Secondary organic aerosol formation from ozone-initiated reactions with nicotine and secondhand tobacco smoke

We used controlled laboratory experiments to evaluate the aerosol-forming potential of ozone reactions with nicotine and secondhand smoke. Special attention was devoted to real-time monitoring of the particle size distribution and chemical composition of SOA as they are believed to be key factors determining the toxicity of SOA. The experimental approach was based on using a vacuum ultraviolet photon ionization time-of-flight aerosol mass spectrometer (VUV-AMS), a scanning mobility particle sizer (SMPS) and off-line thermal desorption coupled to mass spectrometry (TD-GC-MS) for gas-phase byproducts analysis. Results showed that exposure of SHS to ozone induced the formation of ultrafine particles (<100 nm) that contained high molecular weight nitrogenated species (m/z 400–500), which can be due to accretion/acid–base reactions and formation of oligomers. In addition, nicotine was found to contribute significantly (with yields 4–9%) to the formation of secondary organic aerosol through reaction with ozone. The main constituents of the resulting SOA were tentatively identified and a reaction mechanism was proposed to elucidate their formation. These findings identify a new component of thirdhand smoke that is associated with the formation of ultrafine particles (UFP) through oxidative aging of secondhand smoke. The significance of this chemistry for indoor exposure and health effects is highlighted.     

Role of religious communities in enhancing transition experiments: a localised strategy for sustainable solid waste management in Malaysia

Religion in its most ideal form is seen as a powerful force to create ecological transformations to succeeding generations that share similar religious beliefs. This provides an interesting argument for enhancing their role in sustainability transitions. Malaysia is a relevant geographical context in this regard since almost all of its citizens formally embrace some kind of religious belief. However, such ideas are discussed mostly at the theoretical level with little systematic empirical investigation. This paper aims to fill this gap by presenting theoretically informed empirical insights on how a number of religious communities are currently creating successful experiments in recycling within the context of an urban community in Malaysia. The paper argues that such evidence may demonstrate the ‘potential’ role of religious communities to provide localised resources for recycling experiments that can be advantageous for the transition towards a more sustainable municipal solid waste management in Malaysia. The empirical basis of this paper is based on an exploratory multiple case study of successful recycling programmes conducted by selected religious communities from four key religions in Malaysia—Buddhism, Christianity, Hinduism and Islam. The theoretical framework for this research is based on the sustainability transitions literature, particularly the ‘transition experiment’ framework.     

Characterization of Urea Encapsulated by Biodegradable Starch-PVA-Glycerol

The influence of the blending ratio of biodegradable starch/polyvinyl alcohol (PVA)/glycerol in encapsulating urea has been investigated. It is found that water absorption capacity increased approximately 135 % as the amounts of starch, PVA and glycerol in the composite film increase. Therefore, the swell ability of the composite film is increased and the urea is released from the composite film in the wet environment. The FTIR shows that the urea had been encapsulated successfully in the composite films. Moreover, the soil burial biodegradation results indicated that the biodegradability of the starch/PVA/glycerol/urea composite film strongly depended on the PVA proportion in the composite film matrix. The DSC results show that the higher the amount of PVA in the composite film, the less change of the melting enthalpy value. The crystalline region of PVA remains after biodegradation.     

Measurement of biochemical oxygen demand of the leachates

Biochemical oxygen demand (BOD) of the leachates originally from the different types of landfill sites was studied based on the data measured using the two manometric methods. The measurements of BOD using the dilution method were carried out to assess the typical physicochemical and biological characteristics of the leachates together with some other parameters. The linear regression analysis was used to predict rate constants for biochemical reactions and ultimate BOD values of the different leachates. The rate of a biochemical reaction implicated in microbial biodegradation of pollutants depends on the leachate characteristics, mass of contaminant in the leachate, and nature of the leachate. Character of leachate samples for BOD analysis of using the different methods may differ significantly during the experimental period, resulting in different BOD values. This work intends to verify effect of the different dilutions for the manometric method tests on the BOD concentrations of the leachate samples to contribute to the assessment of reaction rate and microbial consumption of oxygen.     

Ergonomic design and evaluation of a diagnostic ultrasound transducer holder

Background. Work-related musculoskeletal disorders (WMSDs) are injuries and disorders that affect the body’s movement and musculoskeletal system. Awkward postures represent one of the major ergonomic risk factors that cause WMSDs among sonographers while working with an ultrasound transducer. This study aimed to design and evaluate a new holder for the ultrasound transducer. Materials and methods. In the first phase a new holder was designed for the transducer, considering design principles. Evaluation of the new holder was then carried out by electrogoniometry and a locally perceived discomfort (LPD) scale. Results. The application of design principles to the new holder resulted in an improvement of wrist posture and comfort. Wrist angles in extension, flexion, radial deviation and ulnar deviation were lower with utilization of the new holder. The severity of discomfort based on the LPD method in the two modes of work with and without the new holder was reported with values of 1.3 and 1.8, respectively (p?<?0.05). Conclusion. Overall, this study indicated that applying ergonomics design principles was effective in minimizing wrist deviation and increasing comfort while working with the new holder.     

Radiant Domestic Combustion Stove System: Experimental and Simulated Study of Energy Use and Thermal Comfort

A steady-state space radiant heat model and a stove combustion model are developed to simulate the heat exchanges between various surfaces in the room and the stove and stack surfaces, assuming stiochiometric combustion inside the stove and the exhaust gases flow out through the stack by natural convection. The space heat model calculates the fuel consumption, the stove, stack temperatures, and the mass flow rate of exhaust gases, and provides an opportunity to study the energy efficiency of the stove, while satisfying the constraints of thermal comfort. Fanger (1982) Fanger, P. O. 1982. Thermal Comfort Analysis and Applications in Engineering, 156–198. New York: McGraw Hill.  [Google Scholar] model and a radiation exchange model between various surfaces of the space, the thermal building energy balance, and stove combustion process is applied to determine the mean radiant temperature (MRT) and the extent of thermal comfort as determined by predicted mean vote (PMV).

The overall model is validated by performing experiments in a room placed inside a controlled outdoor environment. The room is heated using a domestic stove common for rural areas of Lebanon and the MRT, the room air temperature, the walls and window temperatures are measured at two stove positions. The measured MRT, the average room temperature, and the wall surface temperatures agreed within ±7% of values predicted by the numerical model.

A parametric study is performed to optimize the stove and occupant locations in the room where adequate comfort level can be maintained at lower fuel consumption levels. The values of MRT and PMV depend strongly on the position of the radiant stove heater and stack with respect to the cold window and the occupant location. It is shown that it is possible to save up to 15% in stove fuel consumption by changing the stove position in the room with respect to the window and to the person, while maintaining the same level of comfort.     

An Experimental and Metamodeling Approach to Tensile Properties of Natural Fibers Composites

Journal of Polymers and the Environment - The present work presents an analysis of the tensile properties of Palm as well as Luffa natural fiber composites (NFC) in high density polyethylene...