Municipal solid waste composition and food loss reduction in Kyoto City

For 35 years, Kyoto City has conducted detailed household waste composition surveys under the guidance of Kyoto University by dividing household waste into approximately 400 categories. In addition, the city has conducted detailed composition surveys of commercial waste generated by businesses. These surveys show that food loss accounts for approximately 40% of total waste, of which leftovers and untouched food account for about 40% in both households and business facilities. Consequently, the annual generation of household and commercial food loss is estimated at about 30,000 tons. Various efforts have been made to reduce waste, including food loss, but further reduction in environmental burden is needed. Thus, Kyoto City revised the ordinance for waste reduction, and in March 2015, formulated a new municipal waste management plan. The plan not only includes the 2Rs (reduce, reuse), but also, for the first time in Japan, sets quantitative targets for reducing food loss. Kyoto City must ensure that the necessary waste reduction measures are clearly explained to the residents and business operators. To ensure that this plan is successful, it is important to clarify concrete actions that residents and business operators should implement, along with their effects.     

Optimization of Pellet Production from Agro-Industrial By-Products: Effect of Plasticizers on Properties of Pellets and Composite Pots

The present study aimed to optimize the pellets formulation (deoiled rice bran, potato peel powder and plasticizers) for the development of the injection molded pots. The maximum hardness and bulk density (desirable responses) were obtained for pellets having 100 g of deoiled rice bran, 100 g potato peel powder and 14 % of cashew nut shell liquid (CNSL) as well as 14 % of glycerol (GL) (on raw material basis). The optimized pellets and the pots developed from them were characterized for their physico-chemical, functional, rheological and morphological properties. Expansion ratio, pellet durability index and hardness of the pellets with 14 % CNSL were found to be 1.097, 98.647 % and 485.551 N, respectively. For pellets with 14 % GL expansion ratio, pellet durability index and hardness were found to be 1.150, 97.747 % and 462.949 N, respectively. The biodegradation analysis of the pots developed from optimized pellets with 14 % CNSL and GL degraded in 11 and 9 weeks, respectively. Porosity, puncture force, density and hardness of ‘AP’ pots were 27.473 %, 495.731 N, 1.549 g/ml and 542.641 N, respectively. However, for ‘BP’ pots, the porosity, puncture force, density and hardness were 32.548 %, 440.149 N, 1.191 g/ml and 507.841 N, respectively. Pots prepared from 14 % CNSL (AP) were better in physical and mechanical properties as compared to pots developed from glycerol.     

Melt Flow Behavior and Processability of Polylactic Acid/Polystyrene (PLA/PS) Polymer Blends

The present investigation dealt with the flow behavior and processability of polylactic acid/polystyrene (PLA/PS) polymer blends using a capillary rheometer. For this purpose, PLA/PS blends with different ratios of the concentrations were prepared using a single screw extruder. The shear viscosity, shear stress, shear rate, power-law index, viscous activation energy at a constant shear stress, and elongational stress were determined. PLA/PS blends exhibited a typical shear-thinning behavior over the entire range of shear rates tested, and the viscosity values of the blends would tend to decrease with increasing amount of PLA. In addition, the polymer blend of 70 % PLA and 30 % PS was found to be relatively less sensitive to the processing temperature, implying that the extrusion process was more desirable for fabrication of PLA/PS polymer blend than the injection process.     

Food Industry Co-streams: Potential Raw Materials for Biodegradable Mulch Film Applications

Vast amounts of co-streams are generated from plant and animal-based food processing industries. Efficient utilization of these co-streams is important from an economic and environmental perspective. Non-utilization or under-utilization of co-streams results in loss of potential revenues, increased disposal cost of these products and environmental pollution. At present, extensive research is taking place around the globe towards recycling of co-streams to generate value-added products. This review evaluates various co-streams from food processing industries as raw materials in developing biodegradable agricultural mulching applications. Among the agriculture-based co-streams, potato peels, tomato peels, carrot residues, apple pomace, coffee residues and peanut residues were reviewed with respect to production amount, composition, film forming components and film forming capabilities. Similarly, selected co-streams from slaughterhouses, poultry and fish processing industries were also reviewed and evaluated for the same purpose.     

Enhancement of turbulent scalar mixing and its application by a multihole nozzle in selective catalytic reduction of NOx

The mixing characteristics of a passive scalar in the turbulent flow of a selective catalytic reduction process were numerically and experimentally investigated, focusing especially on an injection nozzle with multiple holes for the reducing agent. The multihole injection nozzle studied has six holes that are perpendicular to the ambient flue gas flow and are located near the tip of the nozzle. Large eddy simulation was applied to the turbulent flow and mixing fields to elucidate the mixing mechanism of the proposed nozzle compared with the single-hole nozzle that is commonly used in the conventional selective catalytic reduction process. From the results, there exist broader regions of higher turbulent intensities for the multihole nozzle than for the conventional single-hole nozzle. These regions are well matched with the positions of high vorticity in the near upstream region of the jet flow issuing from the multiple holes of the nozzle. Consequently, the high turbulent intensities and vorticity magnitudes lead to intensified mixing between the flue gas and the reducing agent. Hence, the most suitable molar ratio between NOx and the reducing agent for the catalytic reaction can be easily obtained within a shorter physical mixing length as a result of the enhanced scalar mixing. Finally, the numerical results were applied to a trial design version of a multihole nozzle, and this nozzle was experimentally tested to confirm its mixing performance.     

Initial Changes in Refilled Lysimeters Built with Metal Polluted Topsoil and Acidic or Calcareous Subsoils as Indicated by Changes in Drainage Water Composition

Soil translocation for recultivation of soil removed from construction sites and for the preparation of refilled lysimeters inevitably involves disturbance of soil structure, and, if intermediate storage is included, also drying and rewetting of the soil. We report on an experiment with model forest ecosystems, where uncontaminated forest subsoils were covered with non-contaminated or freshly heavy metal (mainly Zn and Cu) contaminated topsoil in large lysimeters. Monitoring of the chemical composition of the drainage water revealed two distinct soil conditioning phases. During an initial phase of about a year strongly elevated nitrate and sulfate concentrations occurred that were attributed to a mineralisation flush caused by the increased accessability of mineralisable nitrogen and sulfur in destroyed aggregates. These effects were significantly larger in lysimeters with calcareous subsoil than in those with acidic subsoil. The second phase was characterised by a gradual decrease in dissolved organic carbon and sulfate concentrations, in particular in the acidic subsoil. This decrease may be attributed to the depletion of pools made accessible during aggregate destruction or the formation of new aggregates. These chemical changes had only little effects on the concentrations of copper and zinc in the drainage water. Based on our results, it can be concluded that large refilled lysimeters can be used for many purposes without risk of compromised results, if a conditioning phase of about 1 year with sufficiently moist soil conditions is respected. Nevertheless, gradual changes in soil chemical characteristics still occur after this initial phase. Implications for the recultivation of sites using relocated soils are discussed.     

Leaching behavior of heavy metals from municipal solid waste incineration bottom ash and its geochemical modeling

With the increase in the number of municipal solid waste incineration (MSWI) plants constructed in China recently, great attention has been paid to the heavy metal leaching toxicity of MSWI residues. In this study, the effects of various parameters, including extractant, leaching time, liquid-to-solid ratio, leachate pH, and heavy metal content, on the release properties of Cd, Cr, Cu, Ni, Pb, and Zn from MSWI bottom ash were investigated. Partial least-squares analysis was employed to highlight the interrelationships between the factors and response variables. Both experimental research and geochemical modeling using Visual MINTEQ software were conducted to study the pH-dependent leaching behavior of these metals in fresh and weathered bottom ash, considering precipitation/dissolution and surface complexation reactions (adsorption by hydrous ferric oxide and amorphous aluminum oxide/hydroxide). The results showed that leachate pH was the predominant factor influencing heavy metal leachability. The leaching of Cu, Pb, and Zn was mainly controlled by precipitation/dissolution reactions, whereas surface complexation had some effect on the leaching of Cr, Cd, and Ni for certain pH ranges. The modeling results aggreed well with the experimental results. Part of this work was presented at the Fourth International Conference on Combustion, Incineration/Pyrolysis and Emission Control (i-CIPEC)     

Long Term Trends in Concentration of Major Pollutants (SO<Subscript>2</Subscript>, CO,NO, NO<Subscript>2</Subscript>, O<Subscript>3</Subscript> and PM<Subscript>10</Subscript>) in Prague – Czech Republic (Analysis of Data Between 1992 and 2005)

To assess the effect of changes in traffic density and fuels used for heating at the beginning of the 1990s, 1992–2005 monthly averages of PM₁₀, SO₂, NO₂, NO, CO and O₃ from Prague, the Czech capital, were analyzed together with long term trends in emissions of major pollutants, fuel consumption and number of vehicles registered in Prague. The data from all monitoring stations were retrieved from the database of the state automated monitoring system. Correlation coefficients between ambient monthly averaged temperature and all pollutants of concern showed distinct seasonal trends. The results showed that while SO₂ and to some extent also CO concentrations dropped namely in the first half of the analyzed period (1992–1997) as a result decreased fossil fuel consumption for local heating, the behaviour of other pollutant concentrations followed a different pattern. PM₁₀ concentrations decreased during the beginning of the 1990s but showed a sign of increase after 2000. Concentrations of ozone and NO₂ did not reveal any significant change throughout the whole studied period. It can be concluded that during the studied period traditional urban sources of pollution, such as coal and oil combustion, lost their importance but were simultaneously substituted by pollutants from automotive transport (namely PM and NO₂) making the problem of air quality even worse.     

Influence of Technological Process on Biodegradation of PVA/Waxy Starch Blends in an Aerobic and Anaerobic Environment

Improving biodegradability of PVA/starch blends is a reality already documented by a number of works. Admittedly, mechanical properties of products (for example, tensile strength) are somewhat worse, but suitable composition optimizing or chemical modifying of starch may eliminate the problem to a large degree. This work is an attempt to find another potential effect influencing biodegradability, that of technological procedure for producing films from these blends on an extruder. The procedure with a so-called pre-extrusion step (two-stage) and dry-blend (single-stage) produced blends of slightest differences in achieved biodegradability (virtually within limits of experimental error) in aerobic (76 vs. 79%) as well as anaerobic breakdown (48 vs. 52%). Conversely, morphological analysis exhibited superior homogeneity of films prepared by the two-stage process; their tensile strength was also higher.