The relative importance of factors influencing the adoption of sustainable agricultural practices: a factor approach for Malaysian vegetable farmers

This study develops the understanding of the adoption of sustainable agricultural practices (SAPs) by investigating the relative importance of a set of multidimensional factors in the Malaysian vegetable production sector. A factor approach is deployed to identify explanatory indicators within an integrative framework that is synthesized from the theory of interpersonal behavior and the theory of diffusion of innovation. We achieved this by analyzing a logistic regression model for the adoption of six individual SAPs (conservation tillage, intercropping, cover crops/mulches, crop rotation, organic fertilizers/composts, and integrated pest management). The findings indicate that adoption depends on a range of socio-economic, agro-ecological, institutional, informational, and psychological factors, as well as the perceived attributes of SAPs. Fundamental policy understanding of the issue should, therefore, be multidisciplinary. In addition, standardized coefficients reveal that the impact of statistically significant factors on adoption is unequal. In general, the most influential factor is the asymmetric distribution of resources across geographical locations. This is followed by financial capital and a number of factors, including the workforce size, the usefulness of information, Chinese ethnicity, and the perceived relative advantage of SAPs. Guided by this prioritization understanding, future SAPs promotion now has a better opportunity to target the more important areas. Similar research effort should be made to steer sustainable agriculture internationally.     

Enhancing Performance of Sphingobacterium spiritivorum in Bioremediation Phenanthrene Contaminated Sand

Many biodegradation studies have focused on survival of isolated bacteria to increase the bacteria population and subsequently enhance the efficiency of polycyclic aromatic hydrocarbon (PAH) biodegradation. However, there is limited research on enhancing the performance of isolated bacteria through reinoculation. Thus, this study was designed to evaluate the effects of reinoculation on the performance of Sphingobacterium spiritivorum in degradation of phenanthrene contaminated sand. Experiments were performed in three different reactors. Inoculation was performed once (day 0) in reactor 1. In reactor 2, inoculation was performed twice (day 0 and day 5). The bacteria was isolated from reactor 2 and inoculated into reactor 3. The study results show reactor 3 having the highest degradation rate (13.61 mg/kg/day) and percentage removal (95.36 percent). In contrast, without reinoculation in reactor 1, 68.93 percent of phenanthrene was removed. Thus, the performance of S. spiritivorum in phenanthrene degradation can be enhanced through reinoculation. © 2014 Wiley Periodicals, Inc.     

Pesticide risk assessment: A study on inhalation and dermal exposure to 2,4-D and paraquat among Malaysian paddy farmers

A cross-section analytical study was conducted to evaluate the risk of pesticide exposure to those applying the Class II pesticides 2,4-D and paraquat in the paddy-growing areas of Kerian, Perak, Malaysia. It investigated the influence of weather on exposure as well as documented health problems commonly related to pesticide exposure. Potential inhalation and dermal exposure for 140 paddy farmers (handlers of pesticides) were assessed. Results showed that while temperature and humidity affected exposure, windspeed had the strongest impact on pesticide exposure via inhalation. However, the degree of exposure to both herbicides via inhalation was below the permissible exposure limits set by United States National Institute of Occupational Safety and Health (NIOSH). Dermal Exposure Assessment Method (DREAM) readings showed that dermal exposure with manual spraying ranged from moderate to high. With motorized sprayers, however, the level of dermal exposure ranged from low to moderate. Dermal exposure was significantly negatively correlated with the usage of protective clothing. Various types of deleterious health effects were detected among users of manual knapsack sprayers. Long-term spraying activities were positively correlated with increasing levels of the gamma-glutamyl transpeptidase (GGT) liver enzyme. The type of spraying equipment, usage of proper protective clothing and adherence to correct spraying practices were found to be the most important factors influencing the degree of pesticide exposure among those applying pesticides.     

Monitoring and identification of airborne asbestos in unorganized sectors, India

Rajasthan state in India is credited to cater more than 90% of total production of asbestos in this country, of which around 60% is processed there in unorganized sectors including milling and manufacturing of asbestos-based products. Unorganized asbestos units particularly mills showed unhealthy occupational conditions, therefore industrial hygiene study was carried out focusing on the prevalence of asbestos fibres in air at work zone area of asbestos milling units. Fibre levels were in the range of 2.00-5.09f/cm(3) and 4.07-15.60f/cm(3) in unorganized asbestos mills of Rajasthan located at Beawer and Deogarh districts, respectively. Like asbestos concentration, fibre type and length are also vital factors in the health risk assessment of industrial workers. Phase contrast and polarized light microscopic study of asbestos fibres showed their amphibole nature registering about 90% as tremolite and rest as anthophyllite. Fibre length measured micrometrically were sub-grouped in <10microm, 11-20microm, 21-30microm and >30microm. About 30-40% fibres belonged to sub-group <10microm. It is concluded that unorganized asbestos mills bear poor industrial unhygienic conditions reflected specifically from their manyfold higher fibre concentrations than the Indian and International standards. Poor industrial unhygienic conditions are attributable to obsolete milling technology, lack of pollution control devices and escape from regulatory control.     

Source Apportionment of Particulate Matter (PM10) and Indoor Dust in a University Building

A study on source apportionment of indoor dust and particulate matter (PM₁₀) composition was conducted in a university building by using chemometrics. The objective of this study was to investigate the potential sources of selected heavy metals and ionic species in PM₁₀ and indoor dust. PM₁₀ samples were collected using a low-volume sampler (LVS) and indoor dust was collected using a soft brush. Inductively coupled plasma spectrometry (ICP-MS) was used to determine the concentration of heavy metals, while the concentration of cations and anions was determined by atomic absorption spectrometer (AAS) and ion chromatography (IC), respectively. The concentration of PM₁₀ recorded in the building throughout the sampling period ranged from 20 ± 10 μgm^?3 to 80 ± 33 μgm^?3. The composition of heavy metals in PM₁₀ and indoor dust were dominated by zinc (Zn), followed by lead (Pb), copper (Cu), and cadmium (Cd). Principle component analysis (PCA) and multiple linear regression (MLR) showed that the main sources of pollutants in PM₁₀ came from indoor renovations (73.83%), vehicle emissions (16.38%), earth crust sources (9.68%), and other outdoor sources (0.11%). For indoor dust, the pollutant source was mainly earth crust. This study suggests that chemometrics can be used for forensic investigation to determine the possible sources of indoor contaminants within a public building.     

Examining the effectiveness of low-carbon strategies in South Asian countries: the case of energy efficiency and renewable energy

Environment, Development and Sustainability - This paper examines the impact of energy efficiency (EE) and renewable energy (RE) on carbon emissions, using a panel data of South Asian countries...     

Using process stream index (PSI) to assess inherent safety level during preliminary design stage

In the current practice, safety assessment is conducted once the process design has been completed. At this stage of design, the freedom to change the conceptual design is very limited and whatever strategies to be implemented will only control the hazard. This paper reports on the development of inherent safety index known as a process stream index (PSI) for inherent safety level assessment at preliminary design stage from the perspective of an explosion. The aim for PSI is to calculate, compare and prioritize the level of inherent safety of process streams during simulation work that influences the explosion. By prioritizing the streams based on the potential for the explosion, the design engineers can easily identify the critical streams to be considered for improvement in order to avoid or minimize explosion hazards. An enhancement technique to reflect the contribution of the individual components in the mixture is introduced, which provide significant contribution to the ranking of inherent safety level of process streams. The assessment of inherent safety level using PSI is demonstrated by case studies of HYSYS simulation for Acrylic Acid Plant and Natural Gas Liquid (NGL) plant.     

Psychosocial safety climate: Conceptual distinctiveness and effect on job demands and worker psychological health

Psychosocial safety climate is an emerging construct that refers to shared perceptions regarding policies, practices, and procedures for the protection of worker psychological health and safety. The purpose of the research was to: (1) demonstrate that psychosocial safety climate is a construct distinct from related climate measures (i.e., physical safety climate, team psychological safety, and perceived organizational support); and (2) test the proposition that organizational psychosocial safety climate determines work conditions (i.e., job demands) and subsequently worker psychological health. We used samples from two different cultures; an Australian sample (N = 126 workers in 16 teams within a primary health care organization) and a Malaysian sample (N = 180 workers in 31 teams from different organizations and diverse industries). In both samples confirmatory factor analysis verified that psychosocial safety climate is a construct distinct from related climate measures. Using hierarchical linear modeling, psychosocial safety climate was superior to other team level climate measures in its negative relationship to both job demands and psychological health problems. Results supported a mediation process, psychosocial safety climate → job demands → psychological health problems, corroborating psychosocial safety climate as a preeminent stress risk factor, and an efficient target for intervention. We found both physical and psychosocial safety climates were stronger in the Australian, compared with the Malaysian work context. Levels of psychosocial safety climate were significantly lower than those of physical safety climate in both countries indicating a ‘universal’ lack of attention to workplace psychological health.     

At-risk behaviour analysis and improvement study in an academic laboratory

Academic laboratories contain inherently substantial risk conditions that students could expose to chemical and physical hazards. Procedures and guidelines related to laboratory safety are commonly available for students to adhere. However, many injuries and accidents or even fatalities are reported due to students’ violated safety practices while working in the laboratory. There was no reported proactive method or systematic technique to monitor and control students’ at-risk behaviour in the laboratory. This paper presented a program known as laboratory at-risk behaviour and improvement system (Lab-ARBAIS) to monitor and control students’ at-risk behaviours in the laboratory. Lab-ARBAIS used computer database for data acquisition and analysis on students’ at-risk behaviours observed. Pre-program questions on students’ at-risk behaviours that frequently violated safety regulations were utilized by observers to give observation feedback. The collected feedback was analysed and the results were posted in students’ portal to allow everyone to acknowledge their safety habits and practices. The routine observations and posted results are to instill a psychology effect in student’s habitual safety practices by reminding them on their frequently violated safety regulations. The implementation of the Lab-ARBAIS program to chemical engineering laboratory as a case study had shown a significant improvement on students’ frequent at-risk behaviours. The Lab-ARBAIS can easily be adopted in any academic laboratories to manage students’ at-risk behaviours to ensure safe work environment. With minor enhancement, the Lab-ARBAIS can easily be extended to be used in industrial laboratories.     

Dry reforming of methane over oil palm shell activated carbon and ZSM-5 supported cobalt catalysts

In this study, cobalt supported oil palm shell activated carbon (Co/OPS-AC) and ZSM-5 zeolite (Co/ZSM-5) catalysts have been prepared for dry reforming of methane. Cobalt ratios of 6.0 and 14.0 wt% were deposited via wet impregnation method to the OPS-AC and ZSM-5 catalysts. The catalysts were characterized by XRD, N₂ adsorption--desorption isotherms, BET surface area, SEM, FESEM-EDX, TPR-H₂, and TPD-NH₃. The dry reforming of methane was performed using a micro reactor system under the condition of 10,000 ml/h.g-cat, 3 atm, CH₄/CO₂ ratio of 1.2:1.0 and temperature range from 923 K to 1023 K. The gaseous products were analyzed by gas chromatography (GC) with thermal conductivity detector (TCD) and further quantified to determine the conversions of CH₄ and CO₂, and the yields of CO and H₂. Experimental results revealed both catalysts exhibited lower conversions of CO₂ and CH₄ with the increase in temperature from 923 K to 1023 K. The reduced conversions may be due to the formation of carboneous substance on the catalyst known as coking. Comparatively, Co/OPS-AC gave higher conversions of CO₂ and CH₄ as well as higher yields of H₂ and CO as it has a higher surface area than Co/ZSM-5 which subsequently rendered higher activity for the reforming of methane. With the increasing cobalt loadings and reaction temperature, OPS-AC(14) catalyst exhibited improved activity and H₂/CO ratio. Based on these results, cobalt supported OPS activated carbon catalyst was suggested to be more effective for CO₂ and CH₄ conversions.