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31.
对闸北区空气自动监测站2009年SO2、NO2、PM10的浓度和气象参数变化特征进行研究,可吸入颗粒物的时间变化特征表明,总体上呈现冬春季高、夏秋季低;PM10与降水量、相对湿度、温度呈现一定的负相关性,但与风速的相关性随季节不同而不同,与气压略呈正相关性。对典型日和灰霾日PM10、SO2、NO2以及相应气象因子的特征进行了分析比较。 相似文献
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本文系统地分析了建设项目环境影响评价中面临的政策性制约因素,提出相应的解决方案与对策,包括建设项目筛选优化、编制规划环评、落实主要污染物总量控制指标、项目选址(线)努力避开环境敏感区,等等,从而有序、高效推进建设项目环评审批工作. 相似文献
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Potential particulate pollution derived from UV-induced degradation of
odorous dimethyl sulfide 总被引:1,自引:0,他引:1
UV-induced degradation of odorous dimethyl sulfide (DMS) was carried out in a static White cell chamber with UV irradiation. The
combination of in situ Fourier transform infrared (FT-IR) spectrometer, gas chromatograph-mass spectrometer (GC-MS), wide-range
particle spectrometer (WPS) technique, filter sampling and ion chromatographic (IC) analysis was used to monitor the gaseous and
potential particulate products. During 240 min of UV irradiation, the degradation e ciency of DMS attained 20.9%, and partially
oxidized sulfur-containing gaseous products, such as sulfur dioxide (SO2), carbonyl sulfide (OCS), dimethyl sulfoxide (DMSO),
dimethyl sulfone (DMSO2) and dimethyl disulfide (DMDS) were identified by in situ FT-IR and GC-MS analysis, respectively.
Accompanying with the oxidation of DMS, suspended particles were directly detected to be formed by WPS techniques. These
particles were measured mainly in the size range of accumulation mode, and increased their count median diameter throughout
the whole removal process. IC analysis of the filter samples revealed that methanesulfonic acid (MSA), sulfuric acid (H2SO4) and
other unidentified chemicals accounted for the major non-refractory compositions of these particles. Based on products analysis and
possible intermediates formed, the degradation pathways of DMS were proposed as the combination of the O(1D)- and the OH- initiated
oxidation mechanisms. A plausible formation mechanism of the suspended particles was also analyzed. It is concluded that UV-induced
degradation of odorous DMS is potentially a source of particulate pollutants in the atmosphere. 相似文献
36.
Surfactant-enhanced remediation (SER) is an effective method for the removal of volatile organic compounds (VOCs) from contaminated soils and groundwater. To reuse the surfactant the VOCs must be separated from the surfactant solutions. The water solubility of VOCs can be enhanced using reversible surfactants with a redox-acive group, (ferrocenylmethyl)dodecyldimethylammonium bromide (Fcl2) and (ferrocenylmethyl)tetradecanedimethylammonium bromide (Fcl4), above and below their critical micelle concentrations (CMC) under reducing (I+) and oxidative (I2+) conditions. The CMC values of Fcl2 and Fcl4 in I+ are 0.94 and 0.56 mmol/L and the solubilization of toluene by Fcl2 and Fcl4 in I+ for toluene is higher than the solubilization achieved with sodium dodecyl sulfate, cetyltrimethylammonium bromide and Trition X-114. The solubilization capacity of the ferrocenyl surfactants for each tested VOCs ranked as follows: ethylbenzene > toluene > benzene. The solubilities of VOCs by reversible surfactant in I+ were 30% higher than those in I2+ at comparable surfactant concentrations. The effects of Fcl4 concentrations on VOCs removal efficiency were as follows: benzene > toluene > ethylbenzene. However, an improved removal efficiency was achieved at low ferrocenyl surfactant concentrations. Furthermore, the reversible surfactant could be recycled through chemical approaches to remove organic pollutants, which could significantly reduce the operating costs of SER technology. 相似文献
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高温状态下膨润土的物性指标变化是高放核废物深地质处置库设计的重要参数之一。通过高温状态下不同受热时间MX80钠基膨润土的比重、液塑限、自由膨胀率试验,研究了受热时间对膨润土基本物性指标的影响规律;并通过热重分析(TGA)、X衍射(XDR)、电镜扫描(SEM)试验,从微观角度对上述变化规律进行了合理解释。研究结果表明:随着受热时间的增加,膨润土的比重、液塑限、自由膨胀率在受热15~30天内急剧下降,降幅分别为2.5%、3.1%和28.3%,之后各值变化量很小;高温状态下,膨润土的矿物成分转化、结合水脱附、微观形貌改变是膨润土物性指标发生变化的根本原因,三者之间相互作用和彼此影响。 相似文献
40.
The brominated products, formed in chlorination treatment of benzophenone-4 in the presence of bromide ions, were identified, and the formation pathways were proposed.Under disinfection conditions, benzophenone-4 would undertake electrophilic substitution generating mono- or di-halogenated products, which would be oxidized to esters and further hydrolyzed to phenol derivatives. The generated catechol intermediate would be transformed into furan-like heterocyclic product. The product species were p H-dependent,while benzophenone-4 elimination was chlorine dose-dependent. When the chlorination treatment was performed on ambient water spiked with benzophenone-4 and bromide ions, most of brominated byproducts could be detected, and the acute toxicity significantly increased as well. 相似文献