微波消解和ASD消解ICP-MS测定土壤中重金属元素的比较

采用微波消解和ASD消解2种消解方式对不同土壤样品进行消解,ICP-MS测定其中重金属含量。微波和ASD2种消解方式均能够较好地提取土壤中的Cr、Co、Ni、Mn和V元素,实验结果的相对误差和相对标准偏差均≤10%,符合实验分析的要求。微波消解精密度优于ASD,可作为优先选择的前处理方法。     

一种淡水大型底栖无脊椎动物采样器研究

研制出一种长方体的十字筐采样器,在采样器内分别填装石、砂、底泥和水草4种基质,利用大型底栖无脊椎动物对生境的选择性进行样本被动采集。基质越多,采样器采集的生物种类越多,生物量也更丰富。用新研制的十字筐采样器和传统的篮式采样器对松花江流域7个采样点进行大型底栖无脊椎动物对比采样,结果显示:十字筐采样器是一种优良的采样器,适合在松花江流域乃至全国推广应用。     

美国光化学污染监测的经验与启示

针对光化学污染的严峻形势,中国应尽快建立国家层面的光化学监测网络,完善光化学监测的技术体系与质量管理体系,为重点地区光化学污染防治工作提供监测数据支持。研究在总结美国光化学评估监测网络发展历程、运行及其监测目标、技术体系和质量管理体系的基础上,提出了明确光化学监测目标、制定优先监测VOCs名单、完善光化学监测技术体系和质量管理体系、建立光化学监测数据共享平台以及开展VOCs源解析等建设中国光化学监测网络的具体建议。     

Distribution of antifouling biocides in California marinas

Antifouling biocides are used to prevent the settlement and growth of organisms on submerged surfaces. Irgarol 1051 is currently among the most widely used organic booster biocides worldwide. This study reports Irgarol 1051, its major metabolite M1 (aka GS26575), and diuron concentrations found in selected California marinas. Seasonal water samples (n = 46) were collected during the summer and fall of 2006 from eleven marinas throughout Southern and Northern California. The samples were extracted using solid phase extraction and analysed utilizing liquid chromatography tandem mass spectrometry (LC-MS-MS) with electrospray ionization. All three compounds were detected in all samples, representing a 100% frequency of occurrence and indicating widespread use around the sampled marinas. Irgarol concentrations ranged from 12 to 712 ng L(-1) (average 102 ng L(-1)), M1 concentrations were 1-217 ng L(-1) (average 31 ng L(-1)), and diuron concentrations were 5-27 ng L(-1) (average 13 ng L(-1)). In general, concentrations of both Irgarol (15-712 ng L(-1)) and M1 (1-217 ng L(-1)) were greater in samples collected during the summer, corresponding to the peak of the boating season. The detected diuron concentrations in most cases were greater for fall samples (7-27 ng L(-1)), and probably represented a combination of non-agricultural (rights of way) and agricultural applications of diuron in California. The maximum Irgarol concentration detected in California marinas in summer 2006 (712 ng L(-1)) was five times greater than the Irgarol concentration suggested as the plant toxicity benchmark (136 ng L(-1)). Twenty three percent of samples from California marinas in this study exceeded this benchmark, suggesting that detected Irgarol concentrations may be high enough to cause changes in phytoplankton communities in the sampled marinas.     

Occurrence,sources, and ecological risks of PBDEs,PCBs, OCPs,and PAHs in surface sediments of the Yangtze River Delta city cluster,China

Polybrominated diphenyl ethers (PBDEs), organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs), and polycyclic aromatic hydrocarbons (PAHs) in 25 surface sediments in three cities (Nantong, Wuxi, and Suzhou) in the Yangtze River Delta, eastern China were measured. The mean concentrations were 378, 45.8, 1.98, 4,002 ng/g for PBDEs, OCPs, PCBs, and PAHs, respectively. Their levels in the sediments in the three cities were generally consistent with the city industrialization. PBDEs and OCPs were markedly dominated by deca-BDE (>90 %) and DDTs (>70 %). A principle component analysis of the analytes identified three major factors suggesting different sources of the contaminants in the sediments. PBDEs and the organic carbon in the sediments have common sources from industrial activities; whereas OCPs and PCBs, correlated with the second factor, were mainly from historical sources. The third factor with loadings of PAHs is indicative of various combustion sources. Ecological risk assessment indicated that the potential highest risk is from DDTs, for which 22 sites exceed the effects range low (ERL) values and three sites exceed the effects range median (ERM) value.     

Habitat classification: A comparison using avian species and guilds

Results of breeding bird censuses in 1979 and 1980 were used to compare the relationships of both species and guilds to forest habitats in the White Mountains of New Hampshire. Several age classes of 11 forest cover types were studied: northern hard-woods (Fagus-Betula-Acer), spruce (Picea), spruce-fir (Picea-Abies), birth (Betula), swamp hardwoods (Acer-Pinus-Tsuga), pine (Pinus strobus andP. resinosa), balsam fir (Abies), aspen (Populus tremuloides andP. grandidentata), northern red oak (Quercus), oak-pine (Quercus-Pinus), and hemlock (Tsuga). All types were even-aged; only northern hardwoods had an additional uneven-aged condition. Forest cover types were also pooled to consider generalized habitats: hardwoods, mixed forest, or softwoods. Results of ordinations based on censuses of 74 bird species indicate that foraging guilds are more related to general cover types than are nesting substrate guilds, but bird species reflect habitat differences to a greater degree than do either guild scheme. Also, considerable overlap occurs in bird species distribution between hardwoods and mixed forests; softwoods show little overlap with other types. Discriminant function and classification analyses revealed that bird species composition can be used to correctly classify general forest habitats more accurately (83.8%) than either foraging (63.2%) or nesting substrate guilds (58.4%). These results indicate that, of the habitats studied, avian species compositions are more characteristic than are foraging or nesting substrate guild composition, which tend to be similar across forest habitats.     

Flood area and damage estimation in Zhejiang,China

A GIS-based method to estimate flood area and damage is presented in this paper, which is oriented to developing countries like China, where labor is readily available for GIS data collecting, and tools such as, HEC-GeoRAS might not be readily available. At present local authorities in developing countries are often not predisposed to pay for commercial GIS platforms. To calculate flood area, two cases, non-source flood and source flood, are distinguished and a seed-spread algorithm suitable for source-flooding is described. The flood damage estimation is calculated in raster format by overlaying the flood area range with thematic maps and relating this to other socioeconomic data. Several measures used to improve the geometric accuracy and computing efficiency are presented. The management issues related to the application of this method, including the cost-effectiveness of approximate method in practice and supplementing two technical lines (self-programming and adopting commercial GIS software) to each other, are also discussed. The applications show that this approach has practical significance to flood fighting and control in developing countries like China.     

河冰对桥墩作用的冰荷载计算方法(Ⅰ)——河冰的力学性能试验

通过对松花江河冰的物理力学性能试验和松花江公路大桥桥墩的流冰动压力测量、桥面的脉动测量 ,依据国内外对冰 -结构相互作用的分析 ,提出了适合我国黑龙江冰情特点的春季流冰冰荷载的计算方法。     

领导干部安全培训工作的思考

安全生产培训可为安全生产形势的稳定好转提供保障。本文结合安全生产工作实际,在不断摸索和总结培训工作经验的基础上,对如何做好地（市）、县（市）领导干部的安全生产培训工作,特别是培训的目的、方式和方法等方面有了更加清晰的认识。在此基础上对今后如何开展地（市）、县（市）领导干部的安全生产培训工作提出一些建议,如设置模块教学、理好传统教育与现代培训的关系、加大培训力度,扩大培训范围等方式和方法,以增强培训效果。