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91.
Biobased Epoxy/Layered Silicate Nanocomposites: Thermophysical Properties and Fracture Behavior Evaluation 总被引:1,自引:0,他引:1
Hiroaki?Miyagawa Manjusri?Misra Lawrence?T.?Drzal Amar?K.?MohantyEmail author 《Journal of Polymers and the Environment》2005,13(2):87-96
The biobased epoxy containing epoxidized linseed oil (ELO) and its clay nanocomposites were processed with an anhydride curing agent. The certain amount of diglycidyl ether of bisphenol F (DGEBF) was replaced by ELO. The selection of the DGEBF, ELO, an anhydride curing agent, and organo-montmorillonite clay resulted in an excellent combination, to provide new biobased epoxy/clay nanocomposites showing high elastic modulus, high glass transition temperature, and high fracture toughness with larger amount of ELO. Izod impact strength was almost constant while changing the amount of ELO. This is a promising result for future applications in different engineering industries. 相似文献
92.
93.
Kisku GC Pandey P Negi MP Misra V 《Journal of environmental biology / Academy of Environmental Biology, India》2011,32(6):831-838
Uptake and accumulation of metals in crops may cause possible health risks through food chain. A field survey was conducted to investigate the accumulation of potentially toxic metals contamination in soil and plants irrigated with complexed industrial effluents. Concentration of Zn, Cu and Pb was 205-255,101-130,118-177 microg g(-1) in rhizosphere soils and 116-223, 57-102 and 63-95 microg g(-1) d. wt. in root and 95-186, 44-75 and 27-58 microg g(-1) d. wt. in shoot, respectively. The trend in Cu and Pb was in the order: soil > root > shoot > seed while in Zn it was soil > root > seed > shoot. Roots accumulated a larger fraction of soil Cu (70%) > Zn (67%) > Pb (54%). Bioaccumulation coefficient of soil to root ranged from 51-98 for Zn, 54-85 for Cu and 43-63 for Pb.Analysis of variance showed marginal change in bioaccumulation coefficient, noticed between plants (p > 0.05) while it varied significantly (p < 0.01) between tissues and metals. It increased from root to seed/fruit (root > shoot > seed/fruit) while decreased between metals from Zn to Pb (Zn > Cu > Pb). Out of the three, two Cu and Pb accumulated to phyotoxic levels while Zn was within threshold limit of phytotoxicity. 相似文献
94.
95.
A Study of Physicomechanical and Morphological Properties of Starch/Poly(vinylalcohol) Based Films 总被引:2,自引:0,他引:2
Dipa Ray Papri Roy Suparna Sengupta Siba Prasad Sengupta Amar K. Mohanty Manjusri Misra 《Journal of Polymers and the Environment》2009,17(1):56-63
Starch/Poly(vinylalcohol) blends in two different ratios (60:40 and 50:50) were prepared with glycerol as a plasticizer. Films
were cast by a solution casting method. One set of films were filled with 10 wt% of unmodified bentonite clay and another
set of films were crosslinked with epichlorohydrin in an alkaline medium. The prepared film samples were subjected to X-ray
diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), mechanical characterization and scanning electron microscope
(SEM). Significant changes in the tensile properties were observed depending on the different chemical constituents of the
films. The presence of clay and crosslinking with epichlorohydrin were both found to have considerable effect on the morphology
and mechanical property of the films. The SEM investigations, XRD analysis and FTIR studies revealed the interaction between
the various chemical components of the films. 相似文献