Identification and quantification of methyl halide sources in a lowland tropical rainforest

In conjunction with the OP3 campaign in Danum Valley, Malaysian Borneo, flux measurements of methyl chloride (CH₃Cl) and methyl bromide (CH₃Br) were performed from both tropical plant branches and leaf litter in June and July 2008. Live plants were mainly from the Dipterocarpaceae family whilst leaf litter samples were representative mixtures of different plant species. Environmental parameters, including photosynthetically-active radiation, total solar radiation and air temperature, were also recorded. The dominant factor determining magnitude of methyl halide fluxes from living plants was plant species, with specimens of the genus Shorea showing persistent high emissions of both gases, e.g. Shorea pilosa: 65 ± 17 ng CH₃Cl h^?1 g^?1 (dry weight foliage) and 2.7 ± 0.6 ng CH₃Br h^?1 g^?1 (dry weight foliage). Mean CH₃Cl and CH₃Br emissions across 18 species of plant were 19 (range, <LOD ?76) and 0.4 (<LOD ?2.9) ng h^?1 g^?1 respectively; fluxes from leaf litter were 1–2 orders of magnitude smaller per dry mass. CH₃Cl and CH₃Br fluxes were weakly correlated. Overall, the findings suggest that tropical rainforests make an important contribution to global terrestrial emissions of CH₃Cl, but less so for CH₃Br.     

Evaluation of the Chemcatcher and DGT passive samplers for monitoring metals with highly fluctuating water concentrations

Passive sampling devices accumulate chemicals continuously from water and can provide time weighted average (TWA) concentrations of pollutants over the exposure period. Hence, they offer a number of advantages over other conventional monitoring techniques such as spot or grab sampling. The diffusive gradient in thin film (DGT) and the Chemcatcher passive samplers can be used to provide TWA concentrations of labile metals, but the approaches to their calibration differ. DGT uses diffusion coefficients of metals in the hydrogel layer, whereas Chemcatcher uses metal specific uptake rates, with both sets of values obtained under controlled laboratory conditions with constant aqueous metal concentrations. However, little is known of how such samplers respond to fluctuating concentrations. We evaluated the responsiveness of these two passive sampling devices to rapidly changing concentrations of Cd, Cu, Ni, Pb and Zn in natural freshwater, over a relatively short deployment time. Maximum metal concentrations in water were varied between 70 and 140 microg L(-1). Experiments were carried out in a tank with a rotating carousel system and filled with Meuse river water, allowing a degree of control over experimental conditions while using natural river water. Fluctuating concentrations were obtained by stepwise addition of standard solutions of the metals. The reliability and accuracy of the TWA concentrations measured by the samplers were assessed by comparison with concentrations of the metals in spot samples of water taken regularly over the deployment period. The spot samples of water were either unfiltered (total), filtered (0.45 microm) or ultrafiltered (5 kDa). Predictive speciation modelling using the visual MINTEQ programme was also undertaken. There was reasonable agreement between the TWA concentrations of Cd and Ni obtained with Chemcatcher and DGT and the total Cd and Ni concentrations measured in repeated unfiltered spot samples. For elements (i.e. Cu, Pb, Zn) that associate to a significant degree with suspended solids, colloids or dissolved organic carbon, or form complexes with large organic ligands, optimum agreement was with the filtered or ultrafiltered fractions and with the predicted inorganic and inorganic-fulvic acid associated fractions. While Chemcatcher-based TWA concentration ranges for Cu and Zn were in best agreement with the total filtered fraction, there was lack of agreement for Pb. The combined use of DGT devices with open pore (OP) and restricted pore (RP) gels allowed the labile fraction of metal associated with large organic ligands or DOC to be differentiated and quantified, since this is available to DGT OP but unable to diffuse into the DGT RP. This evaluation of the two sampling devices clearly demonstrated their ability to react reliably to transient peaks in concentration of metal pollutants in water and indicated where future efforts are needed to improve calibration data. Such samplers may prove valuable in responding to the monitoring requirements of the European Union's Water Framework Directive.     

Implications of climate change for the stomatal flux of ozone: a case study for winter wheat

Climate change factors such as elevated CO2 concentrations, warming and changes in precipitation affect the stomatal flux of ozone (O3) into leaves directly or indirectly by altering the stomatal conductance, atmospheric O3 concentrations, frequency and extent of pollution episodes and length of the growing season. Results of a case study for winter wheat indicate that in a future climate the exceedance of the flux-based critical level of O3 might be reduced across Europe, even when taking into account an increase in tropospheric background O3 concentration. In contrast, the exceedance of the concentration-based critical level of O3 will increase with the projected increase in tropospheric background O3 concentration. The influence of climate change should be considered when predicting the future effects of O3 on vegetation. There is a clear need for multi-factorial, open-air experiments to provide more realistic information for O3 flux-effect modelling in a future climate.     

Identifying ozone-sensitive communities of (semi-)natural vegetation suitable for mapping exceedance of critical levels

Using published data on the responses of individual species to ozone, 54 EUNIS (European Nature Information System) level 4 communities with six or more ozone-sensitive species (%OS) and c. 20% or more species tested for ozone sensitivity, were identified as potentially ozone-sensitive. The largest number of these communities (23) was associated with Grasslands, with Heathland, scrub and tundra, and Mires, bogs and fens having the next highest representation at 11 and 8 level 4 communities each respectively. Within the grasslands classification, E4 (Alpine and sub-alpine grasslands), E5 (Woodland fringes and clearings) and E1 (Dry grasslands) were the most sensitive with 68.1, 51.6 and 48.6%OS respectively. It is feasible to map the land-cover for these and other communities at level 2, but it may not be currently possible to map the land-cover for all communities identified to be ozone-sensitive at levels 3 and 4.     

企业文化与企业安全文化建设水平互动效应研究

为提高企业安全文化建设水平,基于人类协同国际环形和企业安全文化建设水平评价指标设计调查问卷,以赛轮金宇股份有限公司为研究对象,对其企业文化和企业安全文化建设水平进行相关性分析和多元逐步回归分析,探索二者的互动效应,从企业文化角度发掘安全文化建设重点。结果表明,自我实现文化、亲和文化、传统文化、成就文化与企业安全文化建设水平高度正相关,逃避文化则呈现高度负相关,其相关系数（绝对值）均在0.9以上;同时,多元逐步回归分析中,以上5个文化规则均进入回归方程,其标准化回归系数β分别为:0.395、0.182、0.169、0.129、-0.145。因此,这5种文化规则对企业安全文化建设水平具有很高的预测力,是企业安全文化建设的重点所在。     

Relative effects of elevated background ozone concentrations and peak episodes on senescence and above-ground growth in four populations of Anthoxanthum odoratum L

Four populations of Anthoxanthum odoratum from North Wales, UK, were exposed to the following combinations of mean background and peak concentrations of ozone for 12 weeks in solardomes: LL (14.3 ppb, 18.9 ppb, respectively), LH (14.8 ppb, 52.3 ppb), HL (28.9 ppb, 35.7 ppb) and HH (30.5 ppb, 72.1 ppb). Elevated ozone rapidly induced premature senescence, with effect increasing in the order: LL < LH < HL < HH. By week 11, the LH and HL treatments had induced similar amounts of whole plant senescence even though the AOT40₁₂ values (accumulated between 8am and 8pm) were very different at 10.6 ppm h and 4.1 ppm h, respectively. Overall, linear correlations between whole plant senescence were stronger for AOT0 than for AOT40. Intraspecific variation in the senescence response to the different profiles was observed after 11 weeks of exposure. Effects on growth and tillering were less pronounced than effects on senescence.     

日本环境会计体系分析及对我国启示

环境会计发展的理念与实践是以实现经济、社会、环境的可持续发展为前提,通过实施环境会计制度,可以使企业准确掌握经营活动的资源消耗、环境负荷,促进其提供环境友好产品及服务,推进经济朝着低碳、绿色、可持续模式发展。日本经过十几年的发展,目前已形成较为完善的环境会计体系。本文通过介绍和分析日本环境会计体系产生的背景、发展变化与作用,探讨我国环境会计体系构筑问题。     

A habitat‐based approach to predict impacts of marine protected areas on fishers

Although marine protected areas can simultaneously contribute to biodiversity conservation and fisheries management, the global network is biased toward particular ecosystem types because they have been established primarily in an ad hoc fashion. The optimization of trade‐offs between biodiversity benefits and socioeconomic values increases success of protected areas and minimizes enforcement costs in the long run, but it is often neglected in marine spatial planning (MSP). Although the acquisition of spatially explicit socioeconomic data is perceived as a costly or secondary step in MSP, it is critical to account for lost opportunities by people whose activities will be restricted, especially fishers. We developed an easily reproduced habitat‐based approach to estimate the spatial distribution of opportunity cost to fishers in data‐poor regions. We assumed the most accessible areas have higher economic and conservation values than less accessible areas and their designation as no‐take zones represents a loss of fishing opportunities. We estimated potential distribution of fishing resources from bathymetric ranges and benthic habitat distribution and the relative importance of the different resources for each port of total catches, revenues, and stakeholder perception. In our model, we combined different cost layers to produce a comprehensive cost layer so that we could evaluate of trade‐offs. Our approach directly supports conservation planning, can be applied generally, and is expected to facilitate stakeholder input and community acceptance of conservation.     

厌氧混合培养条件下六氯苯生物降解的外加碳源必要性

采用标准血清瓶实验探讨了厌氧污泥对六氯苯(HCB)的降解活性以及各种环境因素的影响.结果表明,经过14d的HCB驯化,厌氧污泥具备了较好的降解HCB能力;反应温度对HCB的降解速率有很大影响,适宜温度为35℃左右;葡萄糖、甲酸、乙酸、丙酸和丁酸等有机碳源的存在明显促进了HCB的厌氧降解,其中甲酸和乙酸的加入极其重要;根据实验结果推测出,产甲烷过程对HCB的生物降解发挥了重要作用.     

Dissecting the spatial scales of mercury accumulation in Ontario lake sediment

Total mercury concentration was analyzed in 171 lakes from pre-industrial (>30 cm depth; Hg_{pre-industrial}) and present-day sediments (0.5–1 cm; Hg_present-day). Numerous hot or cold spots of sediment mercury enrichment (Hg EF; Hg_{pre-industrial}/Hg_present-day) were evident as determined by local tests of autocorrelation, although in most cases, the maximum correlation among sites was not the nearest neighbor, indicating a strong influence of watershed characteristics. Hg EF was correlated with the area of open water (ha) (r = 0.91, p = 0.035), mine tailings (r = 0.94, p = 0.019), and organic deposits in surficial geology of the watershed (r = −0.91, p = 0.034). Through use of local rather than global regression coefficients, R² increased from 0.20 (p = 0.005) to 0.60 (p = 0.013). A broad spatial pattern (>500 km) observed only in Hg_{pre-industrial} was best explained by mean annual precipitation (shared variance = 3.5%), while finer spatial patterns only observed in Hg_present-day and Hg EF were best explained by pH (average shared variance = 10.8%).