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51.
Harrelkas F Paulo A Alves MM El Khadir L Zahraa O Pons MN van der Zee FP 《Chemosphere》2008,72(11):1816-1822
A photocatalytic process based on immobilized titanium dioxide was used to treat crude solutions of azo, anthraquinone and phthalocyanine textile dyes. In addition, the process was applied to the treat autoxidized chemically reduced azo dyes, i.e. representatives of recalcitrant dye residues after biological sequential anaerobic-aerobic treatment. Photocatalysis was able to remove more than 90% color from crude as well as autoxidized chemically reduced dye solutions. UV-absorbance and COD were also removed but to a lower extent (50% in average). The end products of photocatalytic treatment were not toxic toward methanogenic bacteria. The results demonstrate that photocatalysis can be used as a pre- or post-treatment method to biological anaerobic treatment of dye-containing textile wastewater. 相似文献
52.
The new city of Abuja provided an opportunity to avoid some of the environmental problems associated with other major cities in Africa. The current status of solid waste management in Abuja has been reviewed and recommendations for improvements are made. The existing solid waste management system is affected by unfavourable economic, institutional, legislative, technical and operational constraints. A reliable waste collection service is needed and waste collection vehicles need to be appropriate to local conditions. More vehicles are required to cope with increasing waste generation. Wastes need to be sorted at source as much as possible, to reduce the amount requiring disposal. Co-operation among communities, the informal sector, the formal waste collectors and the authorities is necessary if recycling rates are to increase. Markets for recycled materials need to be encouraged. Despite recent improvements in the operation of the existing dumpsite, a properly sited engineered landfill should be constructed with operation contracted to the private sector. Wastes dumped along roads, underneath bridges, in culverts and in drainage channels need to be cleared. Small-scale waste composting plants could promote employment, income generation and poverty alleviation. Enforcement of waste management legislation and a proper policy and planning framework for waste management are required. Unauthorized use of land must be controlled by enforcing relevant clauses in development guidelines. Accurate population data is necessary so that waste management systems and infrastructure can be properly planned. Funding and affordability remain major constraints and challenges. 相似文献
53.
Heavy metal contamination from mining sites in South Morocco: Monitoring metal content and toxicity of soil runoff and groundwater 总被引:5,自引:0,他引:5
El Khalil H El Hamiani O Bitton G Ouazzani N Boularbah A 《Environmental monitoring and assessment》2008,136(1-3):147-160
The aim of the present work is the assessment of metal toxicity in runoff, in their contaminated soils and in the groundwater
sampled from two mining areas in the region of Marrakech using a microbial bioassay MetPLATE™. This bioassay is based on the
specific inhibition of the β-galactosidase enzyme of a mutant strain of Escherichia coli, by the metallic pollutants. The stream waters from all sampling stations in the two mines were all very toxic and displayed
percent enzyme inhibition exceeding 87% except SWA4 and SWB1 stations in mine C. Their high concentrations of copper (Cu) and zinc (Zn) confirm the acute toxicity shown by MetPLATE.
The pH of stream waters from mine B and C varied between 2.1 and 6.2 and was probably responsible for metal mobilization,
suggesting a problem of acid mine drainage in these mining areas. The bioassay MetPLATE™ was also applied to mine tailings
and to soils contaminated by the acidic waters. The results show that the high toxicity of these soils and tailings was mainly
due to the relatively concentration of soluble Zn and Cu. The use of MetPLATE™ in groundwater toxicity testing shows that,
most of the samples exhibited low metal toxicity (2.7–45.5% inhibition) except GW3 of the mine B (95.3% inhibition during
the wet season and 82.9% inhibition during the dry season). This high toxicity is attributed to the higher than usual concentrations
of Cu (189 μg Cu l−1) and Zn (1505 μg Zn l−1). These results show the potential risk of the contamination of different ecosystems situated to the vicinity of these two
metalliferous sites. The general trend observed was an increase in metal toxicity measured by the MetPLATE with increasing
total and mobile metal concentrations in the studied matrices. Therefore, the MetPLATE bioassay is a reliable and fast bioassay
to estimate the metals toxicity in the aquatic and solids samples. 相似文献
54.
The main objectives of article were monitor the metal concentrations of cadmium, lead, copper, zinc, cobalt, and iron, in the feather of shorebirds species, Western Reef Heron (Egretta gularis) and Siberian Gull (Larus heuglini) from Hara Biosphere Reserve of Southern Iran; and identify any relationships between species. Assaying heavy metals by using Shimadzu AA 680 flame atomic absorption spectrophotometer, the results were given as micrograms per gram dry weight. The concentrations of heavy metal were found to follow the order of iron>zinc>copper>lead>cadmium>cobalt for E. gularis and of iron>zinc>lead>copper>cadmium>cobalt for L. heuglini. Also, they showed that the cadmium, copper, and cobalt concentrations were higher in females than in the males, while the lead concentration for E. gularis and L. heuglini was higher in males. The cadmium concentration means they were measured as1.16 and 1.37 μg/g for E. gularis and L. heuglini, respectively, whereas the lead concentration means 7.04 and 5.48 μg/g for E. gularis and L. heuglini, respectively. The concentrations of nonessential trace elements in E. gularis and L. heuglini were generally comparable to values reported in other studies. The average levels of lead we observed in these birds were greater than 5 μg/g dry weight in the feather that is known to be associated with adverse behavioral or reproductive effects. Data analysis showed that there was a positive correlation between copper and zinc (P?0.01), copper and cobalt (P?0.05). 相似文献
55.
Ahmed El Nemr Abeer A. Moneer Azza Khaled Amany El-Sikaily 《Environmental monitoring and assessment》2013,185(6):4835-4853
The analyses of environmentally persistent pollutants like polychlorinated biphenyls (PCBs), hexachlorocyclohexane (HCH) isomers, and dichlorodiphenyltrichloroethane (DDT) and its metabolites in surficial sediment samples collected from 17 locations along with the coast of the Red Sea in Egypt were carried out using gas chromatography–mass spectrometry. Several potential organic contaminants from agricultural (e.g., DDT and its breakdown products, lindane, endrin, dieldrin, and endosulfan) and industrial (PCBs) sources were measured. The levels of 20 organochlorine pesticides (OCPs) and ten PCB congeners in sediment collected from 17 stations along ~1,200 km were investigated. Concentrations of PCBs, HCHs, DDTs, and cyclodienes ranged from 0.40 to 6.17, 0.01 to 0.09, n.d. to 0.46, and 0.08 to 0.90 ppb dry weight. Two statistical programs were applied on the data (principal component analysis, PCA, and cluster analysis, CA), and it was concluded that it is impossible to predict the distribution patterns of the OCPs in a contaminated area. Risk assessment of the organochlorines contaminated in the sediments of the studied area was investigated. 相似文献
56.
Francesco Riccioli Toufic El Asmar Jean-Pierre El Asmar Roberto Fratini 《Environmental monitoring and assessment》2013,185(7):5361-5374
The study of changes in land use has been included lately in territorial processes in order to optimize future management decisions. The different functions that the territory plays (production, aesthetic, and natural functions, etc.) make planning choices more difficult. This work focuses on the selection and combination of a set of indicators to analyze the variables through which the changes occur in the land used in viticulture for wine production. The proposed approach makes use of the Geographic Information System (GIS) in the development of a map of land use scenario. It is applied to a case study through a model involving cellular automata (CA) implemented with maps of suitability for viticulture and Markov chains. The use in this case of the CA is aimed at validating the scenario map in order to deduce the variables and the orientations of the farmers in the field of wine production. 相似文献
57.
Mohammed F. M. Abushammala Noor Ezlin Ahmad Basri Rahmah Elfithri 《Environmental monitoring and assessment》2013,185(12):9967-9978
Methane (CH4) emissions and oxidation were measured at the Air Hitam sanitary landfill in Malaysia and were modeled using the Intergovernmental Panel on Climate Change waste model to estimate the CH4 generation rate constant, k. The emissions were measured at several locations using a fabricated static flux chamber. A combination of gas concentrations in soil profiles and surface CH4 and carbon dioxide (CO2) emissions at four monitoring locations were used to estimate the CH4 oxidation capacity. The temporal variations in CH4 and CO2 emissions were also investigated in this study. Geospatial means using point kriging and inverse distance weight (IDW), as well as arithmetic and geometric means, were used to estimate total CH4 emissions. The point kriging, IDW, and arithmetic means were almost identical and were two times higher than the geometric mean. The CH4 emission geospatial means estimated using the kriging and IDW methods were 30.81 and 30.49 g m?2 day?1, respectively. The total CH4 emissions from the studied area were 53.8 kg day?1. The mean of the CH4 oxidation capacity was 27.5 %. The estimated value of k is 0.138 year?1. Special consideration must be given to the CH4 oxidation in the wet tropical climate for enhancing CH4 emission reduction. 相似文献
58.
59.
Using Multi-Scale Sampling and Spatial Cross-Correlation to Investigate Patterns of Plant Species Richness 总被引:8,自引:0,他引:8
Land managers need better techniques to assess exoticplant invasions. We used the cross-correlationstatistic, I
YZ, to test for the presence ofspatial cross-correlation between pair-wisecombinations of soil characteristics, topographicvariables, plant species richness, and cover ofvascular plants in a 754 ha study site in RockyMountain National Park, Colorado, U.S.A. Using 25 largeplots (1000 m2) in five vegetation types, 8 of 12variables showed significant spatial cross-correlationwith at least one other variable, while 6 of 12variables showed significant spatial auto-correlation. Elevation and slope showed significant spatialcross-correlation with all variables except percentcover of native and exotic species. Percent cover ofnative species had significant spatialcross-correlations with soil variables, but not withexotic species. This was probably because of thepatchy distributions of vegetation types in the studyarea. At a finer resolution, using data from ten1 m2 subplots within each of the 1000 m2 plots, allvariables showed significant spatial auto- andcross-correlation. Large-plot sampling was moreaffected by topographic factors than speciesdistribution patterns, while with finer resolutionsampling, the opposite was true. However, thestatistically and biologically significant spatialcorrelation of native and exotic species could only bedetected with finer resolution sampling. We foundexotic plant species invading areas with high nativeplant richness and cover, and in fertile soils high innitrogen, silt, and clay. Spatial auto- andcross-correlation statistics, along with theintegration of remotely sensed data and geographicinformation systems, are powerful new tools forevaluating the patterns and distribution of native andexotic plant species in relation to landscape structure. 相似文献
60.
Şebnem Elçi Ramazan Aydın Paul A. Work 《Environmental monitoring and assessment》2009,159(1-4):255-265
Acoustic Doppler current meters (ADV, ADCP, and ADP) are widely used in water systems to measure flow velocities and velocity profiles. Although these meters are designed for flow velocity measurements, they can also provide information defining the quantity of particulate matter in the water, after appropriate calibration. When an acoustic instrument is calibrated for a water system, no additional sensor is needed to measure suspended sediment concentration (SSC). This provides the simultaneous measurements of velocity and concentration required for most sediment transport studies. The performance of acoustic Doppler current meters for measuring SSC was investigated in different studies where signal-to-noise ratio (SNR) and suspended sediment concentration were related using different formulations. However, these studies were each limited to a single study site where neither the effect of particle size nor the effect of temperature was investigated. In this study, different parameters that affect the performance of an ADV for the prediction of SSC are investigated. In order to investigate the reliability of an ADV for SSC measurements in different environments, flow and SSC measurements were made in different streams located in the Aegean region of Turkey having different soil types. Soil samples were collected from all measuring stations and particle size analysis was conducted by mechanical means. Multivariate analysis was utilized to investigate the effect of soil type and water temperature on the measurements. Statistical analysis indicates that SNR readings ob tained from the ADV are affected by water temperature and particle size distribution of the soil, as expected, and a prediction model is presented relating SNR readings to SSC mea surements where both water temperature and sediment characteristics type are incorporated into the model. The coefficients of the suggested model were obtained using the multivariate anal ysis. Effect of high turbidity conditions on ADV performance was also investigated during and after rain events. 相似文献