Environmental estrogenic effects and gonadal development in wild goldfish (Carassius auratus)

Serum vitellogenin (VTG) contents of wild goldfish (Carassius auratus) were investigated as a sensitive biomarker for artificial estrogenic compounds in aquatic environments. Goldfish was sampled from a pristine area, a river situated 5 km downstream from a sewage treatment works (STW), and also from the Young-San River in Korea. The female yolk precursor protein VTG was not detected when gonadosomatic index (GSI) was less than 0.85%, while VTG levels of >10 microg/ml were found in males whose GSI was less than 1.53%. In male goldfish sampled from STW and the Young-San River, the higher VTG corresponded to lower GSI. This study suggested a trend that gonad development was connected to VTG levels in both sexes, and the application of GSI and histological analysis provide an attractive possibility that it could be included in the panel of markers used for estrogenic activity investigation of aquatic environments.     

湖北省降水变化分析

全面分析了湖北省７２个气象台站自建站有观测记录以来的降水资料后,发现全省降水差异较大,分布不均;不同年代之间降水变化亦存在一定的差异。东部和江汉平原６０,７０年代偏少,８０,９０年代偏多,鄂北,三峡河谷和鄂西南５０,７０和９０年代偏少,６０,８０年代偏多,全省平均为７０年你偏少,８０年代偏多。１９８０年以来东部地区降水偏多,降大雨以上的日数增多,西部地区则相反。     

Effect of copper-tolerant rhizosphere bacteria on mobility of copper in soil and copper accumulation by Elsholtzia splendens

The role of rhizosphere bacteria in facilitating the solubility of copper (Cu) in contaminated soil and Cu accumulation in plant were studied. The bacteria strains were isolated from the rhizosphere of Elsholtzia splendens, a Cu accumulator growing on Tonglu Mountain copper mines. After the sandy soils containing 237 mg kg(-1) were incubated with the bacteria strains, it was indicated that rhizosphere microbes played an important role in influencing the availability of water-soluble Cu in soils. Soils had greater concentrations of water-extractable Cu compared with axenic soils inoculated with different bacterial strains. Further evidence for bacterial facilitation of increased solubility of Cu in the soil was obtained using the antibiotic ampicillin (0.1 mg g(-1)). There were 36% decreases in Cu concentration in the presence of bacterial strain MS12 and ampicillin together compared with bacterial inoculation alone. Different bacterial strains had different abilities on soil water-soluble Cu. To achieve the highest rates of plant Cu accumulation, it was necessary for bacteria to be present in the rhizosphere of E. splendens. Inoculated plants supplied with 20 micromol L(-1) CuSO4 had significantly greater concentrations of Cu in shoots and roots than uninoculated plants and bacterial strain MS2 was the most effective strain in promoting plant Cu uptake. There were 2.2-fold and 2.5-fold increases in Cu accumulation in the shoots and roots of plants inoculated with strain MS2 compared to axenic controls. Furthermore, when ampicillin and the bacterial strains were added together to the nutrient solution, the Cu concentrations in roots and shoots of ampicillin-treated plants were lower than those in inoculated plants. When ampicillin was added to the nutrient solution, Cu accumulation was inhibited by about 24-44% in shoots and 20-44% in roots. The above results provided a new insight into the phytoremediation of Cu-contaminated soil.     

上海市郊中小河流夏季水污染特征研究

在夏季对上海郊区一典型的中、小河流河网水质进行监测 ,结果表明 :(1)河流水体普遍有很高的氮磷和有机负荷 ,其CODcr、总磷、总氮等指标均数倍于《地面水环境质量标准》中规定的V类水最大允许值 ,水体正处于严重的富营养化状态。位于集镇居民区和养殖场附近河流的污染更为严重。 (2 )受富营养化和河流底泥污染物释放的影响 ,河流水质还存在分层现象 ,尤其是水流滞缓、水深不足两米的小河流更为明显。主要表现为 :底层水氨氮 ,TRP(总反应态磷 )和SRP(溶解反应态磷 )的含量明显高于表层水 ;而表层水的 pH和DO高于底层水 ;同时 ,由于底层水处于厌氧的环境下 ,NO- 3-N、NO- 2 -N含量低于表层水。 (3)由于长期受纳污水、污物 ,中、小河流底泥有很高的氮磷累积 ,凯氏氮平均达 3.5 2 6 (N ,mg) / g ;总磷平均达 2 0 5 2 .2 5 0 (P ,mg) /kg。集镇居民区河流底泥总磷含量高达 5 813.838(P ,mg) /kg ;养殖场附近河流底泥凯氏氮高达 5 .96 4 (N ,mg) / g。底泥孔隙水中的NO- 3-N、NO- 2 -N含量很低 ;NH+4的含量是河流底层水的 3～ 2 4倍 ;SRP的含量约是河流底层水的 2～ 16倍。由于底泥有机污染重 ,耗氧量大 ,处于厌氧的环境 ,其交换态Fe2 +的含量很高     

Remove cooking fume using catalytic combustion over Pt/La-Al2O3

Five monolithic catalysts with low noble metal content were prepared by irnmerge method （Pt/γ=Al2O3, Pt/La-Al2O3, Pt/YSZ-AI203, Pt＋Pd/La-Al2O3 and Pd/La-Al2O3） and their activity measurements were carried out in a conventional fixed-bed flow reactor. The results show that La-Al2O3 can promote activity of the prepared catalysts and can decrease the complete conversion temperature of cooking fume. The Pt/La-Al2O3 catalyst has the highest activity and can be applied in wide range of gas hourly space velocity （GHSV）. Some characterizations （XRD, TPR） were carried out with the objective to explain differences in catalytic behaviors. The prepared catalyst showed a great potential for application.     

化工园区安全规划发展历史回顾

系统回顾了化工园区安全规划的发展历史,简要介绍不同国家化工园区安全规划的分区制思想以及相应的法律法规要求。以1970年代中期为界,化工园区安全规划历史大体可分为两个阶段。第一阶段基本确立了土地利用规划分区制的思想,风险越大,工业活动就建设在距人居环境越远的区域。但由于没有量化的理论和方法支持,因此,不能准确确定合适的安全距离。第二阶段从科学的土地利用规划开始并得益于定量风险评价的日趋成熟和广泛使用。由于能够定量计算出比较准确的安全距离和可承受风险,因而可以更好地进行工业活动分区和安全规划。目前单纯基于风险的安全规划暴露出一定的局限性,人们不仅要考虑工业活动的潜在风险,而且需要综合考虑经济、社会、环境、生态以及人文历史等诸多因素,因此,急需研究能够综合处理复杂问题的安全规划理论和方法。回顾历史并分析和比较,笔者认为,科学的安全规划是预防重特大事故的根本措施之一,健全的法制基础是实施安全规划的必要保障,风险评价技术是实施安全规划的有力武器。取得的研究成果对我国化工园区以及其他工业园区的建设具有一定的借鉴和启迪作用。     

油气管道腐蚀可靠性的贝叶斯评价法

对油气管道腐蚀危害因素进行分析,建立其失效故障树。根据故障树分析原理,找出导致管道腐蚀穿孔破坏的23个因素。通过对故障树的定性分析,采用下行法求出油气管道腐蚀失效故障树的96个全部最小割集,并确定失效的主要影响因素。结合最小割集不相交化法和贝叶斯可靠性评定法对管道腐蚀失效进行定量分析,通过某油气管道事故统计数据,利用贝叶斯可靠性评定方法求出油气管道腐蚀可靠性的一阶矩和二阶矩。对一阶矩和二阶矩进行拟合,求出油气管道腐蚀可靠性的第一近似下限和第二近似下限。结果表明:得出的油气腐蚀管道贝叶斯可靠性评价结果可以指导管道系统的维护和维修,降低管道运行的风险。     

细水雾熄灭障碍物火的实验研究和数值模拟

为了研究细水雾灭火系统在网状和条状障碍物阻隔条件下的灭火效果,采用全尺寸试验研究和数值模拟的方法研究了障碍物的形状,位置,遮挡面积以及细水雾工作压力对灭火效果的影响.实验结果表明:提高压力有助于快速有效地熄灭障碍物火;障碍物的位置是影响灭火效果的重要因素,近距离的覆盖使细水雾难以进入火区.障碍物下出现局部高温区,余火难以扑灭,灭火时间至少需要56 s;而障碍物距离火源较远时,卷吸作用下细水雾仍能均匀的进入火区,发挥冷却作用,灭火时间在18 s以内;网状障碍物的遮挡面积,对灭火效果影响不大;相同遮挡面积条件下,条状障碍物火比较难熄灭.     

矿井通风网络系统敏感度的研究

根据通风系统的风阻与风量的变化关系,以象山矿的局部通风图为例,对井下复杂的通风网络的敏感度进行研究.经过实例运算,以图形的形式得出敏感区域,然后对这些敏感区进行重点调风,这样不但可以在新建或改建、扩建矿井时减少工时工料,还可以加强对井下通风的安全管理工作.