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101.
Fenton process, as a pretreatment method, was found to be effective in the primary treatment of mature/medium landfill leachate. However, the main problem of the process is the large amount of produced sludge that requires an accurate feasibility evaluation for operational applications. In this study, the response surface methodology was applied for the modeling and optimization of Fenton process in three target responses, (1) overall COD removal, (2) sludge to iron ratio (SIR) and (3) organics removal to sludge ratio (ORSR), where the latter two were new self-defined responses for prediction of sludge generation and applicability assessment of the process, respectively. The effective variables included the initial pH, [H2O2]/[Fe2+] ratio and Fe2+ dosage. According to the statistical analysis, all the proposed models were adequate (with adjusted R2 of 0.9116–0.9512) and had considerable predictive capability (with prediction R2 up to 0.9092 and appropriate adequate precision). It was found that all the variables had significant effects on the responses, specifically by their observed role in dominant oxidation mechanism. The optimum operational conditions obtained by overlay plot, were found to be initial pH of 5.7, [H2O2]/[Fe2+] ratio of 17.72 and [Fe2+] of 195 mM, which led to 69% COD removal, 2.4 (l sludge/consumed mole Fe2+) of SIR and 16.5 (gCOD removed/l produced sludge) for ORSR in verification test, in accordance with models-predicted values. Finally, it was observed that [H2O2]/[Fe2+] ratio and Fe2+ dosage had significant influence on COD removal, while Fe2+ dosage and [H2O2]/[Fe2+] ratio had remarkable effects on SIR and ORSR responses, respectively. 相似文献
102.
Hassan Abdel-Gawad Hamdy Taha 《Journal of environmental science and health. Part. B》2013,48(8):683-690
Sunflower plants were treated with 14C-chlorpyrifos under conditions simulating local agricultural practice. Residues present in the oil, methanol extract and cake of the treated sunflower seeds were 7.2, 2.8, and 12 ppm, respectively. When rats fed on sunflower cake containing bound residues for three days, the animals eliminated 46 % of the radioactivity in urine, 25 % in feces and 10 % in the expired air. A further bioavailable amount of 8 % was found in selected organs indicating that the bound residues were highly bioavailable. Chromatographic analysis of urine extract revealed the presence of the parent compound, its oxon, desethyl chlorpyrifos and desethyl chlorpyrifos oxon as free metabolites in addition to a conjugated metabolite. It was liberated by acid hydrolysis and identified as 3,5,6-trichloro-2-hydroxypyridine. Bound residues were found to have biological effects such as inhibition of rat plasma ChE, elevations of liver parameters (ALT, AST, and ALP), decrease in total protein and albumin content suggesting a hepatotoxic potential. A significant increase in the values of creatinine, urea, cholesterol, triglycerides and significant decrease in Catalase and Glutathion-S-Transfrase were observed in treated rats. 相似文献
103.
Nazan Karsavuran Mohammad Charehsaz Hayati Celik Bayram Murat Asma Cengiz Yakıncı 《毒物与环境化学》2013,95(10):1564-1570
Hydrogen cyanide (HCN) poisoning due to amygdalin (AMY) in apricot seeds is one of the public health issues in Turkey. The aim of this study was to investigate the AMY content of 13 different apricot seeds including bitter and sweet ones, and which are either sulfurized or roasted. The AMY content was determined by a high-performance liquid chromatography. Release of HCN was predicted and total amount of seeds which can cause poisoning was calculated. The mean AMY content of bitter seeds was 26 ± 14 mg g?1 and that of sweet seeds was 0.16 ± 0.09 mg g?1. The consumption of small amounts of bitter seeds may cause cyanide poisoning. 相似文献
104.
Asl Sahar Sadeghi Tafvizi Farzaneh Noorbazargan Hassan 《Environmental science and pollution research international》2023,30(8):20168-20184
Environmental Science and Pollution Research - Drug resistance of cancer cells is a major issue in cancer treatment. Plant-mediated nanoparticle synthesis has been applied in recent years to... 相似文献
105.
Parinaz Poursafa Ehsan Ataee Mohammad Esmaeel Motlagh Gelayol Ardalan Mohammad Hassan Tajadini Maryam Yazdi Roya Kelishadi 《Environmental science and pollution research international》2014,21(23):13496-13502
This study aims to determine the difference of serum Pb and Hg levels in adolescents with or without metabolic syndrome (MetS) and the association of serum levels of these heavy metals with cardiometabolic risk factors and liver enzymes in Iranian adolescents. The study population consisted of 320 adolescents (160 with MetS and 160 healthy controls). The relationship between serum heavy metals and cardiometabolic risk factors was assessed by linear regression. The odds ratios (OR) of having metabolic syndrome across Pb and Hg quartiles were determined by multiple logistic regression analysis. The mean (SD) of Pb and Hg concentrations were higher in adolescents with MetS than in those without it (0.83 (0.27) and 0.17 (0.01) vs. 0.65 (0.15) and 0.10 (0.08)?μg/L, P?=?0.01 and 0.0001, respectively). Increase in serum Pb and Hg was associated with increase in some cardiometabolic risk factors. Among boys and girls, diastolic blood pressure (DBP), fasting blood glucose, total cholesterol (TC), triglycerides (TG), and alanine aminotransaminase increased significantly across quartiles of serum Pb. Among girls, SBP, DBP, TC, and TG had a significant increase across Hg quartiles. The corresponding figure among boys was significant for SBP, DBP, and TG. Higher quartiles of Pb increased the risk of having MetS (OR 95 % CI 3.10, 2.25–4.27), the corresponding figure was 2.03, 1.75–3.16, across Hg quartiles. Our study showed significant associations between serum Pb and Hg levels with cardiometabolic risk factors in adolescents. In future surveys, the role of potential confounders should be considered more extensively. The clinical significance of these findings needs to be confirmed in longitudinal studies. By considering the origins of chronic diseases from early life, controlling environmental pollutants should be considered as a health priority for primordial or primary prevention of noncommunicable diseases. 相似文献
106.
Mohammad Ashik Iqbal Khan Kihachi Ueno Sakae Horimoto Fuminori Komai Takashi Someya Koichi Inoue Kinji Tanaka Yoshitaka Ono 《Waste management (New York, N.Y.)》2009,29(12):2969-2975
The composting process of different organic wastes both in laboratory and on a large-scale was characterized using CIELAB color variables to evaluate compost stability for the better application in agriculture. The time courses of the CIELAB variables of composting materials were determined directly from the bottom of a glass petri dish filled with dried and ground samples using a Minolta Color Reader (CR-13) calibrated with clean empty petri dishes placed on a white tile. To compare the proposed method with conventional methods, the same materials were also evaluated using commonly used compost stability evaluation indices. Most of the CIELAB variables of a compost made from a mixture of green tea waste and rice bran reached a plateau after 84 days of composting and showed strong relationships with the commonly used compost stability evaluation indices. The time needed for CIELAB variables, especially the L*and b* values, to stabilize at large-scale composting plants of cattle litter, farmyard manure, kitchen garbage and bark compost, were more or less similar to the times of maturation evaluated by the respective compost producers. The CIELAB color variable offers a new, simple, rapid and inexpensive means of evaluating compost stability and its quality prior to agricultural use. 相似文献
107.
Roohollah Noori Abdulreza Karbassi Mohammad Salman Sabahi 《Journal of environmental management》2010,91(3):767-771
Artificial neural networks (ANNs) are suitable for modeling solid waste generation. In the present study, four training functions, including resilient backpropagation (RP), scale conjugate gradient (SCG), one step secant (OSS), and Levenberg–Marquardt (LM) algorithms have been used. The main goal of this research is to develop an ANN model with a simple structure and ample accuracy. In the first step, an appropriate ANN model with 13 input variables is developed using the afore-mentioned algorithms to optimize the network parameters for weekly solid waste prediction in Mashhad, Iran. Subsequently, principal component analysis (PCA) and Gamma test (GT) techniques are used to reduce the number of input variables. Finally, comparison amongst the operation of ANN, PCA-ANN, and GT-ANN models is made. Findings indicated that the PCA-ANN and GT-ANN models have more effective results than the ANN model. These two models decrease the number of input variables from 13 to 7 and 5, respectively. 相似文献
108.
Gholam‐Abbas Barani Mohammad Javad Khanjani 《Journal of the American Water Resources Association》2002,38(4):1053-1060
ABSTRACT: To measure crop evapotranspiration, a large double tank, electronic weighting lysimeter system was designed and installed at the Shahid Bahonar University farm, Kerman, Iran. The system was installed in a 50 m2 underground building. It includes two tanks of 3.00 m in diameter and 1.75 m deep. The weighing mechanism for each tank is a set of three compression strain gage load cells, which are fixed on 1.20 m height column above the floor. According to the specification of the load cells, the maximum possible weighing error may be about 0.01 percent of total mass, which is equivalent to 0.28 mm of water, but the measured error was equal to 1 kg mass, which is equivalent to 0.14 mm of water. The load cell data from each tank and the on‐site environmental data (temperature, humidity, and wind velocity and direction) are automatically recorded and saved in a personal computer hard disk for further use and analysis. 相似文献
109.
Ahmed I. El-Seesy Mohamed Nour Ali M. A. Attia Hamdy Hassan 《International Journal of Green Energy》2020,17(3):233-253
ABSTRACTThis article aims to study the influence of the addition of graphene oxide nanoparticles (GO) to diesel/higher alcohols blends on the combustion, emission, and exergy parameters of a CI engine under various engine loads. The higher alcohols mainly n-butanol, n-heptanol, and n-octanol are blended with diesel at a volume fraction of 50%. Then, the 25 and 50 mg/L concentrations of GO are dispersed into diesel/higher alcohols blends using an ultrasonicator. The GO structures are examined using TEM, TGA, XRD and FTIR. The findings show that there is a reduction in pmax. and HRR when adding higher alcohols with diesel fuel. Regarding engine emission, there is a significant improvement in emissions formation with adding higher alcohols. The addition of GO into diesel/higher alcohols blends improves the brake thermal efficiency by 15%. Moreover, the pmax. and HRR are both enhanced by 4%. The CO, UHC and smoke formation are reduced considerably by 40%, 50 and 20%, respectively, while NOx level is increased by 30% with adding GO. Finally, adding high percentages of n-butanol, n-heptanol, and n-octanol with diesel fuel with the presence of GO has the potential to achieve ultra-low CO, UHC, and smoke formation meanwhile keeping high thermal efficiency level. 相似文献
110.
Faezeh Ghanati Parviz Abdolmaleki Majid Vaezzadeh Elham Rajabbeigi Mohammad Yazdani 《The Environmentalist》2007,27(4):429-434
In the present research, the effects of static magnetic field, with or without iron on the growth, the activity of certain
enzymes (like polyphenol oxidase and phenyle alanine ammonialyase), the content of phenolic compounds and the essential oil
composition of sweet basil (Ocimum basilicum) were studied. Treatment of plants with static magnetic field with or without iron led to decrease of the growth of plants
as well as decrease in the activity of phenyle alanine ammonialyase and of phenolic compounds content. In addition in those
plants exposed to magnetic field the amount of essential oils, notably of methyl chavicol, was increased. Exposure of plants
to the magnetic field decreased the activity of polyphenol oxidase, whereas treatment of plants with iron when exposed to
magnetic field increased polyphenol oxidase activity. In this group the content of essential oil was reduced. 相似文献