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21.
Mehmet Sinan Bilgili Gamze Varank Elif Sekman Selin Top Didem Özçimen Remziye Yazıcı 《Environmental Modeling and Assessment》2012,17(3):289-300
Since phenols and phenolic compounds in many industrial wastewaters are toxic organic contaminants for humans and aquatic
life, to remove these compounds via the most efficient way is very important for environmental remediation treatment. In this
context, almost all of the isotherm models (Freundlich, Langmuir, Temkin, Redlich–Peterson, Sips, and Khan) for adsorption
in the literature were applied to explain the adsorption mechanism of 4-chlorophenol on activated carbon in this study. Also
theoretical modeling data were obtained using model equations; interpolation and analysis of variance were made to compare
data by using statistics software. In addition, the thermodynamic and kinetic studies for adsorption mechanism were included
in the article. The adsorption of 4-chlorophenol on activated carbon fits well to the pseudo-first-order kinetic model than
the pseudo-second-order, intraparticular diffusion and Bangham models. It is also indicated that 4-chlorophenol adsorption
by granular activated carbon would be attributed to a type of transition between physical and chemical adsorption rather than
a pure physical or chemical adsorption process. As a result, an environmental remediation problem and the adsorption mechanism
on activated carbon that can be regarded as a solution to this problem are described and explained using the mathematical
models and calculations in this study. 相似文献
22.
When agricultural lands are no longer used for agriculture and allowed to recover its natural vegetation, soil organic carbon
can accumulate in the soil. Measurements of soil organic carbon and aggregate stability changes under various forms of land
use are needed for the development of sustainable systems. Therefore, comparison of soil samples taken from both agricultural
and nearby area close to land-mined fields where no agricultural practices have been done since 1956 can be a good approach
to evaluate the effects of tillage and agriculture on soil quality. The objective of this study was to compare tillage, cropping
and no tillage effects on some soil-quality parameters. Four different locations along the Turkey–Syria border were selected
to determine effects of tillage and cropping on soil quality. Each location was evaluated separately because of different
soil type and treatments. Comparisons were made between non-tilled and non-cropped fallow since 1956 and adjacent restricted
lands that were tilled about every 2 years but not planted (T) or adjacent lands tilled and planted with wheat and lentil
(P). Three samples were taken from the depths of 0–20 and 20–40 cm each site. Soil organic carbon (SOC), pH ,electrical conductivity,
water soluble Ca++, Mg++, CO3-2{\rm CO}_{3}^{-2} and HCO3-{\rm HCO}_{3}^{-}, extractable potassium (K+) and sodium (Na+), soil texture, ammonium (NH4+{\rm NH}_{4}^{+}–N) and nitrate (NO3–N), extractable phosphorous and soil aggregate stability were determined. While the SOC contents of continuous tillage without
cropping and continuous tillage and cropping were 2.2 and 11.6 g kg−1, respectively, it was 30 g kg−1 in non-tilled and non-planted site. Tillage of soil without the input of any plant material resulted in loss of carbon from
the soil in all sites. Soil extractable NO3−N contents of non-tilled and non-cropped sites were greatest among all treatments. Agricultural practices increased phosphorus
and potassium contents in the soil profile. P2O5 contents of planted soils were approximately 20 to 39 times greater than those of non-tilled and non-cropped soils at different
sites. FTIR spectra showed that never tilled sites had greater phenol, carboxylic acid, amide, aromatic compounds, polysaccharide
and carbohydrates than other treatments. 相似文献
23.
Ümit H. Kaynar Seda Çınar Sermin Çam Kaynar Mehmet Ayvacıklı Tülin Aydemir 《Journal of Polymers and the Environment》2018,26(6):2300-2310
Nano-ZnO-chitosan bio-composite beads were prepared for the sorption of \({\text{UO}}_{2}^{{2+}}\) from aqueous media. The resulting nano-ZnO/CTS bio-composite beads were characterized by TEM, XRD etc. The sorption of \({\text{UO}}_{2}^{{2+}}\) by bio-composite beads was optimized using RSM. The correlation between four variables was modelled and studied. According to RSM data, correlation coefficients (R2?=?0.99) and probability F-values (F?=?2.24?×?10??10) show that the model fits the experimental data well. Adsorption capacity for nano-ZnO/CTS bio-composite beads was obtained at 148.7 mg/g under optimum conditions. The results indicate that nano-ZnO/CTS bio-composite beads are appropriate for the adsorption of \({\text{UO}}_{2}^{{2+}}\) ions from aqueous media. Also, the suitability of adsorption values to adsorption isotherms was researched and thermodynamic data were calculated. 相似文献
24.
Buse Tuğba Zaman Emine Gülhan Bakırdere Nursu Aylin Kasa Serenay Deniz Sabriye Sel Dotse Selali Chormey Sezgin Bakırdere 《Environmental monitoring and assessment》2018,190(7):437
This study describes the determination of trace levels of copper by slotted quartz tube atomic absorption spectrometry after dispersive liquid-liquid microextraction. A ligand synthesized from the reaction of salicylaldehyde and 1-naphthylamine was used to form coordinate copper complex prior to extraction. All parameters that influence the output of complex formation, extraction, and instrumental measurement were optimized to enhance the absorbance signal of copper. Under the optimum conditions, about 104-fold enhancement in sensitivity was recorded over the conventional flame atomic absorption spectrometer, corresponding to a 0.51 ng/mL detection limit. The percent relative standard deviation calculated for the lowest concentration (4.8%) indicated high precision for the experimental procedure. Accuracy and applicability of the optimum method were determined by performing spiked recovery tests on urine, lake water, and mineral water samples. Satisfactory recovery results were obtained between 82.2 and 106.3% at four different concentrations. Matrix matching method was also performed to increase the accuracy of quantification, and the percent recovery calculated for 175 ng/mL was 105.14%. 相似文献
25.
Nearest neighbor (NN) methods are widely employed for drawing inferences about spatial point patterns of two or more classes. We introduce a method for testing reflexivity in the NN structure (i.e., NN reflexivity) based on a contingency table which will be called reflexivity contingency table (RCT) henceforth. The RCT is based on the NN relationships among the data points and was used for testing niche specificity in literature, but we demonstrate that it is actually more appropriate for testing the NN reflexivity pattern. We derive the asymptotic distribution of the entries of the RCT under random labeling and introduce tests of reflexivity based on these entries. We also consider Pielou’s approach on RCT and show that it is not appropriate for completely mapped spatial data. We determine the appropriate null hypotheses and the underlying conditions/assumptions required for all tests considered. We investigate the finite sample performance of the tests in terms of empirical size and power by extensive Monte Carlo simulations and illustrate the methods on two real-life ecological data sets. 相似文献
26.
This study proposes and employs a structural model to examine the effects of environmental literacy, environmental awareness, environmental attitudes, and environmental behavior among middle school students in Eski?ehir on their purchase of environmentally friendly products. In the proposed structural model, environmental illiteracy and environmental awareness were the exogenous latent variables, while pro-environmental attitude, pro-environmental behavior, and the purchase of environmentally friendly products were the endogenous latent variables. The latent variable of environmental illiteracy did not have a statistically significant effect on environmental attitudes and purchase of environmentally friendly products, whereas environmental awareness had a positive effect on pro-environmental attitudes and the purchase of environmentally friendly products. These findings indicate that students with environmental awareness also develop positive attitudes toward the environment, and the presence of a positive attitude toward the environment leads them to display pro-environmental behaviors and adopt a positive attitude toward environmentally friendly products. 相似文献
27.
Mehmet Akgül Nadir Ayrilmis Osman Çamlıbel Süleyman Korkut 《Journal of Material Cycles and Waste Management》2013,15(2):195-201
The potential utilization of burned wood in the manufacture of medium density fiberboard (MDF) was investigated. For this aim, the MDF panels were made of various mixtures of burned pine wood (Pinus sylvestris L.), unburned beech (Fagus orientalis L.) and oak (Ouercus robur L.) woods under commercial conditions in an MDF company. The mixture ratio of the unburned beech and oak woods to the burned pine wood were 50/50 wt%. The mixing ratios of burned wood chips with unburned wood chips were 0:100, 25:75, 50:50, 75:25 and 100:0, %, respectively. A commercial urea–formaldehyde resin was used as a binder. The physical properties measured in the investigation included density and thickness swelling, while the mechanical properties examined were bending strength, modulus elasticity, internal bond, screw holding ability perpendicular to the plane of panel, and janka hardness perpendicular to the plane of the panel. Surface roughness and color of the panels were also measured. The results indicated that all the panels met the mechanical properties of general-purpose MDF requirements of EN 622-5. The surface roughness of the MDF panels containing burned wood decreased with increasing burned wood content but remained higher than the control panels. The dimensional stability of the MDF panels decreased with the incorporation of burned wood fibers as compared with the control MDF panels. 相似文献
28.
Evaluation of heavy metal content in digestate from batch anaerobic co-digestion of sunflower hulls and poultry manure 总被引:1,自引:0,他引:1
Burak Demirel Nefise Pınar Göl Turgut Tüzün Onay 《Journal of Material Cycles and Waste Management》2013,15(2):242-246
In this experimental study, the biogas digestate from mesophilic batch anaerobic co-digestion of poultry manure and an agricultural residue, sunflower hulls, was characterized, particularly in terms of heavy metal content, in order to evaluate whether the biogas digestate was suitable for land applications. Ni, Zn, Cu, Pb, Cr, Cd, and Hg were detected in the biogas digestate in each trial, however, their concentrations were always lower than the limit values stated in Turkish regulations. The main source of heavy metals in the biogas digestate seemed to be the poultry manure, not the agricultural residue. The commercial feedstuffs that are frequently supplemented with various essential elements to promote optimum nutrient supply and optimum growth rates may have contributed to heavy metals presence in the biogas digestate. The results indicated that the biogas digestate from anaerobic co-digestion of manure and agricultural residue could be utilized as fertilizer in agricultural applications. 相似文献
29.
Zeynep Kılıç Orhan Atakol Sümer Aras Demet Cansaran-Duman Pelin Çelikkol 《Journal of the Air & Waste Management Association (1995)》2014,64(1):115-123
The biosorption characteristics of Cu(II) ions from aqueous solution using Lobaria pulmonaria (L.) Hoffm. biomass were investigated. The biosorption efficiency of Cu(II) onto biomass was significantly influenced by the operating parameters. The maximum biosorption efficiency of L. pulmonaria was 65.3% at 10 mg/L initial metal concentration for 5 g/L lichen biomass dosage. The biosorption of Cu(II) ions onto biomass fits the Langmuir isotherm model and the pseudo-second-order kinetic model well. The thermodynamic parameters indicate the feasibility and exothermic and spontaneous nature of the biosorption. The effective desorption achieved with HCl was 96%. Information on the nature of possible interactions between the functional groups of the L. pulmonaria biomass and Cu(II) ions was obtained via Fourier transform infrared (FTIR) spectroscopy. The results indicated that the carboxyl (–COOH) and hydroxyl (–OH) groups of the biomass were mainly involved in the biosorption of Cu(II) onto L. pulmonaria biomass. The L. pulmonaria is a promising biosorbent for Cu(II) ions because of its availability, low cost, and high metal biosorption and desorption capacities.
Implications: Lobaria pulmonaria is a promising biosorbent for Cu(II) ions because of its availability, low cost, and high metal biosorption and desorption capacities. To the best of our knowledge, this is the first paper on the biosorption Cu by L. pulmonaria. 相似文献
30.
Sibel Mentese Abbas Yousefi Rad Münevver Arısoy Gülen Güllü 《Journal of the Air & Waste Management Association (1995)》2013,63(12):1380-1393
This study was performed to investigate the possible sources as well as seasonal and diurnal variations of indoor air pollutants in widely used four different environments (house, office, kindergarten, and primary school) in which people spend most of their time. Bioaerosol levels and species, volatile organic compound (VOC) levels, and PM2.5 (particulate matter with an aerodynamic diameter ≤2.5 μm) levels were determined in different parts of these environments in parallel with outdoor sampling. Air pollution samplings were carried out in each microenvironment during five subsequent days in both winter and summer in Ankara, Turkey. The results indicated that bioaerosol, VOC, and PM2.5 levels were higher in the winter than in the summer. Moreover, PM2.5 and bioaerosol levels showed remarkable daily and diurnal variations, whereas a good correlation was found between the VOC levels measured in the morning and in the afternoon. Bacteria levels were, in general, higher than fungi levels. Among the VOCs, toluene was the most predominant, whereas elevated n-hexane levels were also observed in the kindergarten and the primary school, probably due to the frequent wet cleaning during school days. According to factor analysis, several factors were found to be significantly influencing the indoor air quality (IAQ), and amongst them, VOC-based products used indoors ranked first. The overall results indicate that grab sampling in naturally ventilated places may overestimate or underestimate the IAQ due to the inhomogeneous composition of indoor air caused by irregular exchanges with the outdoor air according to the season and/or occupants' habits.
Implications Seasonal and diurnal variations of VOCs, PM2.5, bioaerosols in house, office, and schools were observed, in which PM2.5 and bioaeorosols showed marked both intra- and interday variability, but VOCs did not. VOC-containing products were the most common source of air pollutants affecting the indoor air quality. External factors affecting the indoor air quality were season and indirectly ventilation. A grab sample cannot be representative in evaluating the air quality of a naturally ventilated environment precisely. 相似文献