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921.
922.
Phorate (O,O-diethyl S-ethylthiomethyl phosphorodithioate) dissolved in aqueous solution was almost completely decomposed by ozonation to form various species within 10 minutes of reaction time for the experimental conditions examined in this research. The generation rate of sulfate was found to be fairly independent of solution pH value. However, the formation of phosphate and carbonate was more favorable for alkaline solutions where hydroxyl free radical is the primary oxidative species. The reaction rates increased with initial gaseous ozone concentrations, indicating the reaction was mass transfer-controlled within the experimental range of this research. Combining the analytical results by various instruments, including gas chromatograph equipped with an electron ionization detector (GC-EID), high performance liquid chromatography (HPLC), ion chromatography (IC), and total organic carbon (TOC), the temporal sequence of phorate ozonation was proposed in this study. The oxidation of sulfur atoms on the phosphorus-sulfur double bond or carbon-sulfur-carbon bond by ozonation was found to occur at first to form sulfate and various intermediates. 相似文献
923.
廊坊市的地震基本烈度为 8度 ,同时受中远场和近场地震影响。具有背景地震烈度较高而高烈度地震发震概率较小的特点。本文研究了根据廊坊市地震动加速度参数特点进行的框架结构隔震建筑设计方法与实例 相似文献
924.
采用理论计算和实测相结合的方法估计了江苏数字地震台网的地震监测能力。虽然用两种方法得到的监测区略有差异 ,但几何形状相近 ,其公共区域部分更趋合理地反映了目前江苏数字地震台网的监测范围。比较了速度型和位移型地震记录的差异 ,并讨论了其监测范围差异的原因 相似文献
925.
广州市昼夜道路交通噪声的监测与分析 总被引:7,自引:1,他引:6
对广州市的昼夜交通噪声污染现状进行了分区域分道路等级的实地监测,得到共53个监测点位白天和夜晚的等效声级及其统计声级,同时对每个监测点展开了交通流调查,并分析交通流特征对交通噪声的影响。监测结果表明, 白天快速路、主干路、次干路及支路的平均等效声级分别为74.2、72.2、67.8、65.1 dB,快速路及主干路沿线的交通噪声污染比次干路及支路的严重。夜晚所有测点的噪声值均超过55 dB,快速路、主干路、次干路及支路的平均等效声级分别为72.2、72.3、66.3、64.5 dB,广州市夜晚的交通噪声污染较为严重。 相似文献
926.
927.
928.
Lijin Lin Jun Shi Qihua Liu Ming’an Liao Luoyin Mei 《Environmental monitoring and assessment》2014,186(7):4051-4056
In a preliminary study, we found that the cadmium (Cd) concentrations in shoots of the winter farmland weeds Cardamine hirsuta Linn. and Gnaphalium affine D. Don exceeded the critical value of a Cd-hyperaccumulator (100 mg kg?1), indicating that these two farmland weeds might be Cd-hyperaccumulators. In this study, we grew these species in soil containing various concentrations of Cd to further evaluate their Cd accumulation characteristics. The biomasses of C. hirsuta and G. affine decreased with increasing Cd concentrations in the soil, while the root/shoot ratio and the Cd concentrations in shoot tissues increased. The Cd concentrations in shoots of C. hirsuta and G. affine reached 121.96 and 143.91 mg kg?1, respectively, at the soil Cd concentration of 50 mg kg?1. Both of these concentrations exceeded the critical value of a Cd-hyperaccumulator (100 mg kg?1). The shoot bioconcentration factors of C. hirsuta and G. affine were greater than 1. The translocation factor of C. hirsuta was less than 1 and that of G. affine was greater than 1. These findings indicated that C. hirsuta is a Cd-accumulator and G. affine is Cd-hyperaccumulator. Both plants are distributed widely in the field, and they could be used to remediate Cd-contaminated farmland soil in winter. 相似文献
929.
Biosurfactant-producing strains in enhancing solubilization and biodegradation of petroleum hydrocarbons in groundwater 总被引:2,自引:0,他引:2
Hong Liu Hang Wang Xuehua Chen Na Liu Suriguge Bao 《Environmental monitoring and assessment》2014,186(7):4581-4589
Three biosurfactant-producing strains designated as BS-1, BS-3, and BS-4 were screened out from crude oil-contaminated soil using a combination of surface tension measurement and oil spreading method. Thin layer chromatography and infrared analysis indicated that the biosurfactants produced by the three strains were lipopeptide, glycolipid, and phospholipid. The enhancement of solubilization and biodegradation of petroleum hydrocarbons in groundwater employing biosurfactant-producing strains was investigated. The three strain mixtures led to more solubilization of petroleum hydrocarbons in groundwater, and the solubilization rate was 10.5 mg l?1. The combination of biosurfactant-producing strains and petroleum-degrading strains exhibited a higher biodegradation efficiency of 85.4 % than the petroleum-degrading strains (71.2 %). Biodegradation was enhanced the greatest with biosurfactant-producing strains and petroleum-degrading strains in a ratio of 1:1. Fluorescence microscopy images illustrate that the oil dispersed into smaller droplets and emulsified in the presence of biosurfactant-producing strains, which attached to the oil. Thus, the biodegradation of petroleum hydrocarbons in groundwater was enhanced. 相似文献
930.