Thermal conductivity characteristics of dewatered sewage sludge by thermal hydrolysis reaction

The purpose of this study is to quantify the thermal conductivity of sewage sludge related to reaction temperature for the optimal design of a thermal hydrolysis reactor. We continuously quantified the thermal conductivity of dewatered sludge related to the reaction temperature. As the reaction temperature increased, the dewatered sludge is thermally liquefied under high temperature and pressure by the thermal hydrolysis reaction. Therefore, the bound water in the sludge cells comes out as free water, which changes the dewatered sludge from a solid phase to slurry in a liquid phase. As a result, the thermal conductivity of the sludge was more than 2.64 times lower than that of the water at 20℃. However, above 200℃, it became 0.704 W/m?°C, which is about 4% higher than that of water. As a result, the change in physical properties due to thermal hydrolysis appears to be an important factor for heat transfer efficiency.

ImplicationsThe thermal conductivity of dewatered sludge is an important factor the optimal design of a thermal hydrolysis reactor. The dewatered sludge is thermally liquefied under high temperature and pressure by the thermal hydrolysis reaction. The liquid phase slurry has a higher thermal conductivity than pure water.     

Ozone uptake by citrus trees exposed to a range of ozone concentrations

The Citrus genus includes a large number of species and varieties widely cultivated in the Central Valley of California and in many other countries having similar Mediterranean climates. In the summer, orchards in California experience high levels of tropospheric ozone, formed by reactions of volatile organic compounds (VOC) with oxides of nitrogen (NO_x). Citrus trees may improve air quality in the orchard environment by taking up ozone through stomatal and non-stomatal mechanisms, but they may ultimately be detrimental to regional air quality by emitting biogenic VOC (BVOC) that oxidize to form ozone and secondary organic aerosol downwind of the site of emission. BVOC also play a key role in removing ozone through gas-phase chemical reactions in the intercellular spaces of the leaves and in ambient air outside the plants. Ozone is known to oxidize leaf tissues after entering stomata, resulting in decreased carbon assimilation and crop yield. To characterize ozone deposition and BVOC emissions for lemon (Citrus limon), mandarin (Citrus reticulata), and orange (Citrus sinensis), we designed branch enclosures that allowed direct measurement of fluxes under different physiological conditions in a controlled greenhouse environment. Average ozone uptake was up to 11 nmol s^?1 m^?2 of leaf. At low concentrations of ozone (40 ppb), measured ozone deposition was higher than expected ozone deposition modeled on the basis of stomatal aperture and ozone concentration. Our results were in better agreement with modeled values when we included non-stomatal ozone loss by reaction with gas-phase BVOC emitted from the citrus plants. At high ozone concentrations (160 ppb), the measured ozone deposition was lower than modeled, and we speculate that this indicates ozone accumulation in the leaf mesophyll.     

Effect of mixing ratio of woody waste and food waste on the characteristics of carbonization residue

Biomass such as woody waste and food waste can be converted to a renewable energy source by means of carbonization processes. The basic characteristics of woody waste and food waste, such as proximate analysis and heating value, were evaluated before carrying out carbonization tests. Carbonization tests were carried out to obtain the basic characteristics of carbonization residue on changing the proportion of food waste from 0% to 30% in the mixture of woody waste and food waste. The effect of the food waste was estimated by basic characteristics of the residue such as the heating value, yield, and fuel ratio. As increased the food waste content, the bulk density, yield and chlorine content of the carbonization residue increased, but fuel ratio, the carbon content and heating value of the residue decreased. From the results of the basic characteristics of the residue, the optimum food waste content in carbonization tests was found to be 20%. Even if food waste is combined with woody waste at levels up to 30%, the sulfur and chlorine concentrations in the residue were much lower than the regulatory standard levels. From the results for the fuel ratio and heating value of the residue, the carbonization residue is suitable for use as a renewable energy source and can be categorized by the second grade level of solid fuel products.     

Microalgae growth using high-strength wastewater followed by anaerobic co-digestion

Integration of algal biofuel production to wastewater anaerobic digestion infrastructure has the potential to increase biogas production, decrease high and variable internal nitrogen loads, and improve sludge digestibility and dewaterability. In this research, two species of microalgae, Spirulina platensis and Chlorella sp., were grown on sludge centrate and a centrate and nitrified wastewater effluent mixture. Harvested algae were co-digested with waste activated sludge (WAS) at varying ratios. High-growth (6.8 g m(-2) x d(-1)), nitrogen (36.5 g m(-3) x d(-1)), and phosphorus (6.5 g m(-3) x d(-1)) uptake rates were achieved with Chlorella on centrate. No growth was observed with S. platensis under the same conditions; however, both organisms grew well on the centrate and effluent mixture. Co-digestion of algae with WAS improved volatile solids reduction. Although co-digestion with S. platensis improved biosolids dewaterability, Chlorella had a slight negative effect on dewaterability compared to WAS alone. The efficiency of energy conversion from photons to biogas generated from Chlorella was estimated at 1.4%.     

Toluene vapor capture by activated carbon particles in a dual gas-solid cyclone system

Capturing of odorous compounds such as toluene vapor by a particulate-activated carbon adsorbent was investigated in a gas-solid cyclone, which is one type of mobile beds. The test cyclone was early modified with the post cyclone (PoC) and a spiral flow guide to the vortex finder. The proposed process may contribute to the reduction of gases and dust from industrial exhausts, especially when dealing with a low concentration of odorous elements and a large volume ofdust flow. In this device, the toluene capturing efficiency at a 400 ppm concentration rose up to 77.4% when using activated carbon (AC) particles with a median size of 27.03 microm. A maximum 96% of AC particles could be collected for reuse depending on the size and flow rate. The AC regenerated via thermal treatment showed an adsorption potential up to 66.7% throughout repeated tests.     

Assaying organochlorines in archived serum for a large, long-term cohort: implications of combining assay results from multiple laboratories over time

Conserving irreplaceable, archived serum samples may sometimes conflict with the objective of minimizing measurement error due to laboratory effects. We sought to determine whether we could successfully combine assay results for DDT-related compounds and polychlorinated biphenyls (PCBs) in serum from the same birth cohort obtained from different laboratories over time. Using the Child Health and Development Studies (CHDS) serum archive, we compared variability for assays of a quality control pool to variability for assays of subject serum. The quality control pool was created from native archived serum samples that were pooled, then aliquoted, blinded and inserted pair-wise into assay batches along with the subject serum for 5 studies using CHDS samples conducted over a 13year period by three different laboratories. We found that the variability between laboratory and over time within laboratory was small relative to inter-individual variability for p,p'-DDT (1,1,1-trichloro-2,2-bis(p-chlorophenyl)ethane), p,p'-DDE (1,1'-dichloro-2,2'-bis(p-chlorophenyl)ethylene) and o,p'-DDT (1,1,1-trichloro-2-(p-chlorophenyl)-2-(o-chlorophenyl)-ethane). Results were also consistent for most PCB congeners which were detectable in 85% or more of samples. Our results suggest that it is possible to combine assays for DDT and PCB congeners measured at positive levels as they are accumulated for cohort subjects without risking meaningful misclassification due to variation stemming from laboratory or time period. This has significant implications for future study costs, conservation of irreplaceable archived samples and for leveraging past investments for future research. For PCB congeners with very low levels, findings caution against pooling of assays without further exploration.     

Assessment of wood pellet combustion in a domestic stove

Wood pellet is a densified fuel with homogeneous physical properties suitable for use at various scales in domestic and industrial furnaces. A wood pellet stove is a small-scale furnace for domestic heat production that can replace conventional oil or gas boilers. Since the fuel properties of wood pellet are very different from those of oil or gas, the design of a wood pellet stove requires profound understanding of solid fuel combustion as well as of gas flow mixing and reactions. Due to limitations on the height of an installed furnace (~1 m), poor design of the furnace, air supply, fume extraction, or the heat exchanger may lead to excessive CO emissions or low energy efficiency. This study evaluated the design of an existing wood pellet stove with 30,000 kcal/h capacity, using experimental and computational techniques in order to optimize the furnace design. The results show that it is critical to minimize unused furnace volume and to enhance gaseous mixing for reduced CO emissions while maintaining sufficiently high temperatures for fast oxidation.     

Selective catalytic reduction of NO<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript> using RDF char and municipal solid waste char based catalyst

Experiments were performed in order to investigate the possibility for the development of catalysts for low-temperature selective catalytic reduction (SCR) using municipal waste char and RDF byproduct. Physical and chemical activations, using water, and HCl and KOH, were employed to increase the catalytic activities. The characteristics of the activated catalysts were investigated using N₂ adsorption–desorption and FT-IR. The catalysts activated chemically using basic treatment showed higher NO _x removal efficiencies than those activated physically or chemically using acidic treatment. The de-NO _x performance of the activated catalysts was dependent on the chemical properties, such as oxygen functional groups as well as physical properties, such as specific surface area and pore volume. In order to investigate the effect of MnO _x , which has been reported to be efficient for the removal of NO _x in low-temperature SCR processes, the chemically activated catalyst was impregnated with manganese. The Mn-impregnated catalyst had the highest NO _x conversion at all of the temperatures tested in this study.     

Environmental risk assessment of genetically engineered herbicide-tolerant Zoysia japonica

Herbicide-tolerant Zoysia grass (Zoysia japonica Steud.) has been generated previously through Agrobacterium tumefaciens-mediated transformation. The genetically modified (GM) Zoysia grass survived Basta spraying and grew to maturity normally while the wild-type (WT) grass stopped growing and died. GM Zoysia grass will permit more efficient weed control for various turf grass plantings such as home lawns, golf courses, and parks. We examined the environmental/biodiversity risks of herbicide-tolerant GM Zoysia before applying to regulatory agencies for approval for commercial release. The GM and WT Zoysia grass' substantial trait equivalence, ability to cross-pollinate, and gene flow in confined and unconfined test fields were selectively analyzed for environmental/biodiversity effects. No difference between GM and WT Zoysia grass in substantial traits was found. To assess the potential for cross-pollination and gene flow, a non-selective herbicide, Basta, was used. Results showed that unintended cross-pollination with and gene flow from GM Zoysia grass were not detected in neighboring weed species examined, but were observed in WT Zoysia grass (on average, 6% at proximity, 1.2% at a distance of 0.5 m and 0.12% at a radius of 3 m, and 0% at distances over 3 m). On the basis of these initial studies, we conclude that the GM Zoysia grass generated in our laboratory and tested in the Nam Jeju County field does not appear to pose a significant risk when cultivated outside of test fields.     

Sensitivity of the solution of the Elder problem to density, velocity and numerical perturbations

In this paper the Elder problem is studied with the purpose of evaluating the inherent instabilities associated with the numerical solution of this problem. Our focus is first on the question of the existence of a unique numerical solution for this problem, and second on the grid density and fluid density requirements necessary for a unique numerical solution. In particular we have investigated the instability issues associated with the numerical solution of the Elder problem from the following perspectives: (i) physical instability issues associated with density differences; (ii) sensitivity of the numerical solution to idealization irregularities; and, (iii) the importance of a precise velocity field calculation and the association of this process with the grid density levels that is necessary to solve the Elder problem accurately. In the study discussed here we have used a finite element Galerkin model we have developed for solving density-dependent flow and transport problems, which will be identified as TechFlow. In our study, the numerical results of Frolkovic and de Schepper [Frolkovic, P. and H. de Schepper, 2001. Numerical modeling of convection dominated transport coupled with density-driven flow in porous media, Adv. Water Resour., 24, 63-72.] were replicated using the grid density employed in their work. We were also successful in duplicating the same result with a less dense grid but with more computational effort based on a global velocity estimation process we have adopted. Our results indicate that the global velocity estimation approach recommended by Yeh [Yeh, G.-T., 1981. On the computation of Darcian velocity and mass balance in finite element modelling of groundwater flow, Water Resour. Res., 17(5), 1529-1534.] allows the use of less dense grids while obtaining the same accuracy that can be achieved with denser grids. We have also observed that the regularity of the elements in the discretization of the solution domain does make a difference in obtaining a unique stationary solution for this problem. The results of our study also indicate that the density differences are critical in the solution of the Elder problem and that high density differences lead to the physical instability that is inherent with this problem. Other than the physical instability associated with the level of density differences used in the Elder problem, the following two points should be considered in solving the Elder problem in a consistent manner: (i) strict attention should be paid to the vertical grid Peclet number in developing the criteria for convergent grid selection; and, (ii) with a globally continuous velocity calculation stable solutions can be obtained at lower grid densities.