全文获取类型
收费全文 | 29467篇 |
免费 | 326篇 |
国内免费 | 222篇 |
专业分类
安全科学 | 831篇 |
废物处理 | 1060篇 |
环保管理 | 4034篇 |
综合类 | 4660篇 |
基础理论 | 8531篇 |
环境理论 | 21篇 |
污染及防治 | 7707篇 |
评价与监测 | 1741篇 |
社会与环境 | 1239篇 |
灾害及防治 | 191篇 |
出版年
2022年 | 179篇 |
2021年 | 179篇 |
2019年 | 215篇 |
2018年 | 387篇 |
2017年 | 380篇 |
2016年 | 554篇 |
2015年 | 489篇 |
2014年 | 677篇 |
2013年 | 2132篇 |
2012年 | 841篇 |
2011年 | 1249篇 |
2010年 | 1025篇 |
2009年 | 1033篇 |
2008年 | 1249篇 |
2007年 | 1329篇 |
2006年 | 1182篇 |
2005年 | 1004篇 |
2004年 | 1003篇 |
2003年 | 937篇 |
2002年 | 936篇 |
2001年 | 1239篇 |
2000年 | 860篇 |
1999年 | 548篇 |
1998年 | 426篇 |
1997年 | 435篇 |
1996年 | 442篇 |
1995年 | 482篇 |
1994年 | 438篇 |
1993年 | 395篇 |
1992年 | 414篇 |
1991年 | 373篇 |
1990年 | 376篇 |
1989年 | 411篇 |
1988年 | 347篇 |
1987年 | 300篇 |
1986年 | 276篇 |
1985年 | 305篇 |
1984年 | 286篇 |
1983年 | 321篇 |
1982年 | 322篇 |
1981年 | 271篇 |
1980年 | 243篇 |
1979年 | 269篇 |
1978年 | 229篇 |
1977年 | 195篇 |
1976年 | 200篇 |
1975年 | 192篇 |
1974年 | 172篇 |
1973年 | 171篇 |
1972年 | 198篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
971.
E. J. Ekuase T. J. van ‘t Erve L. W. Robertson M. W. Duffel G. Luthe 《Environmental science and pollution research international》2016,23(3):2119-2127
Determining the relationships between the structures of substrates and inhibitors and their interactions with drug-metabolizing enzymes is of prime importance in predicting the toxic potential of new and legacy xenobiotics. Traditionally, quantitative structure activity relationship (QSAR) studies are performed with many distinct compounds. Based on the chemical properties of the tested compounds, complex relationships can be established so that models can be developed to predict toxicity of novel compounds. In this study, the use of fluorinated analogues as supplemental QSAR compounds was investigated. Substituting fluorine induces changes in electronic and steric properties of the substrate without substantially changing the chemical backbone of the substrate. In vitro assays were performed using purified human cytosolic sulfotransferase hSULT2A1 as a model enzyme. A mono-hydroxylated polychlorinated biphenyl (4-OH PCB 14) and its four possible mono-fluoro analogues were used as test compounds. Remarkable similarities were found between this approach and previously published QSAR studies for hSULT2A1. Both studies implicate the importance of dipole moment and dihedral angle as being important to PCB structure in respect to being substrates for hSULT2A1. We conclude that mono-fluorinated analogues of a target substrate can be a useful tool to study the structure activity relationships for enzyme specificity. 相似文献
972.
Patrícia Gomes Teresa Valente M. Amália Sequeira Braga J. A. Grande M. L. de la Torre 《Environmental science and pollution research international》2016,23(7):6039-6045
Reactive waste dumps with sulfide minerals promote acid mine drainage (AMD), which results in water and soil contamination by metals and metalloids. In these systems, contamination is regulated by many factors, such as mineralogical composition of soil and the presence of sorption sites on specific mineral phases. So, the present study dedicates itself to understanding the distribution of trace elements in different size fractions (<2-mm and <2-μm fractions) of mining soils and to evaluate the relationship between chemical and mineralogical composition. Cerdeirinha and Penedono, located in Portugal, were the waste dumps under study. The results revealed that the two waste dumps have high degree of contamination by metals and arsenic and that these elements are concentrated in the clay size fraction. Hence, the higher degree of contamination by toxic elements, especially arsenic in Penedono as well as the role of clay minerals, jarosite, and goethite in retaining trace elements has management implications. Such information must be carefully thought in the rehabilitation projects to be planned for both waste dumps. 相似文献
973.
H. Pizarro M. S. Vera A. Vinocur G. Pérez M. Ferraro R. J. Menéndez Helman M. dos Santos Afonso 《Environmental science and pollution research international》2016,23(6):5143-5153
Since it was commercially introduced in 1974, glyphosate has been one of the most commonly used herbicides in agriculture worldwide, and there is growing concern about its adverse effects on the environment. Assuming that glyphosate may increase the organic turbidity of water bodies, we evaluated the effect of a single application of 2.4?±?0.1 mg l?1 of glyphosate (technical grade) on freshwater bacterioplankton and phytoplankton (pico, micro, and nanophytoplankton) and on the physical and chemical properties of the water. We used outdoor experimental mesocosms under clear and oligotrophic (phytoplanktonic chlorophyll a?=?2.04 μg l?1; turbidity?=?2.0 NTU) and organic turbid and eutrophic (phytoplanktonic chlorophyll a?=?50.3 μg l?1; turbidity?=?16.0 NTU) scenarios. Samplings were conducted at the beginning of the experiment and at 1, 8, 19, and 33 days after glyphosate addition. For both typologies, the herbicide affected the abiotic water properties (with a marked increase in total phosphorus), but it did not affect the structure of micro and nanophytoplankton. In clear waters, glyphosate treatment induced a trend toward higher bacteria and picoeukaryotes abundances, while there was a 2 to 2.5-fold increase in picocyanobacteria number. In turbid waters, without picoeukaryotes at the beginning of the experiment, glyphosate decreased bacteria abundance but increased the number of picocyanobacteria, suggesting a direct favorable effect. Moreover, our results show that the impact of the herbicide was observed in microorganisms from both oligo and eutrophic conditions, indicating that the impact would be independent of the trophic status of the water body. 相似文献
974.
Impact of temperature on the dynamics of organic matter and on the soil-to-plant transfer of Cd,Zn and Pb in a contaminated agricultural soil 总被引:1,自引:0,他引:1
Jean-Yves Cornu L. Denaix J. Lacoste V. Sappin-Didier C. Nguyen A. Schneider 《Environmental science and pollution research international》2016,23(4):2997-3007
Predicting the soil-to-plant transfer of metals in the context of global warming has become a major issue for food safety. It requires a better understanding of how the temperature alters the bioavailability of metals in cultivated soils. This study focuses on one agricultural soil contaminated by Cd, Zn and Pb. DGT measurements were performed at 10, 20 and 30 °C to assess how the bioavailability of metals was affected by a rise in soil temperature. A lettuce crop was cultivated in the same conditions to determine if the soil-to-plant transfer of metals increased with a rise in soil temperature. A gradual decline in Cd and Zn bioavailability was observed from 10 to 30 °C, which was attributed to more intense complexation of metals in the pore water at higher temperatures. Together with its aromaticity, the affinity of dissolved organic matter (DOM) for metals was indeed suspected to increase with soil temperature. One main output of the present work is a model which satisfactorily explains the thermal-induced changes in the characteristics of DOM reported in Cornu et al. (Geoderma 162:65–70, 2011) by assuming that the mineralization of initial aliphatic compounds followed a first-order reaction, increased with soil temperature according to the Arrhenius law, and due to a priming effect, led to the appearance of aromatic molecules. The soil-to-plant transfer of Cd and Zn was promoted at higher soil temperatures despite a parallel decrease in Cd and Zn bioavailability. This suggests that plant processes affect the soil-to-plant transfer of Cd and Zn the most when the soil temperature rises. 相似文献
975.
976.
C. Nguyen A. J. Soulier P. Masson S. Bussière J. Y. Cornu 《Environmental science and pollution research international》2016,23(4):3152-3164
This work focuses on the exposure of maize plants to nanomolar concentrations of Cd, which is relevant for agricultural soils cropped with food and feed plants. Maize plants were cultivated in nutrient solution at 0.8 or 20 nM Cd during the vegetative growth stages. No significant hormesis or toxic effects of Cd were observed on maize growth, but a decrease in the allocation of Cd to shoots between the 0.8 and 20 nM Cd exposures revealed that the plants already responded to these low concentrations of Cd according to a shoot Cd excluder strategy. The Cd, Cu and Zn concentrations in shoots decreased with time as the result of an early decrease in the root/shoot ratio and of a decrease in the coefficient of allocation to aboveground for Zn and Cd at 20 nM. As a consequence, shoots of young plants were richer in micronutrients Cu and Zn but also in toxic Cd. The rate of delivery of Cd, Cu and Zn from xylem sap was successfully used to predict the time course of concentrations of Cd, Cu and Zn in the shoot. However, it overestimated the actual concentrations of Cd in the shoot, presumably because the reallocation of this trace element from shoots back to roots was not taken into account. 相似文献
977.
Release of PCBs from Silvretta glacier (Switzerland) investigated in lake sediments and meltwater 总被引:1,自引:0,他引:1
P. A. Pavlova M. Zennegg F. S. Anselmetti P. Schmid C. Bogdal C. Steinlin M. Jäggi M. Schwikowski 《Environmental science and pollution research international》2016,23(11):10308-10316
This study is part of our investigations about the release of persistent organic pollutants from melting Alpine glaciers and the relevance of the glaciers as secondary sources of legacy pollutants. Here, we studied the melt-related release of polychlorinated biphenyls (PCBs) in proglacial lakes and glacier streams of the catchment of the Silvretta glacier, located in the Swiss Alps. To explore a spatial and temporal distribution of chemicals in glacier melt, we combined two approaches: (1) analysing a sediment record as an archive of past remobilization and (2) passive water sampling to capture the current release of PCBs during melt period. In addition, we determined PCBs in a non-glacier-fed stream as a reference for the background pollutant level in the area. The PCBs in the sediment core from the Silvretta lake generally complied with trends of PCB emissions into the environment. Elevated concentrations during the most recent ten years, comparable in level with times of the highest atmospheric input, were attributed to accelerated melting of the glacier. This interpretation is supported by the detected PCB fractionation pattern towards heavier, less volatile congeners, and by increased activity concentrations of the radioactive tracer 137Cs in this part of the sediment core. In contrast, PCB concentrations were not elevated in the stream water, since no significant difference between pollutant concentrations in the glacier-fed and the non-glacier-fed streams was detected. In stream water, no current decrease of the PCBs with distance from the glacier was observed. Thus, according to our data, an influence of PCBs release due to accelerated glacier melt was only detected in the proglacial lake, but not in the other compartments of the Silvretta catchment. 相似文献
978.
A. Franzo R. Auriemma F. Nasi J. Vojvoda A. Pallavicini T. Cibic P. Del Negro 《Environmental science and pollution research international》2016,23(13):12645-12661
The benthic ecosystem functioning is a rarely applied holistic approach that integrates the main chemical and biological features of the benthic domain with the key processes responsible for the flux of energy and C through the system. For the first time, such conceptual model, with an emphasis on the heterotrophic pathways, has been applied to the sediments at four stations within one of the most polluted coastal areas in Italy: the Mar Piccolo of Taranto. The functioning of the benthic ecosystem was different according to the investigated site. Nearby the military arsenal, i.e., the main source of organic contaminants and heavy metals, the system seemed inhibited at all the investigated structural and functional levels. Slow microbial processes of C reworking together with very limited densities of benthic fauna suggested a modest transfer of C both into a solid microbial loop and to the higher trophic levels. On the other hand, the ingression of marine water through the “Navigabile” channel seemed to stimulate the organic matter degradation and, consequently, the proliferation of meiofauna and macrofauna. In the innermost part of the basin, the system functioning, to some extent, is less impacted by contaminants and more influenced by mussel farms. The organic matter produced by these bivalves fueled faster C reworking by benthic prokaryotes and enhanced the proliferation of filter feeders. 相似文献
979.
M. J. Bebianno S. Sroda T. Gomes P. Chan E. Bonnafe H. Budzinski F. Geret 《Environmental science and pollution research international》2016,23(6):5046-5055
The increase use of pharmaceutical compounds in veterinary practice and human population results in the ubiquitous presence of these compounds in aquatic ecosystems. Because pharmaceuticals are highly bioactive, there is concern about their toxicological effects in aquatic organisms. Therefore, the aim of this study was to assess the effects of an effluent from a psychiatric hospital (containing a complex mixture of 25 pharmaceutical compounds from eleven therapeutic classes) on the freshwater clam Corbicula fluminea using a proteomic approach. The exposure of C. fluminea to this complex effluent containing anxiolytics, analgesics, lipid regulators, beta blockers, antidepressants, antiepileptics, antihistamines, antihypertensives, antiplatelets and antiarrhythmics induced protein changes after 1 day of exposure in clam gills and digestive gland more evident in the digestive gland. These changes included increase in the abundance of proteins associated with structural (actin and tubulin), cellular functions (calreticulin, proliferating cell nuclear antigen (PCNA), T complex protein 1 (TCP1)) and metabolism (aldehyde dehydrogenase (ALDH), alcohol dehydrogenase, 6 phosphogluconate dehydrogenase). Results from this study indicate that calreticulin, PCNA, ALDH and alcohol dehydrogenase in the digestive gland and T complex protein 1 (TCP1)) and 6 phosphogluconate dehydrogenase in the gills represent useful biomarkers for the ecotoxicological characterization of psychiatric hospital effluents in this species. 相似文献
980.
Petra C. Lindholm-Lehto Heidi S. J. Ahkola Juha S. Knuutinen Jaana Koistinen Kirsti Lahti Heli Vahtera Sirpa H. Herve 《Environmental science and pollution research international》2016,23(18):18043-18054
The occurrence of five pharmaceuticals, consisting of four anti-inflammatory and one antiepileptic drug, was studied by passive sampling and grab sampling in northern Lake Päijänne and River Vantaa. The passive sampling was performed by using Chemcatcher® sampler with a SDB-RPS Empore disk as a receiving phase. In Lake Päijänne, the sampling was conducted during summer 2013 at four locations near the discharge point of a wastewater treatment plant and in the years 2013 and 2015 at four locations along River Vantaa. The samples were analyzed by liquid chromatography coupled to tandem mass spectrometry (LC-MS/MS) in the multiple reaction monitoring mode. The concentrations of carbamazepine, diclofenac, ibuprofen, ketoprofen, and naproxen in Lake Päijänne determined by passive sampling ranged between 1.4–2.9 ng L?1, 15–35 ng L?1, 13–31 ng L?1, 16–27 ng L?1, and 3.3–32 ng L?1, respectively. Similarly, the results in River Vantaa ranged between 1.2–40 ng L?1, 15–65 ng L?1, 13–33 ng L?1, 16–31 ng L?1, and 3.3–6.4 ng L?1. The results suggest that the Chemcatcher passive samplers are suitable for detecting pharmaceuticals in lake and river waters. 相似文献