油田企业安全文化建设亟需解决的几个问题及对策

油田企业生产工作具有点多、线长、面广、庞杂、易燃易爆、有毒有害、高温高压、连续作业等特点,安全生产管理难度相当大,若稍有不慎,就会酿成大的事故.因此,避免或减少重大事故的发生是油田企业安全文化建设的重要目标.20世纪90年代,随着HSE管理体系引入中国,国内油田企业相继建立了HSE管理制度,并把HSE安全管理体系作为企业安全文化建设的主要载体.但油田企业安全文化建设仍存在误区,完全文化建设体系亟需进一步完善.     

Emissions of ammonia, hydrogen sulfide, and odor before, during, and after slurry removal from a deep-pit swine finisher

It is a common practice in the midwestern United States to raise swine in buildings with under-floor slurry storage systems designed to store manure for up to one year. These so-called "deep-pit" systems are a concentrated source for the emissions of ammonia (NH3), hydrogen sulfide (H2S), and odors. As part of a larger six-state research effort (U.S. Department of Agriculture-Initiative for Future Agriculture and Food Systems Project, "Aerial Pollutant Emissions from Confined Animal Buildings"), realtime NH3 and H2S with incremental odor emission data were collected for two annual slurry removal events. For this study, two 1000-head deep-pit swine finishing facilities in central Iowa were monitored with one-year storage of slurry maintained in a 2.4 m-deep concrete pit (or holding tank) below the animal-occupied zone. Results show that the H2S emission, measured during four independent slurry removal events over two years, increased by an average of 61.9 times relative to the before-removal H2S emission levels. This increase persisted during the agitation process of the slurry that on average occurred over an 8-hr time period. At the conclusion of slurry agitation, the H2S emission decreased by an average of 10.4 times the before-removal emission level. NH3 emission during agitation increased by an average of 4.6 times the before-removal emission level and increased by an average of 1.5 times the before-removal emission level after slurry removal was completed. Odor emission increased by a factor of 3.4 times the before-removal odor emission level and decreased after the slurry-removal event by a factor of 5.6 times the before-removal emission level. The results indicate that maintaining an adequate barn ventilation rate regardless of animal comfort demand is essential to keeping gas levels inside the barn below hazardous levels.     

Aniline degradation by electrocatalytic oxidation

The degradation of aniline solution in alkaline medium of pH 11.0 by electrocatalytic oxidation has been studied using an electrochemical reactor containing a SnO₂–Sb₂O₃–PtO anode and a Ti cathode, both of 54 cm² area. Hydroxyl radicals (HO^√) are produced at the anode, being tested with the trace catcher salicylic acid and phenol by spectrophotometery and high performance liquid chromatography. Intermediates dianiline, 4-anilino phenol and azobenzol were detected by gas chromatography–mass spectrometry. The existence of HO^√ produced in the aniline degradation was assayed with scavenger tertiary butanol. The results showed that electrocatalytic oxidation is an effective process for the degradation of aniline. A general reaction pathway that accounts for aniline degradation to CO₂ involving those intermediates is proposed.     

黄河中游水保措施对入黄干支流泥沙特性的影响:Ⅱ.减沙效益分析

应用文献［１］关于不同地貌类型及不同水保措施条件下黄河干支流中泥沙粒径分布的研究结果,可以对相应条件下的减沙效益进行有效的分析。利用文献［１］模型,本文不仅探讨了在给定地貌类型条件下各类水保措施实施前后流域汇入黄河干支流的泥沙总量的变化,而且还在扣除降雨变化的影响之后,预测了各类组合条件下非均匀泥沙中减沙效果最佳的粒径级和相应粒径级泥沙的减沙量,预测结果得到了黄河干支流各站所有实测资料的验证。文中还简要讨论了人类活动（主要是开矿）对减沙效益的影响。     

高精度热电离质谱定年及其对第四纪环境研究的意义

用高精度、高灵敏度不平衡铀系热电离质谱 (TIMS)法测定第四纪地质年龄 ,并已在古气候、古环境、古海洋、考古学以及近代活动火山作用的研究中取得了一系列重要成果。本文介绍了我们用MAT -2 62质谱仪对石笋、珊瑚进行测试并取得比较满意结果的情况。     

固定化微生物技术处理垃圾渗滤液

采用固定化微生物技术建成了处理量为60m3d的垃圾渗滤液处理装置,运转结果表明:在进水CODCr为1980mgL、氨氮为820mgL的情况下,处理出水中CODCr为130mgL、氨氮为0.80mgL。该处理系统具有较强的抗冲击负荷的能力,且未发现水质的变化对微生物特别是硝化细菌产生抑制现象。     

6061‑T6铝合金材料的冲击压缩力学性能实验与数值模拟∗

为了探究 6061?T6 铝合金的冲击力学性能和在防护结构上的应用前景,采用实验与数值模拟相结合的方法开展分析研究。根据多组准静态压缩及冲击压缩实验数据,对 Johnson?Cook 本构模型的相应参数进行了拟合;再进行数值模拟分析,并把数值模拟的结果与实验结果对比分析。最终,得到了 6061?T6 铝合金在常温下的屈服强度、峰值应力等力学参数;拟合出了 6061?T6 铝合金 J?C 模型的相应参数;研究表明 6061?T6 铝合金是一种应变率敏感材料,其屈服强度、流动应力峰值随着应变率的提高而提高,同时材料对冲击荷载的能量吸收也越来越多;当应变率为 1 600 s^-1 时,相对于准静态,其屈服强度和极限承载力分别提高了 30%、78%;数值模拟结果与实验结果吻合较好,表明拟合的 J?C 模型能够较好地表现出 6061?T6 铝合金在高应变率下的应力流动行为。研究成果可为 6061?T6 铝合金材料冲击动力学分析和在抗爆结构上的应用提供依据和参考,其在防护工程,防灾减灾工程领域上应用前景广阔。     

天然气净化厂放空废气对环境的影响及控制措施

天然气净化厂除正常生产有工艺废气排放外,传统装置检修开停产过程、供电或设备异常情况下,会有大量酸气、原料气通过放空火炬燃烧后排放。文章主要分析了天然气净化装置放空废气排放情况及其对周边环境的影响,阐述了异常放空、检修开停产过程原料气和酸气放空的控制措施及其环境效益。     

Pyrolysis characteristics of organic components of municipal solid waste at high heating rates

The pyrolysis characteristics of six representative organic components of municipal solid waste (MSW) and their mixtures were studied in a specially designed thermogravimetric analysis apparatus with a maximum recorded heating rate of 864.8 degrees Cmin(-1). The pyrolysis behavior of individual components was described by the Avrami-Erofeev equation. The influence of final temperature on individual components was studied, and it was concluded that final temperature was a factor in reaction speed and intensity, but that it played only a limited role in determining the reaction mechanism. The interactions between different components were evaluated, and it was concluded that the interaction between homogeneous materials was minimal, whereas the interaction between polyethylene and biomass was significant.     

城市污泥微波干化工艺及干化特性研究

采用微波和烘箱结合及全程烘箱2种方式对城市污泥干化进行对比研究,考察了不同粒径、微波干化预处理、预处理时间及烘箱温度对污泥干燥特性的影响。结果表明,同一温度条件下,微波预处理时间越长,污泥干化速率越快。最优条件下,全程烘箱污泥达到最大干化速率的含水率为77%。微波干燥污泥具有时间短、干燥速率大的特点,微波和烘箱结合对比全程烘箱干化速率高且能耗低。