental Science and Pollution Research - The control of storage insect pests is largely based on synthetic pesticides. However, due to fast growing resistance in the targeted insects,...