Microplastics removal strategies: A step toward finding the solution

• Physical, chemical and biological methods are explored for MPs removal. • Physical methods based on adsorption/filtration are mostly used for MPs removal. • Chemical methods of MPs removal work on coagulation and flocculation mechanism. • MBR technology has also shown the removal of MPs from water. • Global policy on plastic control is lacking. Microplastics are an emerging threat and a big challenge for the environment. The presence of microplastics (MPs) in water is life-threatening to diverse organisms of aquatic ecosystems. Hence, the scientific community is exploring deeper to find treatment and removal options of MPs. Various physical, chemical and biological methods are researched for MPs removal, among which few have shown good efficiency in the laboratory. These methods also have a few limitations in environmental conditions. Other than finding a suitable method, the creation of legal restrictions at a governmental level by imposing policies against MPs is still a daunting task in many countries. This review is an effort to place all effectual MP removal methods in one document to compare the mechanisms, efficiency, advantages, and disadvantages and find the best solution. Further, it also discusses the policies and regulations available in different countries to design an effective global policy. Efforts are also made to discuss the research gaps, recent advancements, and insights in the field.     

Materials,fuels, upgrading,economy, and life cycle assessment of the pyrolysis of algal and lignocellulosic biomass: a review

Climate change issues are calling for advanced methods to produce materials and fuels in a carbon–neutral and circular way. For instance, biomass pyrolysis has been intensely investigated during the last years. Here we review the pyrolysis of algal and lignocellulosic biomass with focus on pyrolysis products and mechanisms, oil upgrading, combining pyrolysis and anaerobic digestion, economy, and life cycle assessment. Products include oil, gas, and biochar. Upgrading techniques comprise hot vapor filtration, solvent addition, emulsification, esterification and transesterification, hydrotreatment, steam reforming, and the use of supercritical fluids. We examined the economic viability in terms of profitability, internal rate of return, return on investment, carbon removal service, product pricing, and net present value. We also reviewed 20 recent studies of life cycle assessment. We found that the pyrolysis method highly influenced product yield, ranging from 9.07 to 40.59% for oil, from 10.1 to 41.25% for biochar, and from 11.93 to 28.16% for syngas. Feedstock type, pyrolytic temperature, heating rate, and reaction retention time were the main factors controlling the distribution of pyrolysis products. Pyrolysis mechanisms include bond breaking, cracking, polymerization and re-polymerization, and fragmentation. Biochar from residual forestry could sequester 2.74 tons of carbon dioxide equivalent per ton biochar when applied to the soil and has thus the potential to remove 0.2–2.75 gigatons of atmospheric carbon dioxide annually. The generation of biochar and bio-oil from the pyrolysis process is estimated to be economically feasible.

     

Large inter annual variation in air quality during the annual festival ‘Diwali' in an Indian megacity

A network of air quality and weather monitoring stations was established under the System of Air Quality Forecasting and Research(SAFAR) project in Delhi. We report observations of ozone(O_3), nitrogen oxides(NO_x), carbon monoxide(CO) and particulate matter(PM_2.5and PM_(10)) before, during and after the Diwali in two consecutive years, i.e., November 2010 and October 2011. The Diwali days are characterised by large firework displays throughout India. The observations show that the background concentrations of particulate matter are between 5 and 10 times the permissible limits in Europe and the United States. During the Diwali-2010, the highest observed PM_(10) and PM_2.5mass concentration is as high as2070 μg/m~3 and 1620 μg/m3, respectively(24 hr mean), which was about 20 and 27 times to National Ambient Air Quality Standards(NAAQS). For Diwali-2011, the increase in PM_(10) and PM_2.5mass concentrations was much less with their peaks of 600 and of 390 μg/m~3 respectively, as compared to the background concentrations. Contrary to previous reports,firework display was not found to strongly influence the NO_x, and O_3 mixing ratios, with the increase within the observed variability in the background. CO mixing ratios showed an increase. We show that the large difference in 2010 and 2011 pollutant concentrations is controlled by weather parameters.     

Optimization of pretreatment conditions for enhanced sugar release

Present investigation was done to evaluate various algal genera found in water bodies of Varanasi city. The potential of any biomass for biofuels (bioalcohols, biohydrogen, etc.) production depends on the quantity of extractable sugar present in it. Acid (H₂SO₄) and alkali (NaOH) pretreatment were performed, and H₂SO₄ was chosen due to its nearly double yield as compared with alkaline pretreatment. Response surface methodology was utilized for the optimization of operating parameters such as treatment temperature, time, and acid concentration. Sugar yield up to 0.33 g/g of dry biomass was obtained using cyanobacterial biomass of Lyngbya limnetica, at 100°C, 59.19 min, and H₂SO₄ concentration of 1.63 M.     

Correction to: Hydrogen production,storage, utilisation and environmental impacts: a review

Environmental Chemistry Letters -     

Conductive and convective heat transfer augmentation in flat plate solar collector from energy,economic and environmental perspectives — a comprehensive review

Environmental Science and Pollution Research - The primary objective of the paper is to identify the effective way to enhance the conductive and convective heat transfer of the FPSC. The...     

Hydrogen production,storage, utilisation and environmental impacts: a review

Environmental Chemistry Letters - Dihydrogen (H2), commonly named ‘hydrogen’, is increasingly recognised as a clean and reliable energy vector for decarbonisation and defossilisation by...     

Fullerenes for the treatment of cancer: an emerging tool

Environmental Science and Pollution Research - Cancer is a most common cause of mortality globally. Available medicines possess severe side effects owing to their non-specific targeting. Hence,...     

Study on chemical kinetics and catalytic cracking of tar from gasification of rice straw using various catalysts

Journal of Material Cycles and Waste Management - The tar formed within the producer gas is a major problem in the biomass gasification process. The catalytic cracking of tar is the best method to...     

Lead content in new decorative paints in India

The paint industry in India is broadly classified into two categories: organized sector and unorganized sector. Multinational and big Indian companies form the organized sector, whereas the small- and medium-scale industries which produce paints for the local market form the unorganized sector. The present study was undertaken to determine the level of lead in decorative paints in India. A total of 148 paint samples sourced from four organized sector companies and six unorganized sector companies were analyzed for the total lead content. Results of this study reveal that 39 % of the total paints tested (n = 148) contain lead more than 300 ppm, the voluntary limit prescribed by Bureau of Indian Standards, BIS (IS 15489:2011), and 45 % of the tested paints contain lead more than 90 ppm, the US limit. Further analysis of the data indicates that only 5 % of the tested paints manufactured by organized sector companies contain lead more than 300 ppm (n = 91), whereas 93 % of the tested paints manufactured by unorganized sector companies contain lead more than 300 ppm (n = 57). Comparison with earlier reported data suggests that while organized sector companies are gradually abandoning the use of lead-based compounds in their paints, the unorganized sector companies are still adding lead-based compounds intentionally in their paints despite the potential health hazards associated with it. The maximum concentration of lead obtained was 80,350 ppm in one of the paints manufactured by an unorganized sector company. The presence of high concentration of lead in yellow and green color paints indicates that color can be a predictor of lead content in decorative paints.