Demand of the tourists visiting protected areas in small oceanic islands: the Azores case-study (Portugal)

In general, tourism plays a significant role in the economy of archipelagos and islands. The Autonomous Region of the Azores has a great potential for tourism, offering multiple attractions, both natural and cultural, creating a big challenge for a sustainable tourism policy since little attention has been paid to the archipelagos and their special needs. This work aims to understand the profile and type of ecotourist that visits the Azores. This knowledge is of great importance for a better management and development of nature-based tourism, and products tailored to the needs and expectations of visitors. The data were collected by means of exit surveys conducted at the Airport of São Miguel Island, the larger and most populated island of the archipelago, during the high tourist season—July–September 2009. The analysis of the visitor’s profile and preferences is crucial to draw adequate strategies of management for tourism, while it helps to adequate the offer to the demand. Results showed that 41.1 % of the tourists claimed to be attracted to the islands due to their “natural values” (e.g., landscape, biodiversity, and geodiversity). The most practiced activities were whale-watching (32.4 %) and mountaineering/hiking (31.6 %), followed by diving (7 %) and other sports (5.1 %). The tourists’ profile points to a mainstream, soft, and incidental type of ecotourist. This information helps to develop and support a strategic planning and management, both at local and regional levels, for sustainable tourism policies.     

“Modern agriculture” transfers many pesticides to watercourses: a case study of a representative rural catchment of southern Brazil

Environmental Science and Pollution Research - The total cultivated area in Brazil reached to 62 million ha in 2018, with the predominance of genetically modified soybean and corn (36 and 17...     

Evidence of reproductive disturbance in Astyanax lacustris (Teleostei: Characiformes) from the Doce River after the collapse of the Fundão Dam in Mariana,Brazil

Environmental Science and Pollution Research - The Fundão Dam collapsed, on November 5th, 2015, dumping more than 50 million/m3 of iron ore tailings, enriched with metals, into the Doce River...     

Inflammation biomarkers associated with arsenic exposure by drinking water and respiratory outcomes in indigenous children from three Yaqui villages in southern Sonora,México

Environmental Science and Pollution Research - Environmental arsenic exposure in adults and children has been associated with a reduction in the expression of club cell secretory protein (CC16) and...     

Glyphosate concentrations in global freshwaters: are aquatic organisms at risk?

Environmental Science and Pollution Research - Glyphosate is the most used herbicide worldwide. Many studies have reported glyphosate risks to aquatic organisms of different trophic levels....     

Solar heterogeneous photocatalytic degradation of phenol on TiO2/quartz and TiO2/calcite: a statistical and kinetic approach on comparative efficiencies towards a TiO2/glass system

Environmental Science and Pollution Research - Phenol is a widely used synthetic organic compound, which according to global estimations, is discharged into the environment at a rate of 10...     

Photocatalysis for arsenic removal from water: considerations for solar photocatalytic reactors

Environmental Science and Pollution Research - The following work provides a perspective on the potential application of solar heterogeneous photocatalysis, which is a nonselective advanced...     

Electrochemical monitoring of methylparathion degradation in an acid aqueous medium in presence of Cu(II)

A study was undertaken to determine the effect of Cu(II) in degradation of methylparathion (o,o-dimethyl o,4-nitrophenyl phosphoriotioate) in acid medium. Initial electrochemical characterization of Cu(II) and methylparathion was done in an aqueous medium at a pH range of 2-7. Cu(II) was studied in the presence of different anions and it was observed that its electroactivity depends on pH and is independent of the anion used. Methylparathion had two reduction signals at pH < or = 6 and only one at pH > 6. The pesticide's transformation kinetic was then studied in the presence of Cu(II) in acid buffered aqueous medium at pH values of 2, 4, and 7. Paranitrophenol appeared as the only electroactive product at all three pH values. The reaction was first order and had k values of 5.2 x 10(-3) s(-1) at pH 2, 5.5 x 10(-3) s(-1) at pH 4 and 9.0 x 10(-3) s(-1) at pH 7. It is concluded that the principal degradation pathway of methylparathion in acid medium is a Cu(II) catalyzed hydrolysis reaction.     

Evaluation of relative photonic efficiency in heterogeneous photocatalytic reactors

The evaluation of photonic efficiency in heterogeneous photocatalysis remains elusive because the number of absorbed photons is difficult to assess experimentally. The photonic efficiency of heterogeneous photocatalytic reactors depends on the reactor geometry, irradiation source, and photocatalyst properties. In this work, the relative photonic efficiency of heterogeneous photocatalytic reactors to degrade an azo dye was evaluated using phenol as the standard system. The experimental tests were carried out in a batch reactor under different conditions of pH, catalyst dosage, initial concentration, and ultraviolet (UV) lamps. The kinetics of disappearance of both phenol and azo dye were studied using the initial rate method and were described according to the Langmuir-Hinshelwood (L-H) kinetic model. It was observed that the relative photonic efficiency depends on the adsorption/desorption properties of the photocatalyst.     

DOC removal paradigms in highly humic aquatic ecosystems

Background, aim, and scope  Dissolved humic substances (HS) usually comprise 50–80% of the dissolved organic carbon (DOC) in aquatic ecosystems. From a trophic and biogeochemical perspective, HS has been considered to be highly refractory and is supposed to accumulate in the water. The upsurge of the microbial loop paradigm and the studies on HS photo-degradation into labile DOC gave rise to the belief that microbial processing of DOC should sustain aquatic food webs in humic waters. However, this has not been extensively supported by the literature, since most HS and their photo-products are often oxidized by microbes through respiration in most nutrient-poor humic waters. Here, we review basic concepts, classical studies, and recent data on bacterial and photo-degradation of DOC, comparing the rates of these processes in highly humic ecosystems and other aquatic ecosystems. Materials and methods  We based our review on classical and recent findings from the fields of biogeochemistry and microbial ecology, highlighting some odd results from highly humic Brazilian tropical lagoons, which can reach up to 160 mg C L⁻¹. Results and discussion  Highly humic tropical lagoons showed proportionally lower bacterial production rates and higher bacterial respiration rates (i.e., lower bacterial growth efficiency) than other lakes. Zooplankton showed similar δ¹³C to microalgae but not to humic DOC in these highly humic lagoons. Thus, the data reviewed here do not support the microbial loop as an efficient matter transfer pathway in highly humic ecosystems, where it is supposed to play its major role. In addition, we found that some tropical humic ecosystems presented the highest potential DOC photo-chemical mineralization (PM) rates reported in the literature, exceeding up to threefold the rates reported for temperate humic ecosystems. We propose that these atypically high PM rates are the result of a joint effect of the seasonal dynamics of allochthonous humic DOC input to these ecosystems and the high sunlight incidence throughout the year. The sunlight action on DOC is positive to microbial consumption in these highly humic lagoons, but little support is given to the enhancement of bacterial growth efficiency, since the labile photo-chemical products are mostly respired by microbes in the nutrient-poor humic waters. Conclusions  HS may be an important source of energy for aquatic bacteria in humic waters, but it is probably not as important as a substrate to bacterial growth and to aquatic food webs, since HS consumption is mostly channeled through microbial respiration. This especially seems to be the case of humic-rich, nutrient-poor ecosystems, where the microbial loop was supposed to play its major role. Highly humic ecosystems also present the highest PM rates reported in the literature. Finally, light and bacteria can cooperate in order to enhance total carbon degradation in highly humic aquatic ecosystems but with limited effects on aquatic food webs. Recommendations and perspectives  More detailed studies using C- and N-stable isotope techniques and modeling approaches are needed to better understand the actual importance of HS to carbon cycling in highly humic waters.