Polycyclic aromatic hydrocarbon transport processes on the scale of a flood event in the rural watershed of Le Bebec, France

Transport processes of polycyclic aromatic hydrocarbons (PAHs) were investigated in a rural watershed in France, which led to new quantitative results on the scale of a flood event. For that purpose, principal components analysis (PCA) combined with signal decomposition of PAH Breakthrough curves were used. The results obtained by PCA enabled us to distinguish (i) the transport of low molecular weight PAHs in dissolved form and (ii) the transport of high molecular weight PAHs in particulate form. The intermediate molecular weight PAHs are distributed in these two clusters. The application of a signal decomposition method confirms the results of PCA and makes it possible to quantify the mass PAH resulting, respectively, from resuspension (13.3mg, i.e. 77% of the total mass) and from direct transfer (2.8mg=16% of the total mass). For the resuspension phase, desorption of PAH (38% of the total exported mass) could be also distinguished from sediment resuspension (39%).     

The impact of preventive coping on business travelers' work and private life

Frequent business travel can be a burden for travelers' work and private life. We tested whether preventive coping (the proactive accumulation of resources in advance of potential stressors) makes such trips beneficial despite their potential to be stressful. In a longitudinal three‐wave study, we investigated whether frequent travel relates to an increase or decrease in work–life balance, emotional exhaustion, work engagement, and relationship satisfaction depending on preventive coping. Findings from a sample of 133 frequent business travelers revealed significant indirect effects for emotional exhaustion, work engagement, and relationship satisfaction through work–life balance. Among employees who engaged less in preventive coping, a higher number of business trips was related to a decrease in work–life balance, which, in turn, was related to more emotional exhaustion, less work engagement, and lower relationship satisfaction. Among those who reported higher preventive coping, we found opposing indirect effects: Frequent travel was related to an increase in work–life balance and, in turn, to less emotional exhaustion, more work engagement, and higher relationship satisfaction. These findings advance our knowledge in the field of business travel, future‐oriented coping, and work–life balance. They highlight that travelers and their organizations should resort to preventive coping to make frequent travel more beneficial.     

Job insecurity and crossover of burnout in married couples

We investigated crossover of burnout between spouses in 98 married couples in an organization undergoing downsizing. Burnout was found to be associated with feelings of job insecurity, self‐control and social undermining. Using SEM, findings supported the crossover of burnout from husbands to wives and the impact of burnout on undermining behavior. They also supported the research hypothesis of a direct relationship between job insecurity and burnout among husbands but not among wives. Sense of control was found to have a negative impact on burnout and on the spouse's undermining behavior and a positive impact on the spouse's sense of control. Copyright © 2001 John Wiley & Sons, Ltd.     

Utilization of regenerated iron oxide for treatment of organotin compounds in seawater

We examined the removal and degradation efficiencies of regenerated amorphous iron oxide on tributyltin (TBT) and triphenyltin (TPT) in seawater. It was confirmed that following contact with iron oxide at 20 and 60?°C, the half-lives of TBT and TPT were shortened. These half-lives were from one-thousandth to one-tenth for natural environment conditions. Dibutyltin and benzene were identified as the reaction products from TBT and TPT, respectively, indicating that the degradation pathways were mainly dealkylation and dephenylation. These results indicate that the treatment method by natural energy will enable the economical and rapid reduction of organotin compounds (OTCs). For OTCs in seawater will be adsorbed on the iron oxide by the ebb and flow of the tide and solar energy will be heat source for degradation when iron oxide is prepared in coastal locations.     

The use of artificial neural networks and multiple linear regression to predict rate of medical waste generation

Prediction of the amount of hospital waste production will be helpful in the storage, transportation and disposal of hospital waste management. Based on this fact, two predictor models including artificial neural networks (ANNs) and multiple linear regression (MLR) were applied to predict the rate of medical waste generation totally and in different types of sharp, infectious and general. In this study, a 5-fold cross-validation procedure on a database containing total of 50 hospitals of Fars province (Iran) were used to verify the performance of the models. Three performance measures including MAR, RMSE and R² were used to evaluate performance of models. The MLR as a conventional model obtained poor prediction performance measure values. However, MLR distinguished hospital capacity and bed occupancy as more significant parameters. On the other hand, ANNs as a more powerful model, which has not been introduced in predicting rate of medical waste generation, showed high performance measure values, especially 0.99 value of R² confirming the good fit of the data. Such satisfactory results could be attributed to the non-linear nature of ANNs in problem solving which provides the opportunity for relating independent variables to dependent ones non-linearly. In conclusion, the obtained results showed that our ANN-based model approach is very promising and may play a useful role in developing a better cost-effective strategy for waste management in future.     

Minimizing human health effects of urban air pollution through quantification and control of motor vehicular carbon monoxide (CO) in Lahore

Impact of urban air pollution has variety of focuses such as urban ecology, human health, economy, etc. But human health is always given priority. Air pollution is threat to the lives of people living in big cities of Pakistan. In Lahore only there die 1,250 people annually because of air pollution. A strong correlation exists between urban air pollution and human health in Lahore. Growth of COPD is highest among other air pollution borne diseases. Existing mass transit system (one of driving forces behind motor vehicular emission) in Lahore due to frequent stoppages, entering and exit in flow of traffic causes excess discharge of motor vehicular carbon monoxide (CO) which is a hazardous to human health. Quantification and enumeration of this discharge is essential for environmental management. The paper is an attempt to highlight human health effects of urban air pollution through correlation and regression analysis. Further it is focused upon quantifying excess motor vehicular carbon monoxide through application of simplified mobile emission model. In light of results emission control measures are recommended.     

Erroneous mass transit system and its tended relationship with motor vehicular air pollution (An integrated approach for reduction of urban air pollution in Lahore)

Air pollution is threat to the lives of people living in big cities of Pakistan. In Lahore 1,250 people die annually because of air pollution.Mass transit system that can be put forth as solution to urban air pollution is contingent with right choice of system and its affiliation with motorized vehicles and nature of urban air pollution.Existing mass transit system in Lahore due to untrue operation causes surfeit discharge of motor vehicular carbon monoxide. Tended relationships of mass transit system with motorized vehicles and urban air pollution are quite noteworthy. The growing motor vehicles (a consequence of flawed public mass transit system) are potential source of urban air pollution. This paper attempts to highlight correlations and regression curves of existing mass transit system. Further it recommends a two facet approach for reduction of motor vehicular air pollution in Lahore.     

Hexavalent chromium reduction kinetics in rodent stomach contents

Reduction of hexavalent chromium (Cr(VI)) to trivalent chromium (Cr(III)) in the stomach prior to absorption is a well-recognized detoxification process thought to limit the toxicity of ingested Cr(VI). However, administration of high concentrations of Cr(VI) in drinking water cause mouse small intestinal tumors, and quantitative measures of Cr(VI) reduction rate and capacity for rodent stomach contents are needed for interspecies extrapolation using physiologically-based toxicokinetic (PBTK) models. Ex vivo studies using stomach contents of rats and mice were conducted to quantify Cr(VI) reduction rate and capacity for loading rates (1-400 mg Cr(VI) L⁻¹ stomach contents) in the range of recent bioassays. Cr(VI) reduction was measured with speciated isotope dilution mass spectrometry to quantify dynamic Cr(VI) and Cr(III) concentrations in stomach contents at select time points over 1 h. Cr(VI) reduction followed mixed second-order kinetics, dependent upon concentrations of both Cr(VI) and the native reducing agents. Approximately 16 mg Cr(VI)-equivalents of reducing capacity per L of fed stomach contents (containing gastric secretions, saliva, water and food) was found for both species. The second-order rate constants were 0.2 and 0.3 L mg⁻¹ h⁻¹ for mice and rats, respectively. These findings support that, at the doses that caused cancer in the mouse small intestine (?20 mg Cr(VI) L⁻¹ in drinking water), the reducing capacity of stomach contents was likely exceeded. Thus, for extrapolation of target tissue dose in risk assessment, PBTK models are necessary to account for competing kinetic rates including second order capacity-limited reduction of Cr(VI) to Cr(III).     

Exposure to carbonyl compounds in charcoal production plants in Bahia, Brazil

Studies have investigated the exposure levels of carbonyl compounds (CC) in the indoor and outdoor air of homes, vehicles, workplaces, urban and industrial areas, and rural sites. However, an investigation of these emissions and occupational exposure to CC in charcoal production facilities has not been previously conducted. The objective of this study was to measure the atmospheric concentrations of several CC to assess the exposure of workers of two charcoal plants located north of Salvador, Bahia, Brazil. Stationary and personal samples were collected using Sep-Pak® C18 cartridges that were coated with a 0.2 % acidic solution of 2,4-dinitrophenylhydrazine. The quantification of the resulting 2,4-dinitrophenylhydrazone derivatives was conducted using a high-performance liquid chromatography system with UV detection. In the personal samples, the concentrations of formaldehyde, acetaldehyde, propanone, furfural, and C4 isomers (n-butanal-isobutanal-butanone) ranged from 12 to 139, 38 to 165, 136 to 483, 39 to 114, and 63 to 132 μg?m^?3, respectively. In the stationary samples, the concentrations of these CC ranged from 20 to 160, 111 to 284, 328 to 644, 70 to 163, and 100 to 176 μg?m^?3, respectively. When compared to the occupational exposure limits for 8 h, the concentrations of formaldehyde were often greater than the levels recommended by the American National Institute for Occupational Safety and Health, which indicates a health risk for charcoal workers. These results are the first reported concerning the occupational exposure to CC in charcoal plants.