Experiments on vertical transverse mixing in a large-scale heterogeneous model aquifer

Vertical transverse mixing is known to be a controlling factor in natural attenuation of extended biodegradable plumes originating from continuously emitting sources. We perform conservative and reactive tracer tests in a quasi two-dimensional 14 m long sand box in order to quantify vertical mixing in heterogeneous media. The filling mimics natural sediments including a distribution of different hydro-facies, made of different sand mixtures, and micro-structures within the sand lenses. We quantify the concentration distribution of the conservative tracer by the analysis of digital images taken at steady state during the tracer-dye experiment. Heterogeneity causes plume meandering, leading to distorted concentration profiles. Without knowledge about the velocity distribution, it is not possible to determine meaningful vertical dispersion coefficients from the concentration profiles. Using the stream-line pattern resulting from an inverse model of previous experiments in the sand box, we can correct for the plume meandering. The resulting vertical dispersion coefficient is approximately approximately 4 x 10(-)(9) m(2)/s. We observe no distinct increase in the vertical dispersion coefficient with increasing travel distance, indicating that heterogeneity has hardly any impact on vertical transverse mixing. In the reactive tracer test, we continuously inject an alkaline solution over a certain height into the domain that is occupied otherwise by an acidic solution. The outline of the alkaline plume is visualized by adding a pH indicator into both solutions. From the height and length of the reactive plume, we estimate a transverse dispersion coefficient of approximately 3 x 10(-)(9) m(2)/s. Overall, the vertical transverse dispersion coefficients are less than an order of magnitude larger than pore diffusion coefficients and hardly increase due to heterogeneity. Thus, we conclude for the assessment of natural attenuation that reactive plumes might become very large if they are controlled by vertical dispersive mixing.     

Estimation of biogenic emissions with satellite-derived land use and land cover data for air quality modeling of Houston-Galveston ozone nonattainment area

The Houston-Galveston Area (HGA) is one of the most severe ozone non-attainment regions in the US. To study the effectiveness of controlling anthropogenic emissions to mitigate regional ozone nonattainment problems, it is necessary to utilize adequate datasets describing the environmental conditions that influence the photochemical reactivity of the ambient atmosphere. Compared to the anthropogenic emissions from point and mobile sources, there are large uncertainties in the locations and amounts of biogenic emissions. For regional air quality modeling applications, biogenic emissions are not directly measured but are usually estimated with meteorological data such as photo-synthetically active solar radiation, surface temperature, land type, and vegetation database. In this paper, we characterize these meteorological input parameters and two different land use land cover datasets available for HGA: the conventional biogenic vegetation/land use data and satellite-derived high-resolution land cover data. We describe the procedures used for the estimation of biogenic emissions with the satellite derived land cover data and leaf mass density information. Air quality model simulations were performed using both the original and the new biogenic emissions estimates. The results showed that there were considerable uncertainties in biogenic emissions inputs. Subsequently, ozone predictions were affected up to 10 ppb, but the magnitudes and locations of peak ozone varied each day depending on the upwind or downwind positions of the biogenic emission sources relative to the anthropogenic NOx and VOC sources. Although the assessment had limitations such as heterogeneity in the spatial resolutions, the study highlighted the significance of biogenic emissions uncertainty on air quality predictions. However, the study did not allow extrapolation of the directional changes in air quality corresponding to the changes in LULC because the two datasets were based on vastly different LULC category definitions and uncertainties in the vegetation distributions.     

Development of information intensive agrichemical management services in wisconsin

This paper examines opportunities to improve the environmental and economic performance of cropping systems through intensified application of information in agrichemical management. Through intensified application of information, both net farm income and environmental quality may increase through more closely matching the specific needs of the crop with the type, timing, and volume of chemical inputs used in crop production. This study examines the current status and future prospect of agrichemical dealers offering information intensive agrichemical management services to producers. Agrichemical dealers are the focus of this study because: (1) farmers are perceived as ill-prepared to substantially upgrade the sophistication of their agrichemical management without off-farm support, and (2) dealers enjoy a close relationship with farmers, which potentially could be expanded to include a variety of information-based services. A mail survey was conducted of all agrichemical suppliers/applications in Wisconsin. The response rate was 76% (172 of 225). Substantial numbers of services were found to be offered by many dealers. The majority of these services were related to traditional yield-enhancement function. Services that have a greater potential to mitigate the negative environmental impacts of inefficient agrichemical use and have higher on-farm data requirements were found to be less widely offered by dealers. Analysis of constraints to further development of information-intensive services indicates that dealers offering significant numbers of services are concerned with constraints external to the dealership, while dealers offering relatively few services perceive internal constraints as most limiting. This relationship indicates that efforts to accelerate dealerships' development of information-intensive agrichemical management services should focus on specific constraints operating on targeted dealerships.     

Auxin induced stress tolerance in algae

IAA effect on responses of West African algae Caloglosa, Bostrychia, Rhizoclonium and the fresh water alga Pithophora to different growth conditions was examined in growth chamber experiments. The auxin (2.28 x 10(-5) M) caused growth increase of 2.3- and 2.6-fold in Caloglossa and 1.6 and 1.7 in Rhizoclonium, respectively, in sea water and 1:1 diluted sea water/Erdschreiber medium. In Bostrychia pronounced deterioration of growth was noticed in the control samples between 16 and 32 days in culture. The cultures maintained an active growth, however, in the presence of IAA. IAA also allowed Pithophora to withstand salinity: Compared to growth in fresh water, a 65% growth inhibition was recorded in 1:1 diluted sea water in the absence of auxin and a slight growth stimulation when the auxin was present. Pithophora and Rhizoclonium also maintained higher rates of growth in extremal temperatures of 10 and 45 degrees C when the auxin was present.     

Effect of sludge treatment on the bioaccumulation of nonylphenol in grass grown on sludge-amended soil

We studied the accumulation of p353-nonylphenol residues in the biomass of grass grown in soil amended with sewage sludge submitted to various conditioning/dewatering treatments. Incubation experiments were conducted growing Poa pratensis in sludge-amended soils and applying one ¹⁴C-labelled isomer of nonylphenol in the different systems. More metabolites than parent compounds were recovered in both roots and leaves of the grass. The type of sludge conditioning and dewatering treatment had a slight effect on the bioaccumulation of nonylphenol and its metabolites. When the grass was cultivated in soils amended with dewatered sludge without conditioning pretreatment, an increased accumulation was observed in the roots, while the final biomass of the grass was lower.     

Simulation of wind-driven dispersion of fire pollutants in a street canyon using FDS

Air quality in urban areas attracts great attention due to increasing pollutant emissions and their negative effects on human health and environment. Numerous studies, such as those by Mouilleau and Champassith (J Loss Prevent Proc 22(3): 316–323, 2009), Xie et al. (J Hydrodyn 21(1): 108–117, 2009), and Yassin (Environ Sci Pollut Res 20(6): 3975–3988, 2013) focus on the air pollutant dispersion with no buoyancy effect or weak buoyancy effect. A few studies, such as those by Hu et al. (J Hazard Mater 166(1): 394–406, 2009; J Hazard Mater 192(3): 940–948, 2011; J Civ Eng Manag (2013)) focus on the fire-induced dispersion of pollutants with heat buoyancy release rate in the range from 0.5 to 20 MW. However, the air pollution source might very often be concentrated and intensive, as a consequence of the hazardous materials fire. Namely, transportation of fuel through urban areas occurs regularly, because it is often impossible to find alternative supply routes. It is accompanied with the risk of fire accident occurrences. Accident prevention strategies require analysis of the worst scenarios in which fire products jeopardize the exposed population and environment. The aim of this article is to analyze the impact of wind flow on air pollution and human vulnerability to fire products in a street canyon. For simulation of the gasoline tanker truck fire as a result of a multivehicle accident, computational fluid dynamics large eddy simulation method has been used. Numerical results show that the fire products flow vertically upward, without touching the walls of the buildings in the absence of wind. However, when the wind velocity reaches the critical value, the products touch the walls of the buildings on both sides of the street canyon. The concentrations of carbon monoxide and soot decrease, whereas carbon dioxide concentration increases with the rise of height above the street canyon ground level. The longitudinal concentration of the pollutants inside the street increases with the rise of the wind velocity at the roof level of the street canyon.