Identifying the major players behind increasing global carbon dioxide emissions: a decomposition analysis

The paper using data on 114 countries during 1992–2004 identifies the major perpetrators of escalating global emissions. Using the LMDI decomposition technique, we examine the contribution of the major factors in changing the level of emissions. The effect of GDP on emission is found to be substantially more than that of population. However, the income effect shows high fluctuation over time, while the population effect has been roughly constant. The upper middle-income countries, particularly of Europe and Central Asia, despite high economic growth have reduced their emissions substantially, while in the countries of North America, East Asia Pacific and South Asia increase in income have been significantly accompanied by increase in emission. Apart from few low emitting countries, almost all others have been successful in increasing emission efficiency, but their energy efficiencies have not been remarkable. Although emission efficiency has been more instrumental in curtailing emission, in some cases the path of change in emission follows that of change in energy intensity. Thus, both energy and emission intensity have crucial roles in determining the level of emissions. It may be suggested that emphasis should be given on policies oriented towards sufficient counteractive energy and emission efficiencies before embarking on a path towards economic growth.     

Remediation technologies for heavy metal contaminated groundwater

The contamination of groundwater by heavy metal, originating either from natural soil sources or from anthropogenic sources is a matter of utmost concern to the public health. Remediation of contaminated groundwater is of highest priority since billions of people all over the world use it for drinking purpose. In this paper, thirty five approaches for groundwater treatment have been reviewed and classified under three large categories viz chemical, biochemical/biological/biosorption and physico-chemical treatment processes. Comparison tables have been provided at the end of each process for a better understanding of each category. Selection of a suitable technology for contamination remediation at a particular site is one of the most challenging job due to extremely complex soil chemistry and aquifer characteristics and no thumb-rule can be suggested regarding this issue. In the past decade, iron based technologies, microbial remediation, biological sulphate reduction and various adsorbents played versatile and efficient remediation roles. Keeping the sustainability issues and environmental ethics in mind, the technologies encompassing natural chemistry, bioremediation and biosorption are recommended to be adopted in appropriate cases. In many places, two or more techniques can work synergistically for better results. Processes such as chelate extraction and chemical soil washings are advisable only for recovery of valuable metals in highly contaminated industrial sites depending on economical feasibility.     

Chemical oxidation of C. I. Reactive Red 2 using Fenton-like reactions

A detailed investigation on the kinetics of the oxidative degradation of a reactive dye, C. I. Reactive Red 2 by hydroxyl radicals generated by H202 and Fe2+ has been carried out in aqueous acidic media. Effects of different parameters like initial concentration of dye, H2O2, Fe2+, pH of the solution, reaction temperature and added electrolytes on the oxidation process have been studied. The results indicate that 1.63 x 10(-4) mol dm(-3) dye can be most effectively degraded at a dye: Fe2+: H2O2 molar ratio of 1:0.22: 8.13 at pH approximately 2.7 and at 299 K. The addition of excess 2-propanol or t-butyl alcohol, well known scavengers of hydroxyl radicals, almost stopped the degradation of the dye indicating the absence of any possible reductive pathways in the degradation. The results may be useful for designing the treatment systems of wastewater containing various reactive dyes.     

ARTIFICIAL GROUND WATER RECHARGE EXPERIMENTS IN CARBONATE AND CLASTIC AQUIFERS OF KUWAIT1

ABSTRACT: Injection of water and subsequent withdrawal were carried out in three existing water wells (SU-10, C-105, and SU-135A) in Kuwait. The objective of the study was to assess the technical feasibility of artificial recharge in the carbonate Dammam Formation and the clastic Kuwait Group aquifers. In the absence of any pretreatment of injection water and measures for maintenance of line pressure, clogging from suspended solids and air entrapment occurred in all three experiments. It was, however, possible to inject for one month in Wells SU-10 and C-105 where injection took place in the Dammam aquifer. In Well SU-135A, where the Kuwait Group aquifer was the target for injection, clogging became so severe that the injection experiment had to be abandoned. The injection/withdrawal data were analyzed with the help of a multi-aquifer flow model and a transport model. The models took into account the effects of crossflow within the boreholes on the distribution of intake and discharge rates for different aquifers, and hence, on the recovery efficiency. The experiments suggested that the artificial recharge of the Dammam and the Kuwait Group aquifers was technically feasible. The problem of clogging was, however, more severe for the Kuwait Group.     

Economy wide impacts of ethanol and biodiesel policy in Canada: An input–output analysis

The Government of Canada has committed that Canada’s total greenhouse gas (GHG) emissions be reduced by 17% from 2005 levels by 2020. The new Renewable Fuels Regulations required 2% renewable content in diesel fuel and heating distillate oil and 5% for gasoline. This represents approximately 2.1 billion liters of ethanol and 600 million liters of biodiesel requirement per year, which would reduce GHG emissions by more than four million tones. Canada is expected to consume more fuel ethanol compared to its production capacity. The above mandates as well as the gap in consumption and production of biofuel will have enormous impact on the Canadian economy. In this backdrop, an input–output model of the Canadian economy is developed to estimate the macroeconomic impact of the ethanol and biodiesel production in Canada. The impacts on sectoral prices have also been calculated. Simulation exercises have been attempted to reach the mandates using modified Leontief model. Results show that agriculture sector is affected because of feedstock use in the biofuel sector. Mining and manufacturing industries also show a considerable impact. In addition, the impact on commodity prices cannot be ignored. Finally, to meet the target of Copenhagen commitment, the nation needs to revise the blending capacity of ethanol and biodiesel.     

Nondestructive characterization of municipal-solid-waste-contaminated surface soil by energy-dispersive X-ray fluorescence and low-Z (atomic number) particle electron probe X-ray microanalysis

The long-term environmental impact of municipal solid waste (MSW) landfilling is still under investigation due to the lack of detailed characterization studies. A MSW landfill site, popularly known as Dhapa, in the eastern fringe of the metropolis of Kolkata, India, is the subject of present study. A vast area of Dhapa, adjoining the current core MSW dump site and evolving from the raw MSW dumping in the past, is presently used for the cultivation of vegetables. The inorganic chemical characteristics of the MSW-contaminated Dhapa surface soil (covering a 2-km stretch of the area) along with a natural composite (geogenic) soil sample (from a small countryside farm), for comparison, were investigated using two complementary nondestructive analytical techniques, energy-dispersive X-ray fluorescence (EDXRF) for bulk analysis and low-Z (atomic number) particle electron probe X-ray microanalysis (low-Z particle EPMA) for single-particle analysis. The bulk concentrations of K, Rb, and Zr remain almost unchanged in all the soil samples. The Dhapa soil is found to be polluted with heavy metals such as Cu, Zn, and Pb (highly elevated) and Ti, Cr, Mn, Fe, Ni, and Sr (moderately elevated), compared to the natural countryside soil. These high bulk concentration levels of heavy metals were compared with the Ecological Soil Screening Levels for these elements (U.S. Environment Protection Agency) to assess the potential risk on the immediate biotic environment. Low-Z particle EPMA results showed that the aluminosilicate-containing particles were the most abundant, followed by SiO2, CaCO3-containing, and carbonaceous particles in the Dhapa samples, whereas in the countryside sample only aluminosilicate-containing and SiO2 particles were observed. The mineral particles encountered in the countryside sample are solely of geogenic origin, whereas those from the Dhapa samples seem to have evolved from a mixture of raw dumped MSW, urban dust, and other contributing factors such as wind, precipitation, weather patterns, farming, and water logging, resulting in their diverse chemical compositions and the abundant observation of carbonaceous species. Particles containing C and P were more abundant in the Dhapa samples than in the countryside soil sample, suggesting that MSW-contaminated soils are more fertile. However, the levels of particles containing potentially toxic heavy metals such as Cr, Mn, Ni, Cu, Zn, and/or Pb in the Dhapa samples were significant, corroborated by their high bulk concentration levels (EDXRF), causing deep concern for the immediate environment and contamination of the food chain through food crops.     

Hydro-chemical characterization of groundwater and evaluation of health risk assessment for fluoride contamination areas in the eastern blocks of Purulia district,India

Environment, Development and Sustainability - Purulia is a hard rock terrain where water scarcity as well as water quality degradation has been a major threat for the past few decades. The prolong...