海洋石油工程清洁生产评估方法研究

从资源能源利用、废弃物产生、废弃物回收利用、污染物处理、环境管理效果和环境响应情况着手,建立了包括6个一级指标、29个二级指标的海洋石油工程清洁生产评估指标体系;研究利用专家调查和层次分析法确定各评估指标的权重值,探索评估指标的赋值方法、标准化方法,提出了海洋石油工程清洁生产综合指数计算方法体系。     

我国石油炼化企业主要水污染物排放量核算方法研究

从企业工艺和产品特点出发,分析了石油炼制企业主要水污染物的排放量与企业加工量、加工工艺、加工装置、末端治理设施之间的简单逻辑关系,提出了一种基于企业规模、生产装置特征和污染治理技术的石油炼化企业水污染物排放量复杂系数核算方法。通过与实际监测数据的对比,该方法的误差满足总量核算中石油炼化企业排放量核算的要求,为行业总量减排核算提供了一种新的方法。     

Influence of hypothyroidism on oxidative stress,c-Fos expression,cell cycle,and apoptosis in rats testes

The molecular basis of male reproduction for cross-regulation between androgen and thyroid hormone axes is still rudimentary. This study aims to define a possible mechanism of hypothyroidism-induced reproductive influence with respect to sex hormone, mineral, sperm motility, oxidative stress, c-Fos expression, cell cycle, and apoptosis in rat testes. The Wistar rats were randomly divided into control group (NS) and hypothyroidism group [1 ml/100g BW/day, 0.1% propylthiouracil (PTU)] by intragastric gavage for 60 days. Blood samples were collected to measure the serum levels. The epididymis was excised to measure sperm motility and testes were excised to measure mineral, oxidative stress, c-Fos expression, cell cycle, and apoptosis. After 60 days, body weight, relative testes weight, triiodothyronine, and total thyroxine were all significantly decreased, whereas thyroid stimulating hormone was increased in the hypothyroidism group. A significant increase in sex hormone level of estradiol (E2) and significant decreases in testosterone (T) and T/E2 ratio were observed following PTU treatment. And sperm quality was also significantly changed. There were significant decreases in the contents of calcium (Ca²⁺) and zinc (Zn²⁺). On the other hand, malondialdehyde and hydrogen peroxide contents significantly increased, whereas the activity of superoxide dismutase, catalase and nitric oxide synthase and nitric oxide content significantly decreased in hypothyroid rats. The mRNA and protein expressions of c-Fos decreased significantly. The cell percentage in G0/G1 phase increased significantly, whereas decreased significantly in S and G2/M phases. Also, a significant increase in testicular cell apoptosis was observed in hypothyroid-treated rats. These results suggested that hypothyroidism could affect reproductive function in the form of changed sex hormone levels, sperm motility and testicular Ca²⁺ and Zn²⁺, and enhanced oxidative stress leading to c-Fos abnormal expression and increased apoptosis.     

基于粗糙集与GIS的滑坡地质灾害风险评估——以广西梧州为例

针对梧州市地质环境条件、地质灾害发育情况,选取地貌类型、坡度、河水侧蚀、地层岩性、残坡积层厚度、断裂发育情况、年降雨量、道路工程活动和建筑工程活动9个因子作为滑坡地质灾害危险性评估指标;选取人口密度、土地资源、交通设施、房屋及其附属价值和抗灾能力5个因子作为承灾体易损性评估指标,通过地理信息系统空间分析技术和粗糙集理论,划分研究区评估单元,构建滑坡地质灾害危险性与承灾体易损性评估知识表达系统和决策表,实现决策表的优化和各指标权重的计算。给合地质灾害风险评估模型,将研究区滑坡地质灾害风险性分为极高风险、高风险、中风险和低风险区,其中,极高风险区约占研究区总面积的6.44%,主要沿傍山而建的城镇和切坡坡度、坡高较大的交通干线分布。研究结果表明,粗糙集与GIS的组合方法能合理可靠地评估滑坡地质灾害风险性,对类似地区的滑坡地质灾害风险评估具有借鉴意义。     

Serious BTEX pollution in rural area of the North China Plain during winter season

Atmospheric BTEX compounds(benzene, toluene, ethylbenzene and xylenes) in a rural site of the North China Plain(NCP) were preliminarily investigated in winter, and the outdoor concentrations(25.8–236.0 μg/m3) were found to be much higher than those reported in urban regions. The pollution of BTEX inside a farmer's house was even more serious, with combined concentrations of 254.5–1552.9 μg/m3. Based on the ratio of benzene to toluene(1.17 ± 0.34) measured, the serious BTEX pollution in the rural site was mainly ascribed to domestic coal combustion for heating during the winter season. With the enhancement of farmers' incomes in recent years, coal consumption by farmers in the NCP is rapidly increasing to keep their houses warm, and hence the serious air pollution in rural areas of the NCP during winter, including BTEX, should be paid great attention.     

推进养殖污染防治,实现产业优化与环境保护双赢——对《水污染防治行动计划》的解读

针对《水污染防治行动计划》提出的畜禽养殖污染治理思路和措施,梳理了我国现阶段畜禽养殖污染防治中存在的问题,对《水污染防治行动计划》中提出的"调布局、建设施、促利用"三大举措进行了分析和解读,提出了落实《水污染防治行动计划》的几项重点工作,为地方推进畜禽养殖污染防治工作提供参考。     

连续流动法测定沉积物中的酸挥发性硫化物

优化沉积物中酸挥发性硫化物(Acid Volatile Sulfide,AVS)的提取方法并采用连续流动分析法检测提取液中的硫化物.研究了吸收液的种类、氮气流量与吹气的时间和反应温度对AVS提取效果的影响以优化提取方法.结果表明,与传统的氢氧化钠或硫酸镉-氢氧化钠吸收液相比,以氯化锌-羧甲基纤维素钠溶液为吸收液吸附效率好,稳定性高且无毒.用连续流动分析法检测提取液中的AVS快速、准确、稳定性好.     

石化企业阀门内漏检测模拟试验研究

自行设计、加工一套阀门内漏模拟试验装置,通过对不同尺寸阀门的模拟检测和数据分析,找出阀门发生内漏时的最佳检测位置,并发现阀门内漏时的声发射信号与系统压力、阀门尺寸之间的关系,保证了石化企业阀门内漏检测工作的顺利开展.